Granted Patent B2

US 8,153,541 · App. 12/174,982 · Granted Apr 10, 2012

Abstract

Claims (45)

1. A ceramic article comprising:

ceramic particles;

ceramic fibers having an aspect ratio of greater than or equal to 10:1; and

an inorganic binder comprising silica;

wherein greater than 90 out of 100 ceramic fibers are randomly oriented in three dimensions in said ceramic article,

wherein greater than 85 out of 100 ceramic fibers are spaced at least one ceramic fiber diameter away from an adjacent ceramic fiber,

wherein said ceramic article has a consistent density of from 0.9 to 1.1 g/cm 3 in x-, y-, and z-dimensions and has a uniform strength in three dimensions as measured in accordance with ASTM C1424, and

wherein said ceramic particles, said ceramic fibers, and said inorganic binder are extruded through a multi-screw extruder having at least three intermeshing screws prior to firing.

2. A ceramic article as set forth in claim 1 wherein said ceramic fibers are present in said ceramic article in an amount of from 3 to 15 parts by volume based on 100 parts by volume of said ceramic article.

3. A ceramic article as set forth in claim 2 wherein said ceramic fibers comprise an element from period 2, 3, 4, or 5 of the periodic table of the elements.

4. A ceramic article as set forth in claim 2 wherein said ceramic fibers comprise aluminum, silicon, oxygen, zirconium, or carbon.

5. A ceramic article as set forth in claim 1 wherein said ceramic fibers are selected from the group of alumina-silica fibers, alumina-silica-zirconia fibers, carbon-graphite fibers, and combinations thereof.

6. A ceramic article as set forth in claim 2 wherein said ceramic particles are present in said ceramic article in an amount of from 15 to 30 parts by volume based on 100 parts by volume of said ceramic article.

7. A ceramic article as set forth in claim 1 wherein said ceramic particles are present in said ceramic article in an amount of from 15 to 30 parts by volume based on 100 parts by volume of said ceramic article.

8. A ceramic article as set forth in claim 7 wherein said ceramic particles comprise an element from period 2, 3, or 4 of the periodic table of the elements.

9. A ceramic article as set forth in claim 7 wherein said ceramic particles comprise silicon, oxygen, carbon, aluminum, or boron.

10. A ceramic article as set forth in claim 1 wherein said ceramic particles are selected from the group of silicon carbide, alumina, boron carbide, and combinations thereof.

11. A ceramic article as set forth in claim 1 wherein said inorganic binder is present in said ceramic article in an amount of from 2 to 5 parts by weight based on 100 parts by weight of said ceramic article.

12. A ceramic article as set forth in claim 1 further comprising an additive component.

13. A ceramic article as set forth in claim 12 wherein said additive component comprises a filler.

14. A method of forming a ceramic article comprising the steps of:

providing a composition comprising;

ceramic particles;

ceramic fibers having an aspect ratio of greater than or equal to 10:1;

an organic binder comprising a cellulose ether;

an inorganic binder comprising silica; and

water;

extruding the composition through a multi-screw extruder having at least three intermeshing screws to form an extrudate; and

heating the extrudate to form the ceramic article

wherein greater than 90 out of 100 ceramic fibers are randomly oriented in three dimensions in the ceramic article,

wherein greater than 85 out of 100 ceramic fibers are spaced at least one ceramic fiber diameter away from an adjacent ceramic fiber, and

wherein the ceramic article has a consistent density of from 0.9 to 1.1 g/cm 3 in x-, y-, and z-dimensions and has a uniform strength in three dimensions as measured in accordance with ASTM C1424.

15. A method as set forth in claim 14 wherein said step of extruding is further defined as rotating at least three intermeshing screws at from 20 to 1,200 rpm.

16. A method as set forth in claim 14 wherein the multi-screw extruder includes from 3 to 24 screws formed in a ring configuration.

17. A method as set forth in claim 16 wherein the multi-screw extruder has from 2 to 8mixing zones.

18. A method as set forth in claim 17 wherein the multi-screw extruder has an L/D ratio of 18 to 56.

19. A method as set forth in claim 14 wherein said step of providing is further defined as dry-mixing the ceramic particles, the ceramic fibers, the organic binder comprising the cellulose ether, and the inorganic binder comprising the silica, to form the composition.

20. A method as set forth in claim 14 further comprising the step of conveying the composition to the multi-screw extruder.

21. A method as set forth in claim 20 wherein said step of conveying includes the step of agitating the composition.

22. A method as set forth in claim 21 wherein said step of conveying includes the step of feeding the composition to the multi-screw extruder at a flow rate of from 36 to 136 kg/hr.

23. A method as set forth in claim 14 wherein said step of extruding and said step of heating are simultaneous.

24. A method as set forth in claim 14 wherein the cellulose ether is selected from the group of methyl cellulose, hydroxypropylmethylcellulose, hydroxybutylmethylcellulose, and combinations thereof.

25. A method as set forth in claim 14 wherein the composition further comprises an additive component.

26. A method as set forth in claim 25 wherein the additive component comprises a filler.

27. A method as set forth in claim 26 wherein the filler is selected from the group of walnut shell flour, cellulose fiber, air, and combinations thereof.

Assignments (15)