Nano-skeletal catalyst
A method of producing a catalyst material with nano-scale structure, the method comprising: introducing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material; the nano-powder production reactor nano-sizing the starting powder, thereby producing a nano-powder from the starting powder, the nano-powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material; and forming a catalyst precursor material from the nano-powder, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material, the catalyst material having a nano-scale structure.
1. A method of producing a catalyst material with nano-scale structure, the method comprising:
providing a starting powder into a nano-powder production reactor, the starting powder comprising a catalyst material;
nano-sizing the starting powder by using a plasma flow in the nano-powder production reactor, thereby producing a nano-powder from the starting powder, the nano powder comprising a plurality of nano-particles, each nano-particle comprising the catalyst material;
forming a catalyst precursor material from the nano-powder by using a bonding device, wherein the catalyst precursor material is a densified bulk porous structure comprising the catalyst material, the catalyst material having a nano-scale structure, wherein the bulk porous structure of the catalyst precursor material further comprises a filler material; and
further comprising removing a substantial portion of the filler material from the bulk structure of the catalyst precursor to form a nano-scale skeletal structure comprising the catalyst material, such that the catalyst material is activated to form a nano-skeletal catalyst.
2. The method of claim 1 , wherein the step of nano-sizing the starting powder includes:
generating the plasma flow within the nano-powder production reactor; and
applying the plasma flow to the starting powder.
3. The method of claim 1 , wherein the step of forming a catalyst precursor material includes pressing the nano-powder.
4. The method of claim 1 , wherein the step of forming a catalyst precursor material includes bonding the nano-powder using spark plasma sintering, thereby preserving the nano-scale structure of the catalyst material.
5. The method of claim 1 , wherein the starting powder has an average grain size greater than or equal to 1 micron.
6. The method of claim 1 , wherein the filler material comprises aluminum, zinc, or silicon.
7. The method of claim 1 , wherein the step of removing the filler material is performed by using a leaching solution.
8. The method of claim 1 , wherein the step of forming the catalyst precursor material includes adding a promoter material to the bulk porous structure, the promoter material comprising at least one of zinc, molybdenum and chromium.
9. The method of claim 1 , further comprising the step of removing surface contamination from the catalyst material.
10. The method of claim 1 , wherein the bonding device is fluidly coupled to the nano-powder production reactor.
11. The method of claim 1 , wherein the bonding device is separated from the nano-powder production reactor.
12. The method of claim 1 , wherein the bonding device is configured to receive the nano-powder to form the catalyst precursor material.
13. The method of claim 1 , wherein the bonding device employs spark-plasma sintering.
14. The method of claim 1 , wherein the nano-powder production reactor is coupled to a sampling device such that the nano-powder is exposed to the sampling device as the nano-powder is emitted from the nano-powder production reactor.
15. The method of claim 1 , wherein the nano-powder production reactor comprises one or more dispensing devices, each dispensing device coupled with a port that opens into the nano-powder production reactor.
16. The method of claim 1 , wherein the catalyst material comprises a metal of the transition group VIII of the periodic table of elements.
17. The method of claim 16 , wherein the metal comprises nickel, iron, or cobalt.
18. The method of claim 1 , wherein the starting powder consists only of the catalyst material.
19. The method of claim 18 , wherein the step of nano-sizing the starting powder includes:
generating the plasma flow within the nano powder production reactor; and
applying the plasma flow to the starting powder.
20. The method of claim 18 , wherein the step of forming a catalyst precursor material includes pressing the nano-powder.
21. The method of claim 18 , wherein the step of forming a catalyst precursor material includes bonding the nano-powder using spark plasma sintering, thereby preserving the nano-scale structure of the catalyst material.
22. The method of claim 18 , wherein the starting powder has an average grain size greater than or equal to 1 micron.
23. The method of claim 18 , wherein the step of forming the catalyst precursor material includes adding a promoter material to the bulk porous structure, the promoter material comprising at least one of zinc, molybdenum and chromium.
24. The method of claim 18 , wherein the catalyst material comprises a metal of the transition group VIII of the periodic table of elements.
25. The method of claim 24 , wherein the metal comprises nickel, iron, or cobalt.