Nitride semiconductor light emitting device and method of fabricating nitride semiconductor laser device
View Patent ↗There is provided a nitride semiconductor light emitting device having a light emitting portion coated with a coating film, the light emitting portion being formed of a nitride semiconductor, the coating film in contact with the light emitting portion being formed of an oxynitride. There is also provided a method of fabricating a nitride semiconductor laser device having a cavity with a facet coated with a coating film, including the steps of: providing cleavage to form the facet of the cavity; and coating the facet of the cavity with a coating film formed of an oxynitride.
1. A method of fabricating a nitride semiconductor light emitting device having a light emitting portion coated with a coating film, comprising:
forming a stack including at least a substrate, an active layer, and a clad layer, the substrate being formed of GaN;
cleaning said light emitting portion; and
coating said light emitting portion with said coating film such that said coating film is in contact with said light emitting portion, said coating film formed of an oxynitride, said oxynitride being in contact with said light emitting portion,
wherein said cleaning is performed before said coating and includes exposing said light emitting portion to a plasma of argon, nitrogen, or a combination thereof,
wherein said nitride semiconductor light emitting device is a nitride semiconductor laser device and said light emitting portion is a facet of a cavity, the facet being formed by cleaving the stack, and
wherein the light emitting portion is first exposed to a plasma of nitrogen followed by exposure to a plasma of argon.
2. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein said coating film is provided by employing aluminum as a target and introducing at least gaseous nitrogen and gaseous oxygen into a film deposition chamber.
3. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein said coating film is provided by employing at least one of aluminum oxynitride and aluminum oxide as a target and not introducing gaseous oxygen into a film deposition chamber.
4. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein said coating film is provided by oxidizing at least a part of a film deposition chamber and not introducing gaseous oxygen into said film deposition chamber.
5. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein said cleaning includes heating said light emitting portion.
6. The method of fabricating a nitride semiconductor light emitting device according to claim 5 , wherein the heating is performed at a temperature of at least 100° C. and at most 500° C.
7. The method of fabricating a nitride semiconductor light emitting device according to claim 6 , wherein the heating is performed simultaneously with exposure to the plasma of nitrogen and argon.
8. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein the oxynitride contains oxygen in an amount of at least 2 atomic percent and at most 35 atomic percent.
9. The method of fabricating a nitride semiconductor light emitting device according to claim 8 , wherein the oxynitride contains oxygen in an amount of at least 2 atomic percent and at most 15 atomic percent.
10. The method of fabricating a nitride semiconductor light emitting device according to claim 1 , wherein the coating film has a thickness of at least 1 nm.
11. The method of fabricating a nitride semiconductor light emitting device according to claim 10 , wherein the coating film has a thickness between 6 nm and 80 nm.