TREATED ARTICLES AND METHODS OF TREATING ARTICLES
Treated articles are provided. The treated articles may have at least one functional particle in a substrate and at least one blocking material. The blocking material inhibits the release of the at least one functional particle from the substrate. Methods of treating articles are further provided.
1 . A treated article, comprising:
a substrate;
at least one functional particle in the substrate; and
a blocking material comprising at least one polymer formed from self-assembling monomers, wherein the blocking material inhibits release of the at least one functional particle from the substrate, and wherein the blocking material is disposed on at least a portion of at least one surface of the substrate.
2 . The treated article as claimed in claim 1 wherein the at least one functional particle comprises at least one nanoparticle comprising carbon nanotubes, TiO 2 , Ag, carbon black, ZrO 2 , MgO, SiO 2 , ZnO, Al 2 O 3 , Nb 2 O 5 , WO 3 , Ta 2 O 5 , HfO 2 , SnO 2 , SiAlO 3.5 , SiTiO 4 , ZrTiO 4 , Al 2 TiO 5 , ZrW 2 O 8 , CaCO 3 , MoO 3 , Mo, V 2 O 5 , Sb 2 O 5 , Pd, ZnO, Fe 3 O 4 , Kaolin, Sulfur, CoFe 2 O 4 , Au, Pt, Cu, Ni, quantum dots, halloysites, inorganic nanomaterials, organic nanomaterials, and naturally occurring nanomaterials, or combinations thereof.
3 . The treated article as claimed in claim 1 wherein the at least one functional particle comprises activated carbon, fabric softeners, thermochromic materials, magnetic particles, reflective particles, fire retardants, fire suppressant chemicals, insect repellents, electromagnetic interference shielding materials, radio frequency interference shielding materials, heat-releasing phase change agents, fragrances, metallic reflector colloids, pigments, zeolites, dyes, fertilizers, sun blocking agents, pharmaceuticals, antimicrobial agents, anti-fungal agents, and sporicidal agents, or combinations thereof.
4 . The treated article as claimed in claim 1 wherein the self-assembling monomers comprises lipids, diacetylene derivatives, monomers for forming conjugated polymers, alkyl trichlorosilane derivatives, alkyl trialkoxysilane derivates, liquid crystalline monomers, 3-(trimethoxysilyl)-1-propanethiol, thiols, vinyl monomers, epoxides, lignins, dienes, eneynes, pyrolles, thiphenes, pyrazoles, urethanes, imides, acrylonitriles, alkynes, anthracenes, stilbenes, and cationic, anionic and neutral surfactants, monomers for liquid crystalline polymers, or combinations thereof.
5 . The treated article as claimed in claim 1 wherein the self-assembling monomers comprise diacetylene monomers.
6 . The treated article as claimed in claim 1 wherein the polymer comprises a conjugated polymer selected from lipid poly(diacetylene) derivatives, poly(p-phenylene vinylene), polyanilines, natural and synthetic vinyl polymers, or combinations thereof.
7 . The treated article as claimed in claim 1 wherein the polymer further comprises functional groups selected from amines, carboxylic acid, N-hydroxy succinimide, isocyanates, hydroxyl groups, or combinations thereof.
8 . The treated article as claimed in claim 1 wherein the substrate is selected from fibers, yarns, porous and non-porous textiles, membranes, metals, and natural and synthetic polymers, or combinations thereof.
9 . The treated article as claimed in claim 1 wherein the blocking material comprises a nanomaterial.
10 . The treated article as claimed in claim 1 wherein the substrate comprises a textile and the self-assembling monomer comprises a diacetylene.
11 . The treated article as claimed in claim 10 wherein the diacetylene comprises 10,12-pentacosadiynoic acid.
12 . A method for treating articles, comprising:
providing a substrate having at least one functional particle;
treating the substrate with self-assembling monomers; and
polymerizing the self-assembling monomers such that release of the at least one functional particle from the substrate is inhibited.
13 . The method as claimed in claim 12 , wherein the step of treating the substrate comprises applying a solution of a self-assembling monomer to the substrate.
14 . The method as claimed in claim 13 , wherein the step of applying a solution of self-assembling monomer to the substrate is performed by spin coating, dip coating, flow coating, spray coating, or combinations thereof.
15 . The method as claimed in claim 12 , wherein the step of polymerizing is performed by at least one of drying, heating, UV curing, and radiation curing of the substrate having the self-assembling monomer thereon.
16 . The method as claimed in claim 12 , wherein the step of treating the substrate comprises treating the substrate with self-assembling monomers comprising lipids, diacetylene derivatives, monomers for forming conjugated polymers, alkyl trichlorosilane derivatives, alkyl trialkoxysilane derivates, liquid crystalline monomers, 3-(trimethoxysilyl)-1-propanethiol, thiols, vinyl monomers, epoxides, lignins, dienes, eneynes, pyrolles, thiphenes, pyrazoles, urethanes, imides, acrylonitriles, alkynes, anthracenes, stilbenes, and cationic, anionic and neutral surfactants, monomers for liquid crystalline polymers, or combinations thereof.
17 . The method as claimed in claim 12 , wherein the step of providing a substrate comprises providing a substrate having at least one functional particle comprising carbon nanotubes, TiO 2 , Ag, carbon black, ZrO 2 , MgO, SiO 2 , ZnO, Al 2 O 3 , Nb 2 O 5 , WO 3 , Ta 2 O 5 , HfO 2 , SnO 2 , SiAlO 3.5 , SiTiO 4 , ZrTiO 4 , Al 2 TiO 5 , ZrW 2 O 8 , CaCO 3 , MoO 3 , Mo, V 2 O 5 , Sb 2 O 5 , Pd, ZnO, Fe 3 O 4 , Kaolin, Sulfur, CoFe 2 O 4 , Au, Pt, Cu, Ni, quantum dots, halloysites, inorganic nanomaterials, organic nanomaterials, and naturally occurring nanomaterials, or combinations thereof.
18 . The method as claimed in claim 12 , wherein the step of providing a substrate comprises providing a substrate having at least one functional particle comprising activated carbon, fabric softeners, thermochromic materials, magnetic particles, reflective particles, fire retardants, fire suppressant chemicals, insect repellents, electromagnetic interference shielding materials, radio frequency interference shielding materials, heat-releasing phase change agents, fragrances, metallic reflector colloids, pigments, zeolites, dyes, fertilizers, sun blocking agents, pharmaceuticals, antimicrobial agents, anti-fungal agents, and sporicidal agents, or combinations thereof.
19 . The method as claimed in claim 12 , wherein the step of providing a substrate comprises providing a substrate comprising fibers, yarns, porous and non-porous textiles, membranes, metals, and natural and synthetic polymers, or combinations thereof.
20 . The method as claimed in claim 12 , wherein the step of providing a substrate comprises providing a textile, and wherein the step of treating a substrate comprises applying a solution of 10,12-pentacosadiynoic acid to the textile.
21 . The method as claimed in claim 20 , wherein the step of polymerizing comprises drying the treated substrate and exposing the treated substrate to UV radiation for a period sufficient to cause cross-linking of the 10,12-pentacosadiynoic acid.