Cleaning blade for removing toner
View Patent ↗A cleaning blade member includes a cleaning layer and an elastic layer provided on the cleaning layer's back surface. Both are formed of a polyurethane member produced through curing and molding a castable polyurethane composition, the cleaning layer containing a long-chain polyol, a polyisocyanate, and a diamino compound having a melting point≦80° C., the elastic layer containing a long-chain polyol, a polyisocyanate, a short-chain diol, and a short-chain triol, and has a percent edge drooping≦7.0%, the cleaning and elastic layers have Young's modulus contribution factors R a and R b , respectively. (R b /R a )=0.05-6.0. R a =[T a E a /(T a +T b )]. R b =[T b E b /(T a +T b )]. E a and E b are Young's modulus of the cleaning and elastic layers, respectively. T a and T b represent the thicknesses of the cleaning and elastic layers, respectively, and the overall Young's modulus of the cleaning layer and elastic layer is (R a +R b )=5.0-14.0 MPa.
1. A cleaning blade member for removing toner deposited on an object, the cleaning blade member comprising:
a cleaning layer which contacts the object, and
an elastic layer provided on the back surface of the cleaning layer, wherein,
the cleaning layer is formed of a polyurethane member produced through curing and molding a castable polyurethane composition comprising a long-chain polyol, a polyisocyanate, and a diamino compound having a melting point of 80° C. or lower,
the elastic layer is formed of a polyurethane member produced through curing and molding a castable polyurethane composition comprising a long-chain polyol, a polyisocyanate, a short-chain diol, and a short-chain triol, the polyisocyanate being contained in an amount of 20 to 45 parts by mass with respect to 100 parts by mass of the polyol, and a ratio of the amount by mole of the short-chain triol to the total amount by mole of the short-chain diol and the short chain triol being 0.4 or higher, and has a percent edge drooping of 7.0% or less,
the cleaning layer has a Young's modulus contribution factor (R a ), and the elastic layer has a Young's modulus contribution factor (R b ), with the ratio (R b /R a ) being 0.05 to 6.0, wherein R a is defined by formula (1):
R a =[T a E a /( T a +T b )] (1),
and R b is defined by formula (2):
R b =[T b E b /( T a +T b )] (2),
E a represents the Young's modulus of the cleaning layer; E b represents the Young's modulus of the elastic layer; T a represents the thickness of the cleaning layer; and T b represents the thickness of the elastic layer, and
the overall Young's modulus of the cleaning layer and the elastic layer as defined by (R a +R b ) is 5.0 to 14.0 MPa.
2. The cleaning blade member as defined in claim 1 , wherein the diamino compound having a melting point of 80° C. or lower contains no chlorine atom but contains an aromatic ring in the molecular structure thereof and exhibits a reaction rate slower than that of 2,2′,3,3′-tetrachloro-4,4′-diaminodiphenylmethane under given hardening and molding conditions.
3. The cleaning blade member of claim 1 , wherein the percent edge drooping is 8.0% or less.
4. The cleaning blade member of claim 1 , wherein the percent edge drooping is 4.0% or more.
5. The cleaning blade member of claim 1 , wherein the ratio (R b /R a ) is in a range of 0.73 to 2.25.
6. The cleaning blade member of claim 1 , wherein the overall Young's modulus (R a +R b ) is in a range of 6.0 to 6.5 Mpa.