Production of ester-based fuels such as biodiesel from renewable starting materials
Production of ester-based fuels such as biodiesel or jet fuel from renewable starting materials such as lignocellulosic material or algae is disclosed. Pulping and saccharification of the renewable starting materials produces carboxylic acids such as fatty acids or rosin acids, which are esterified via a gas sparged, slurry form of heterogeneous reactive distillation to yield ester-based fuels.
1. A process for the production of biodiesel ester based fuel from a concentration of algae comprising about 15% by weight solids, the process comprising:
i) comminution of the concentration by solid or liquid shearing;
ii) production of an organic layer comprising 30-40% fatty acid soaps via alkali lysing of the concentration;
iii) collection of the organic layer via settling and skimming;
iv) acidulation of the organic layer to produce free fatty acids;
v) collection of the free fatty acids via settling and skimming;
vi) addition of a C1-C8 alcohol to the fatty acid and heterogeneous esterification; and
vii) refining of the resulting ester to produce an ester-based fuel.
2. The process according to claim 1 , wherein following production of the organic layer residual material is further processed in fermentation and purification steps to yield ethanol.
3. The process according to claim 2 , wherein the ethanol produced from the residual material makes up a substantial amount of the C1-C8 alcohol of step vi.
4. The process according to claim 1 , wherein the organic layer is processed to contain between about 0.1% and about 30% by weight triglyceride and glycerin and greater than about 70% free fatty acid.
5. The process according to claim 1 , wherein the C1-C8 alcohol of step vi is selected from methanol, ethanol, propanol, butanol, and mixtures thereof.
6. The process according to claim 1 , wherein the esterification of step vi occurs via a gas sparged, slurry form of heterogeneous reactive distillation in a reaction chamber.
7. The process according to claim 6 , wherein the gas sparged, slurry form of heterogeneous reactive distillation includes free particulate acidic ion exchange resin catalysts to catalyze esterification.
8. The process according to claim 7 , wherein the reaction chamber of step vi comprises a vertical column reactor provided with a plurality of esterification trays mounted one above another, wherein the esterification trays are adapted to allow liquid phase to pass down the column reactor and vapor phase to pass up the column reactor.
9. The process according to claim 1 , wherein the alcohol esterification of step vi occurs via a continuous reactive process.
10. The process according to claim 9 , wherein the reaction chamber for step vi comprises a vertical column reactor provided with structured packing wherein the packing is adapted to support catalyst at one or more points in the reactor and to allow liquid phase to pass down and vapor phase to pass up the column reactor.
11. The process according to claim 1 , wherein the yield of ester is greater than about 1.5% or greater than about 2% by weight of the concentration of algae.
12. The process according to claim 1 , wherein the refining step v yields an ester-based fuel with low glycerin, soap, alcohol, and water content.
13. The process according to claim 12 , wherein the glycerin, soap, alcohol, and water content are less than 0.5% by weight.