Process for producing membrane-electrode assembly for polymer electrolyte fuel cells
View Patent ↗To provide a process for producing a membrane-electrode assembly for polymer electrolyte fuel cells, which has a high output voltage in a wide range of current densities and is excellent in durability against a humidity change. With respect to the process for producing a membrane-electrode assembly 10 comprising a first electrode 20 comprising a catalyst layer 12 and a gas diffusion layer 14 , a second electrode 30 comprising a catalyst layer 12 and a gas diffusion layer 14 and the polymer electrolyte membrane 40 disposed between the catalyst layers 12 of the respective electrodes, the catalyst layer 12 is formed in such a manner that after forming a coating solution layer by applying a coating solution containing an electrode catalyst and an ion exchange resin on a substrate film, the gas diffusion layer 14 is put on the coating solution layer, and then, the coating solution layer is dried in such a state.
1. A process for producing a membrane-electrode assembly for polymer electrolyte fuel cells, which comprises a first electrode comprising a catalyst layer and a gas diffusion layer, a second electrode comprising a catalyst layer and a gas diffusion layer, and a polymer electrolyte membrane disposed between the catalyst layer of the first electrode and the catalyst layer of the second electrode, said process comprising the following steps (a) to (c) and (g):
(a) a step of applying a coating solution containing an electrode catalyst and an ion exchange resin on a substrate film to form a coating solution layer,
(b) a step of putting a gas diffusion layer on the coating solution layer formed in the step (a), followed by drying the coating solution layer to form a catalyst layer,
(c) a step of removing the substrate film from the catalyst layer formed in the step (b) to obtain the first electrode, and
(g) a step of heat-bonding the first electrode, the second electrode and the polymer electrolyte membrane, to have the catalyst layer and the polymer electrolyte membrane contacted to each other.
2. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 1 , which further contains the following steps (d) to (f):
(d) a step of applying a coating solution containing an electrode catalyst and an ion exchange resin on a substrate film to form a coating solution layer,
(e) a step of putting a gas diffusion layer on the coating solution layer formed in the step (d), followed by drying the coating solution layer to form a catalyst layer, and
(f) a step of removing the substrate film from the catalyst layer formed in the step (e) to obtain the second electrode.
3. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 1 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the catalyst layer is from 0.01 to 0.5 mg/cm 2 .
4. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 2 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the catalyst layer is from 0.01 to 0.5 mg/cm 2 .
5. A process for producing a membrane-electrode assembly for polymer electrolyte fuel cells, which comprises a first electrode comprising a release layer, a catalyst layer and a gas diffusion layer in this order, a second electrode comprising a catalyst layer and a gas diffusion layer, and a polymer electrolyte membrane disposed between the release layer of the first electrode and the catalyst layer of the second electrode, the process comprising the following steps (a′), (b), (c) and (g):
(a′) a step of applying a coating solution containing an electrode catalyst and an ion exchange resin on a release layer formed on the surface of a substrate film, to form a coating solution layer,
(b) a step of putting a gas diffusion layer on the coating solution layer formed in the step (a′), followed by drying the coating solution layer to form a catalyst layer,
(c) a step of removing the substrate film from the release layer after the step (b), to obtain the first electrode, and
(g) a step of heat-bonding the first electrode, the second electrode and the polymer electrolyte membrane, to have the release layer of the first electrode and the polymer electrolyte membrane contacted to each other and to have the catalyst layer of the second electrode and the polymer electrolyte membrane contacted to each other.
6. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 5 , wherein the release layer contains an ion exchange resin, and the thickness of the release layer is from 0.1 to 5 μm.
7. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 5 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the catalyst layer is from 0.01 to 0.5 mg/cm 2 .
8. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 6 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the catalyst layer is from 0.01 to 0.5 mg/cm 2 .
9. A process for producing a membrane-electrode assembly for polymer electrolyte fuel cells, which comprises a first electrode comprising a release layer, a catalyst layer and a gas diffusion layer in this order, a second electrode comprising a release layer, a catalyst layer and a gas diffusion layer in this order, and a polymer electrolyte membrane disposed between the release layer of the first electrode and the release layer of the second electrode, the process comprising the following steps (a′), (b), (c), (d′), (e), (f) and (g):
(a′) a step of applying a coating solution containing an electrode catalyst and an ion exchange resin on a release layer formed on the surface of a substrate film, to form a coating solution layer,
(b) a step of putting a gas diffusion layer on the coating solution layer formed in the step (a′), followed by drying the coating solution layer to form a catalyst layer,
(c) a step of removing the substrate film from the release layer after the step (b), to obtain the first electrode,
(d′) a step of applying a coating solution containing an electrode catalyst and an ion exchange resin on a release layer formed on the surface of a substrate film, to form a coating solution layer,
(e) a step of putting a gas diffusion layer on the coating solution layer formed in the step (d′), followed by drying the coating solution layer to form a catalyst layer,
(f) a step of removing the substrate film from the release layer after the step (e), to obtain the second electrode, and
(g) a step of heat-bonding the first electrode, the second electrode and the polymer electrolyte membrane, to have the catalyst layer and the polymer electrolyte membrane contacted to each other.
10. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 9 , wherein the release layer contains an ion exchange resin, and the thickness of the release layer is from 0.1 to 5 μm.
11. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 9 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the catalyst layer is from 0.01 to 0.5 mg/cm 2 .
12. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 10 , wherein the electrode catalyst contains a noble metal, and the amount of the noble metal per unit area of the above catalyst layer is from 0.01 to 0.5 mg/cm 2 .
13. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 3 , wherein the noble metal is platinum.
14. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 4 , wherein the noble metal is platinum.
15. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 7 , wherein the noble metal is platinum.
16. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 8 , wherein the noble metal is platinum.
17. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 11 , wherein the noble metal is platinum.
18. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 12 , wherein the noble metal is platinum.
19. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 6 , wherein the ion exchange resin of the release layer comprises a fluorinated ion exchange resin.
20. The process for producing a membrane-electrode assembly for polymer electrolyte fuel cells according to claim 10 , wherein the ion exchange resin of the release layer comprises a fluorinated ion exchange resin.