Dissolvable thermal direct adhesive label and label assembly including the same
A label assembly including one or more dissolvable thermal direct adhesive labels mounted on a release liner. According to one embodiment, each label includes a base layer, a thermal direct layer, an adhesive layer, and a barrier layer. The base layer, which has an upper surface and a lower surface, is water-dissolvable and may be made of a water-dissolvable paper. The thermal direct layer is positioned directly over the upper surface of the base layer and functions in the conventional manner to produce markings therein in response to heat. The adhesive layer is water-dissolvable and is positioned below the lower surface of the base layer. The barrier layer, which is positioned directly below the lower surface of the base layer and directly over the adhesive layer, serves to prevent migration of the adhesive layer through the base layer and into contact with the thermal direct layer.
1. A dissolvable thermal direct adhesive label comprising:
(a) a base layer, the base layer being water-dissolvable and having an upper surface and a lower surface, wherein the base layer is a monolayer of a water-dissolvable paper made of sodium carboxy methyl cellulose and wooden pulp;
(b) a thermal direct layer, the thermal direct layer being positioned over and in direct contact with the upper surface of the base layer, the thermal direct layer being coupled to the upper surface of the base layer, wherein the thermal direct layer is one of water-dispersible and water-soluble, wherein the thermal direct layer is a monolayer comprising a basic chromogenic material and an acidic color developer material, both of which are contained in a solid matrix, and wherein the components of the thermal direct layer are substantially homogeneously distributed therethroughout;
(c) an adhesive layer, the adhesive layer being water-dissolvable, the adhesive layer being positioned below and coupled to the lower surface of the base layer, wherein the adhesive layer comprises copolymers of a carboxylic hydroxyalkyl ester monomer and an ethoxylated or propoxylated hydroxyalkyl (meth)acrylate;
(d) a water-soluble barrier layer, the water-soluble barrier layer being positioned below and in direct contact with the lower surface of the base layer and being positioned above and in direct contact with the adhesive layer, the water-soluble barrier layer preventing migration of the adhesive layer through the base layer and into contact with the thermal direct layer; and
(e) a protective overcoat, the protective overcoat being positioned over and in direct contact with the thermal direct layer, the protective overcoat comprising one or more acrylate coatings, polyvinyl chloride coatings, styrenated layers and styrenated maleic anhydride layers.
2. The dissolvable thermal direct adhesive label as claimed in claim 1 wherein the adhesive layer is a pressure-sensitive adhesive layer.
3. A label assembly comprising a release liner and a dissolvable thermal direct adhesive label as recited in claim 1 , the dissolvable thermal direct adhesive label being releasably mounted on the release liner.
4. The label assembly as claimed in claim 3 wherein the release liner comprises a support and a release, the release being positioned over the support, the dissolvable thermal direct adhesive label being positioned over the release.
5. The label assembly as claimed in claim 4 wherein the adhesive layer of the dissolvable thermal direct adhesive label is in direct contact with the release.
6. A label assembly comprising:
(a) a release liner; and
(b) a plurality of dissolvable thermal direct adhesive labels releasably mounted on the release liner, each of said plurality of dissolvable thermal direct adhesive labels comprising
(i) a base layer, the base layer being water-dissolvable and having an upper surface and a lower surface, wherein the base layer is a monolayer of a water-dissolvable paper made of sodium carboxy methyl cellulose and wooden pulp,
(ii) a thermal direct layer, the thermal direct layer being positioned over and in direct contact with the upper surface of the base layer, the thermal direct layer being coupled to the upper surface of the base layer, wherein the thermal direct layer is one of water-dispersible and water-soluble, wherein the thermal direct layer is a monolayer comprising a basic chromogenic material and an acidic color developer material, both of which are contained in a solid matrix, and wherein the components of the thermal direct layer are substantially homogeneously distributed therethroughout,
(iii) an adhesive layer, the adhesive layer being water-dissolvable, the adhesive layer being positioned below and coupled to the lower surface of the base layer, wherein the adhesive layer comprises copolymers of a carboxylic hydroxyalkyl ester monomer and an ethoxylated or propoxylated hydroxyalkyl (meth)acrylate,
(iv) a water-soluble barrier layer, the water-soluble barrier layer being positioned below and in direct contact with the lower surface of the base layer and being positioned above and in direct contact with the adhesive layer, the water-soluble barrier layer preventing migration of the adhesive layer through the base layer and into contact with the thermal direct layer, and
(v) a protective overcoat, the protective overcoat being positioned over and in direct contact with the thermal direct layer, the protective overcoat comprising one or more acrylate coatings, polyvinyl chloride coatings, styrenated layers and styrenated maleic anhydride layers.
7. The label assembly as claimed in claim 6 wherein the adhesive layer is a pressure-sensitive adhesive layer.
8. The label assembly as claimed in claim 6 wherein the release liner comprises a support and a release, the release being positioned over the support and wherein each of the dissolvable thermal direct adhesive labels is positioned over the release.
9. The label assembly as claimed in claim 8 wherein the adhesive layer of each of the dissolvable thermal direct adhesive labels is in direct contact with the release.