Multilayer film structures comprising bio-based materials
View Patent ↗A multilayer film structure is disclosed which comprises at least a first layer made of a bio-based polymer composition; a tie layer comprising one or more ethylene copolymers and one or more inorganic fillers; and optionally at least one additional layer.
1. A multilayer film structure comprising a first layer, a tie layer, and at least one additional layer wherein
the first layer is made of a bio-based polymer composition, said bio-based polymer comprising a poly(hydroxyalkanoic acid) (PHA) or a bio-based polyester;
the tie layer is adjacent to and lies between the first layer and the additional layer;
the tie layer includes 50 to 95 wt %, based on the weight of the tie layer, of an ethylene copolymer and 5 to 50 wt % of a filler;
the ethylene copolymer is selected from the group consisting of ethylene methyl (meth)acrylate copolymer, ethylene ethyl (meth)acrylate copolymer, ethylene butyl (meth)acrylate copolymer, and combinations of two or more thereof;
the filler is talc, calcium carbonate, calcinated clay, mica, zinc borate, or combinations of two or more thereof;
the additional layer is selected from the group consisting of a heat sealable layer, a foil, a paperboard, a nonwoven material, and combinations of two or more thereof; and
the heat sealable layer is selected from the group consisting of poly(hydroxyalkanoic acid), glycoside, polyethylene, polypropylene, polyester, polyamide, ethylene vinyl acetate copolymer, ethylene alkyl (meth)acrylate copolymer, ethylene acid copolymers, ionomers, and combinations of two or more thereof.
2. The film of claim 1 wherein the poly(hydroxyalkanoic acid) is selected from the group consisting of poly(glycolic acid), poly(lactic acid), poly(hydroxybutyric acid), and combinations of two or more thereof.
3. The film of claim 1 wherein the poly(hydroxyalkanoic acid) is poly(lactic acid) and the ethylene copolymer is selected from the group consisting of the ethylene methyl acrylate copolymer, the ethylene butyl acrylate copolymer, and combinations of two or more thereof.
4. The film of claim 3 wherein the filler is talc.
5. The film of claim 2 wherein the thickness of the tie layer is between 1 and 100 μm.
6. The film of claim 3 wherein the tie layer further comprises, in an amount of 0.1 to 20 wt % based on the weight of the tie layer, one or more tackifiers including coumarone-indene resins, terpene resins, butadiene-styrene resins, polybutadiene resins, hydrocarbon resins, rosins, or combinations of two or more thereof.
7. The film of claim 6 wherein the thickness of the tie layer is between 1 and 100 μm.
8. The film of claim 1 wherein the bio-based polyester is poly(1,3-propylene terephthalate).
9. The film of claim 8 wherein the filler is talc and the tie layer is between 1 and 100 μm in thickness.
10. The film of claim 9 wherein the tie layer further comprises, in an amount of 0.1 to 20 wt % based on the weight of the tie layer, one or more tackifiers including coumarone-indene resins, terpene resins, butadiene-styrene resins, polybutadiene resins, hydrocarbon resins, rosins, or combinations of two or more thereof.
11. An article comprising or produced from a multilayer film wherein the article is injection molded article, blow molded article, pressed article, thermoformed rigid article, a blister, a thermoform blister, or combinations of two or more thereof and the film is as characterized in claim 1 .
12. The article of claim 11 wherein the article is a lid, a cap, a cup, a tray, or a bag and the poly(hydroxyalkanoic acid) is a polylactic acid.
13. The article of claim 11 wherein the article is a lid, a cap, a cup, a tray, or a bag and the bio-based polyester is a poly(1,3-propylene terephthalate).
14. A multilayer film structure comprising a first layer, a tie layer, at least one functional layer, a second tie layer, and at least one additional layer wherein
the first layer is made of a bio-based polymer composition;
the tie layer lies between the first layer and the additional layer;
the tie layer includes 50 to 95 wt %, based on the weight of the tie layer, of an olefin polymer selected from the group consisting of polyethylene homopolymer, an ethylene copolymer, or combinations thereof and 5 to 50 wt % of a filler;
the ethylene copolymer is selected from the group consisting of ethylene vinyl acetate copolymer, ethylene methyl (meth)acrylate copolymer, ethylene ethyl (meth)acrylate copolymer, ethylene butyl (meth)acrylate copolymer, modified ethylene copolymers, and combinations of two or more thereof;
the filler is talc, calcium carbonate, calcinated clay, mica, zinc borate, or combinations of two or more thereof;
the at least one functional layer is positioned between the tie layer and the second tie layer, wherein the functional layer is made of starch, ethylene vinyl alcohol polymer, polyamide, or combinations of two or more thereof;
the second tie layer is positioned between the functional layer and the additional layer;
the additional layer is selected from the group consisting of a heat sealable layer, a foil, a paperboard, a nonwoven material, and combinations of two or more thereof; and
the heat sealable layer is selected from the group consisting of poly(hydroxyalkanoic acid), glycoside, polyethylene, polypropylene, polyester, polyamide, ethylene vinyl acetate copolymer, ethylene alkyl (meth)acrylate copolymer, ethylene acid copolymers, ionomers, and combinations of two or more thereof.
15. The film of claim 14 wherein the ethylene copolymer is the modified ethylene copolymer.
16. The film of claim 15 wherein the modified ethylene copolymer is modified with an acid, an anhydride, a glycidyl functionality, or combinations of two or more thereof.