Curable composition
View Patent ↗Provided is a curable composition excellent in curability and mechanical properties as well as a cured product thereof. Specially provided is a curable composition containing a vinyl-based polymer (I) having one or more crosslinkable functional groups at a terminus on average and a nucleophilic agent (II) and a cured product obtained by curing the curable composition. Preferably, the curable composition of the invention further contains an epoxy resin (III).
1. A curable composition comprising a vinyl-based polymer (I) having one or more crosslinkable functional groups at a terminus on average, a nucleophilic agent (II) and an epoxy resin (III), wherein
the molecular-weight distribution of said vinyl-based polymer (I) is less than 1.8,
the crosslinkable functional group of said vinyl-based polymer (I) is a group having a polymerizable carbon-carbon double bond,
said vinyl-based polymer (I) is a polymer produced by living radical polymerization, and said vinyl-based polymer (I) comprises a main chain formed from at least one vinyl-based monomer selected from the group consisting of
(meth)acrylic acid, methyl(meth)acrylate, ethyl(meth)acrylate, n-propyl(meth)acrylate, isopropyl(meth)acrylate, n-butyl(meth)acrylate, isobutyl(meth)acrylate, tert-butyl (meth)acrylate, n-pentyl(meth)acrylate, n-hexyl(meth)acrylate, cyclohexyl(meth)acrylate, n-heptyl(meth)acrylate, n-octyl(meth)acrylate, 2-ethylhexyl(meth)acrylate, nonyl(meth)acrylate, decyl(meth)acrylate, dodecyl(meth)acrylate, phenyl(meth)acrylate, tolyl(meth)acrylate, benzyl(meth)acrylate, 2-methoxyethyl(meth)acrylate, 3-methoxybutyl(meth)acrylate, stearyl(meth)acrylate, glycidyl(meth)acrylate, γ-(methacryloyloxypropyl)trimethoxysilane, an ethylene oxide adduct of (meth)acrylic acid, trifluoromethylmethyl(meth)acrylate, 2-trifluoromethylethyl(meth)acrylate, perfluoroethylmethyl(meth)acrylate, 2-perfluoroethylethyl(meth)acrylate, perfluoroethylperfluorobutylmethyl(meth)acrylate, 2-perfluoroethyl-2-perfluorobutylethyl(meth)acrylate, perfluoroethyl(meth)acrylate, perfluoromethyl(meth)acrylate, diperfluoromethylmethyl(meth)acrylate, 2,2-diperfluoromethylethyl(meth)acrylate, perfluoromethylperfluaroethylmethyl(meth)acrylate, 2-perfluoromethyl-2-perfluaroethylethyl(meth)acrylate, 2-perfluorohexylmethyl(meth)acrylate, 2-perfluorohexylethyl(meth)acrylate, 2-perfluorodecylmethyl(meth)acrylate, 2-perfluorodecylethyl(meth)acrylate, 2-perfluorohexadecylmethyl(meth)acrylate and 2-perfluorohexadecylethyl(meth)acrylate.
2. The curable composition according to claim 1 , wherein the nucleophilic agent (II) is a compound having active hydrogen.
3. The curable composition according to claim 2 , wherein said compound having active hydrogen is an amine compound and/or a thiol compound.
4. The curable composition according to claim 3 , wherein said amine compound is at least one member selected from the group consisting of an aliphatic polyamine, an aromatic polyamine, an alicyclic polyamine, a polyamidoamine, and an imidazole.
5. The curable composition according to claim 3 , wherein said thiol compound is at least one member selected from the group consisting of an aliphatic polythiol, an aromatic polythiol and a modified polythiol.
6. The curable composition according to claim 1 , wherein the crosslinkable functional group of said vinyl-based polymer (I) is an alkenyl group.
7. The curable composition according to claim 1 , wherein the main chain of said vinyl-based polymer (I) is a (meth)acrylic polymer.
8. The curable composition according to claim 1 , wherein the main chain of said vinyl-based polymer (I) is an acrylic polymer.
9. The curable composition according to claim 1 , wherein the main chain of said vinyl-based polymer (I) is an acrylate polymer.
10. The curable composition according to claim 1 , wherein the living radical polymerization is atom transfer radical polymerization.
11. The curable composition according to claim 10 , wherein the atom transfer radical polymerization uses, as a catalyst, a metal complex selected from transition metal complexes composed of a VII, VIII, IX, X, or XI group element in the periodic table as a central metal.
12. The curable composition according to claim 11 , wherein the metal complex used as a catalyst is a complex selected from the group consisting of complexes of copper, nickel, ruthenium, or iron.
13. The curable composition according to claim 12 , wherein the metal complex used as a catalyst is a complex of copper.
14. A cured product obtained by curing the curable composition according to claim 1 .