IP Library Granted Patent US 9,332,756
Granted Patent B2
US 9,332,756 · App. 12/159,124 · Granted May 10, 2016

Liquid formulations of carboxamide arthropodicides

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 9,332,756
App. No.
12/159,124
Granted
May 10, 2016
Kind
B2
Abstract

Disclosed are suspension concentrate compositions comprising by weight based on the total weight of the composition, about 0.1 to about 40% of at least one carboxamide arthropodicide; 0 to about 20% of at least one other biologically active agent; about 30 to about 95% of at least one water-immiscible liquid carrier; about 2 to about 50% of at least one emulsifier; about 0.01 to about 10% of a silica thickener; about 0.1 to about 10% of at least one protic solvent selected from water, a C 1 -C 12 alkanol and a C 2 -C 3 glycol; and about 0.001 to about 5% of at least one water-soluble carboxylic acid. A method for controlling an arthropod pest comprising diluting said suspension concentrate composition with water, and optionally adding an adjuvant to form a diluted composition, and contacting the arthropod pest or its environment with an effective amount of said diluted composition is also disclosed.

Claims (22)

1. An arthropodicidal suspension concentrate composition comprising by weight based on the total weight of the composition:

(a) about 0.1 to about 40% of at least one carboxamide arthropodicide that is solid at room temperature;

(b) 0 to about 20% of at least one biologically active agent other than the at least one carboxamide arthropodicide that is solid at room temperature;

(c) about 30 to about 95% of at least one water-immiscible liquid carrier selected from the group consisting of a methylated seed oil of sunflower, soybean, cotton or linseed;

(d) about 2 to about 50% of at least one emulsifier comprising a mixture of a dodecylbenzenesulfonate and an ethoxylated sorbitol hexaoleate;

(e) about 0.01 to about 10% of a silica thickener comprising fumed silica;

(f) about 0.1 to about 10% of water; and

(g) about 0.001 to about 5% of citric acid;

wherein component (a) is selected from anthranilamides of Formula 1, N-oxides, and salts thereof

wherein

X is N, CF, CCl, CBr or Cl;

R 1 is CH 3 , Cl, Br or F;

R 2 is H, F, Cl, Br or —CN;

R 3 is F, Cl, Br, C 1 -C 4 haloalkyl or C 1 -C 4 haloalkoxy;

R 4a is H, C 1 -C 4 alkyl, cyclopropylmethyl or 1-cyclopropylethyl;

R 4b is H or CH 3 ;

R 5 is H, F, Cl or Br; and

R 6 is H, F, Cl or Br.

2. The composition of claim 1 wherein component (a) is from about 5 to about 25% of the composition by weight; component (b) is from 0 to about 15% of the composition by weight; component (c) is from about 40 to about 70% of the composition by weight; component (d) is from about 10 to about 40% of the composition by weight; component (e) is from about 0.01 to about 5% of the composition by weight; component (f) is from about 0.5 to about 5% of the composition by weight; and component (g) is from about 0.01 to about 5% of the composition by weight.

3. The composition of claim 1 wherein component (c) comprises a methylated soybean oil.

4. The composition of claim 1 wherein the at least one biologically active agent other than the at least one carboxamide arthropodicide is selected from abamectin, acetamiprid, amitraz, avermectin, azadirachtin, bifenthrin, buprofezin, cartap, chlorfenapyr, chlorpyrifos, clothianidin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, cypermethrin, cyromazine, deltamethrin, dieldrin, dinotefuran, diofenolan, emamectin, endosulfan, esfenvalerate, ethiprole, fenothiocarb, fenoxycarb, fenvalerate, fipronil, flonicamid, flufenoxuron, hexaflumuron, hydramethylnon, imidacloprid, indoxacarb, lufenuron, metaflumizone, methomyl, methoprene, methoxyfenozide, nitenpyram, nithiazine, novaluron, oxamyl, pymetrozine, pyrethrin, pyridaben, pyridalyl, pyriproxyfen, ryanodine, spinetoram, spinosad, spirodiclofen, spiromesifen, tebufenozide, thiacloprid, thiamethoxam, thiodicarb, thiosultap-sodium, tralomethrin, triazamate, triflumuron, Bacillus thuringiensis subsp. aizawai, Bacillus thuringiensis subsp. kurstaki , nucleopolyhedrovirus, and an encapsulated delta-endotoxin of Bacillus thuringiensis.

5. A method for controlling an arthropod pest, comprising diluting a arthropodicidal suspension concentrate composition of claim 1 with water, and optionally adding an adjuvant to form a diluted composition, and contacting the arthropod pest or its environment with an effective amount of said diluted composition.

Assignments (4)
PATENT SECURITY AGREEMENT Recorded Apr 17, 2026
From: FMC CORPORATION
To: CITIBANK, N.A.
Reel/Frame 075403/0891 →
CHANGE OF ADDRESS Recorded Sep 14, 2025
From: FMC IP TECHNOLOGY GMBH
To: FMC IP TECHNOLOGY GMBH
Reel/Frame 072892/0066 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2024
From: FMC AGRO SINGAPORE PTE. LTD.
To: FMC IP TECHNOLOGY GMBH
Reel/Frame 067639/0738 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 17, 2018
From: E.I. DU PONT DE NEMOURS AND COMPANY
To: FMC AGRO SINGAPORE PTE. LTD.; FMC CORPORATION
Reel/Frame 047254/0541 →