Hydrogenation catalyst and use thereof for hydrogenating fischer-tropsch endproducts
View Patent ↗A hydrogenation catalyst particularly suitable for hydrogenating oxygenates in a hydrogenation unit of a Fischer-Tropsch plant is disclosed. A preferred embodiment comprises more than 5% and less than 20% nickel based on a wide pore alumina support. The catalyst successfully hydrogenates oxygenates which otherwise tend to poison a catalyst in a hydroconversion unit downstream. Moreover, the temperature at which the unwanted hydrogenolysis of long chain paraffins to methane occurs is higher for one catalyst disclosed herein than a comparable known catalyst. This allows the hydrogenation plant to operate at a higher temperature.
1. A hydrogenation catalyst, the catalyst comprising a metallic active portion comprising nickel crystallites and a support comprising wide pore alumina, wherein the support does not catalyse an acid catalysed reaction and wherein over 90% of the pores within the support are sized between 100 Å-400 Å, wherein the catalyst comprises between 5 and 20% nickel and wherein the nickel crystallites are around 2.5 nm.
2. A hydrogenation catalyst as claimed in claim 1 , wherein the median pore diameter is greater than 170 Å, and wherein less than 11% of the pore volume is provided by pores with a diameter greater than 350 Å.
3. A hydrogenation catalyst as claimed in claim 1 , wherein the catalyst comprises between 7 and 18% nickel.
4. A method for manufacturing a hydrogenation catalyst according to claim 1 , the method comprising:
admixing a solution of a nickel salt with a support;
drying and calcining the mixture.
5. A method as claimed in claim 4 , wherein the metal salt is mixed in a basic solution.