High strength L12 aluminum alloys
View Patent ↗High temperature aluminum alloys that can be used at temperatures from about −420° F. (−251° C.) up to about 650° F. (343° C.) are described. The alloys are strengthened by dispersion of particles based on the L1 2 intermetallic compound Al 3 X. These alloys comprise aluminum, at least one of nickel, iron and chromium; at least one of scandium, erbium, thulium, ytterbium, and lutetium, and at least one of gadolinium, yttrium, zirconium, titanium, hafnium, and niobium.
1. An aluminum alloy having high strength, ductility, corrosion resistance and fracture toughness, comprising:
at least one of about 4 to about 25 weight percent of nickel, about 1.5 to about 20 weight percent of iron, and about 1 to about 20 weight percent chromium;
at least one first element selected from the group consisting of: about 0.1 to about 4 weight percent scandium, about 0.1 to about 15 weight percent thulium, about 0.1 to about 25 weight percent ytterbium, and about 0.1 to about 25 weight percent lutetium;
at least one second element selected from the group consisting of: about 2 to about 30 weight percent yttrium, about 0.5 to about 5 weight percent zirconium, about 0.5 to about 10 weight percent titanium, about 0.5 to about 10 weight percent hafnium, and about 0.5 to about 5 weight percent niobium; and
the balance substantially aluminum, whereby the alloy comprises:
an aluminum solid solution matrix and a plurality of dispersoids, the dispersoids comprising at least one of Al 3 Ni, Al 3 Fe, Al 6 Fe, and Al 3 X;
each Al 3 X dispersoid having a coherent L1 2 structure where X comprises at least one of scandium, thulium, ytterbium, and lutetium, and at least one of yttrium, zirconium, titanium, hafnium, and niobium; and
wherein the alloy is formed by a rapid solidification process, wherein the rapid solidification process has a cooling rate greater that about 10 3 ° C./second.
2. The aluminum alloy of claim 1 , wherein the alloy is capable of being used at temperatures from about −420° F. (−251° C.) up to about 650° F. (343° C.).
3. The aluminum alloy of claim 1 , wherein the aluminum alloy is used in at least one of: an aircraft component, a rocket component, and an automobile component.
4. The aluminum alloy of claim 1 , wherein the rapid solidification technique comprises at least one of: melt spinning, splat quenching, atomization, spray deposition, vacuum plasma spraying, cold spraying, laser melting, mechanical alloying, cryomilling, spin forming, and ball milling.
5. The aluminum alloy of claim 1 , wherein the rapid solidification technique comprises at least the following steps:
creating an ingot having a predetermined composition;
melting the ingot;
atomizing the melted ingot to form a powder;
degassing the powder;
compacting the powder to create a billet; and
hot working the billet into a predetermined form.
6. The alloy of claim 1 , comprising no more than about 1 weight percent total impurities.
7. The alloy of claim 1 , comprising no more than about 0.1 weight percent manganese, about 0.1 weight percent vanadium, and about 0.1 weight percent cobalt.
8. An aluminum alloy having high strength, ductility, corrosion resistance and fracture toughness, comprising:
at least one of nickel, iron, and chromium;
at least one first element selected from the group consisting of: about 0.1 to about 4 weight percent scandium, about 0.1 to about 15 weight percent thulium, about 0.1 to about 25 weight percent ytterbium, and about 0.1 to about 25 weight percent lutetium;
at least one second element selected from the group consisting of: yttrium, zirconium, titanium, hafnium, and niobium; and
the balance substantially aluminum, whereby the alloy comprises:
an aluminum solid solution matrix and a plurality of dispersoids, the dispersoids comprising at least one of Al 3 Ni, Al 3 Fe, Al 6 Fe, and Al 3 X;
each Al 3 X dispersoid having a coherent L1 2 structure where X comprises at least one of scandium, thulium, ytterbium, and lutetium, and at least one of yttrium, zirconium, titanium, hafnium, and niobium; and
wherein the alloy is formed by a rapid solidification process, wherein the rapid solidification process has a cooling rate greater that about 10 3 ° C./second.