Expanded PFTE membrane and method of making
View Patent ↗A method of making a porous membrane includes, in an exemplary embodiment, mixing together a first fine powder PTFE resin and a second fine powder PTFE resin to form a PTFE resin mixture. The first PTFE resin having a characteristic of forming more and longer fibrils than fibrils formed from the second PTFE resin. The second PTFE resin having a characteristic of forming thicker nodes than nodes formed from the first PTFE resin. The method also includes forming a preform from the PTFE resin mixture, extruding the preform into a tape, passing the tape through a plurality of opposing calender rolls to form a calendered tape having a thickness of about 380 μm to about 1200 μm, and stretching the calendered tape in the transverse direction to form a porous membrane having a plurality of nodes and fibrils and having a thickness of at least about 100 μm.
1. A method of making a porous membrane, said method comprising:
mixing together about 60% to about 68% by weight of a first fine powder PTFE resin, about 15% to about 17% by weight of a second fine powder PTFE resin, and about 15% to about 25% by weight of the hydrocarbon lubricating aid, the weight percent based on the total weight of the PTFE resin mixture, to form a PTFE resin mixture, the first PTFE resin having a characteristic of forming more and longer fibrils than fibrils formed from the second PTFE resin, the second PTFE resin having a characteristic of forming thicker nodes than nodes formed from the first PTFE resin;
forming a preform from the PTFE resin mixture;
extruding the preform into a tape;
passing the tape through a plurality of opposing calender rolls to form a calendered tape having a thickness of about 380 μm to about 1200 μm; and
stretching the calendered tape in a transverse direction to form a porous membrane comprising a plurality of nodes and fibrils, the porous membrane having a thickness of about 100 μm to about 380 μm, and a machine direction peel strength of at least about 1.0 pounds-force per inch.
2. A method in accordance with claim 1 , wherein passing the tape through a plurality of opposing calender rolls comprises passing the tape through a plurality of opposing calender rolls at a temperature of about 400° F. to about 550° F.
3. A method in accordance with claim 1 , wherein passing the tape through a plurality of opposing calender rolls comprises passing the tape through a plurality of opposing calender rolls at about 10 to about 25 feet per minute.
4. A method in accordance with claim 1 , wherein stretching the calendered tape comprises stretching the calendered tape in the transverse direction from about 3 to about 15 times and in the machine direction from 0 to about 12 times.
5. A method in accordance with claim 1 , wherein stretching the calendered tape comprises stretching the calendered tape in the transverse direction at a maximum temperature of about 550° F. to about 680° F.
6. A method in accordance with claim 1 , wherein stretching the calendered tape comprises stretching the calendered tape in the transverse direction at a line speed of about 10 to about 60 feet per minute.
7. A porous expanded PTFE article comprising:
an expanded PTFE resin, the PTFE resin comprising about four parts of a first fine powder PTFE resin and about one part of a second fine powder PTFE resin, the first PTFE resin having a characteristic of forming more and longer fibrils than the fibrils formed from the second PTFE resin, the second PTFE resin having a characteristic of forming thicker nodes than nodes formed from the first PTFE resin, said expanded PTFE article comprising a plurality of nodes and fibrils and having a thickness of about 100 μm to about 380 μm and a machine direction peel strength of at least about 1.0 pounds-force per inch.
8. A porous expanded PTFE article in accordance with claim 7 , wherein said expanded PTFE article comprising a unit weight of at least about 1.0 ounce per square yard.
9. A porous expanded PTFE article in accordance with claim 7 , wherein said expanded PTFE article stretched in the transverse direction from about 3 to about 15 times and in the machine direction from 0 to about 12 times.
10. A micro-filtration membrane comprising:
an expanded PTFE membrane, the PTFE membrane comprising a first fine powder PTFE resin and a second fine powder PTFE resin, the first PTFE resin having a characteristic of forming more and longer fibrils than fibrils formed from the second PTFE resin, the second PTFE resin having a characteristic of forming thicker nodes than nodes formed from the first PTFE resin, said expanded PTFE membrane comprising a plurality of nodes and fibrils and having a thickness of about 100 μm to about 380 μm, and a machine direction peel strength of at least about 1.0 pounds-force per inch,
said expanded PTFE membrane comprises said first PTFE resin and said second PTFE in ratio of about 4 parts of said first PTFE resin to about one part of said second PTFE resin.
11. A micro-filtration membrane in accordance with claim 10 , wherein said expanded PTFE membrane comprising a unit weight of at least about 1.0 ounce per square yard.
12. A micro-filtration membrane in accordance with claim 10 , wherein said expanded PTFE membrane stretched in the transverse direction from about 3 to about 15 times and in the machine direction from 0 to about 12 times.