Hybrid process using ion exchange resins in the selective recovery of nickel and cobalt from leaching effluents
The present invention is directed to a hybrid process using ion exchange resins in the selective recovery of nickel and cobalt of leaching effluents that is comprised of the steps of processing ( 1 ) the laterite ore (M), which is then treated through leaching ( 2 ) (either atmospheric or under pressure), considering solutions from the solid-liquid separation step of existing plants already in operation ( 2 ) as well, in a way that the downstream process comprises an ion exchange hybrid circuit, wherein the first ion exchange step ( 3 ) with resins (Re) exhibits specific selectivity conditions for the removal of iron, aluminum and copper and an increased pH, and the second ion exchange step ( 4 ) allows the removal of nickel and cobalt.
1. A hybrid process using ion exchange resins in selective recovery of nickel and cobalt from leaching effluents comprising processing laterite ore being later treated for leaching, said hybrid process including a cationic or chelating resin hybrid circuit consisting of:
a first step of ion exchange with the resins fed with a first effluent having a pH value of no more than 1 comprising impurities including iron, aluminum and copper, the resins exhibiting specific selectivity conditions for absorbing iron, aluminum and copper and neutralizing the pH while rejecting nickel and cobalt so that the pH of the effluent from the first step is raised to a value higher than 1,
a second step of ion exchange, in series with the first step of ion exchange with the resins fed, with effluent of the first step, the resins of the second step absorbing nickel and cobalt; and
eluting the resins of the second step having absorbed nickel and cobalt ions to form an eluate comprising nickel and cobalt; and separating the nickel and cobalt in the eluate through solvent extraction and recovering metals in solution,
wherein the leaching is one of atmospheric leaching or pressure leaching.
2. The hybrid process according to claim 1 , wherein a neutralization of the leached ore is eliminated.
3. The hybrid process according to claim 1 or claim 2 , wherein the first effluent that feeds the first step is acidic, the resins, under the conditions of the first step, adsorbs iron, copper and aluminum under highly acidic conditions, contains mobile alkali metal ions that are exchanged by Fe 3+ , Al 3+ and Cu 2+ ions, and increases the pH.
4. The hybrid process according to claim 3 , wherein an intermediate neutralization step with a strong basic reagent takes place between the first and second ion exchange steps, and the pH of the effluent that feeds the second step of adsorption of nickel and cobalt is increased.
5. The hybrid process according to claim 4 , wherein, in the second step, the resins contains a functional group comprising an iminodiacetic group, and nickel and cobalt are selectively recovered when the second step is complete.
6. The hybrid process according to claim 1 , wherein the eluting step includes regenerating the eluted resins with inorganic solutions and returning the regenerated resins to the second step.
7. The method of claim 1 , wherein the laterite ore is treated in existing plants.
8. The hybrid process according to claim 1 , wherein the resins of the first step comprise cationic resins and wherein the resins of the second step comprise chelating resins.
9. The hybrid processing according to claim 1 , wherein the resins of the first step comprise cationic resins whose mobile ions are alkali metals in a disodium form conditioning.
10. The hybrid processing according to claim 9 , wherein the cationic resins are adapted to eliminate iron, copper and aluminum.
11. The hybrid processing according to claim 1 , wherein the resins of the second step comprise chelating resins.
12. The hybrid processing according to claim 11 , wherein the resins of the first step are adapted to eliminate iron, copper and aluminum and wherein the chelating resins are adapted to recover the nickel and cobalt from the effluent of the first step at a pH greater than 1.
13. The hybrid processing according to claim 11 , wherein the chelating resins comprise an iminodiacetic acid functional group.
14. The hybrid processing according to claim 1 , wherein the resins of the first circuit are the same type as the resins in the second circuit.
15. The hybrid processing according to claim 1 , wherein the step of eluting includes eluting the resins of the second step with one of hydrochloric acid, sulfuric acid, and an ammonium salt to separate the nickel and cobalt from the resins of the second step.
16. The hybrid processing according to claim 1 , wherein the eluting step includes regenerating the eluted resins and returning the regenerated resins to the second step.