Metal nanodisks using bicellar templates
View Patent ↗Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.
1. A metal nanodisk, comprising:
a hub-like metal structure approximately at a center point of an approximately circular metal nanodisk; and
a dendritic metal nanosheet extending radially out from the hub-like metal structure.
2. The metal nanodisk of claim 1 , further comprising a rim-like metal structure circumscribing the dendritic metal nanosheet.
3. The metal nanodisk of claim 1 , wherein the dendritic metal nanosheet is substantially uniform in thickness.
4. The metal nanodisk of claim 1 , wherein the dendritic metal nanosheet is less than approximately 10 nm thick.
5. The metal nanodisk of claim 1 , wherein a diametric dimension of the metal nanodisk is less than approximately 1000 nm.
6. The metal nanodisk of claim 5 , wherein the diametric dimension of the metal nanodisk is greater than approximately 100 nm and less than approximately 1000 nm.
7. A method for making metal nanodisks, comprising:
combining an anionic surfactant and a cationic surfactant to form a solution of template bicelles;
combining the solution of template bicelles and a metal salt to form a reaction solution;
adding a reducing agent to the reaction solution; and
reacting the metal salt and the reducing agent to deposit metal within the template bicelles to form the metal nanodisks, wherein the metal nanodisks each comprise a hub-like metal structure approximately at a center point of an approximately circular metal nanodisk and a dendritic metal nanosheet extending radially out from the hub-like metal structure, and optionally a rim-like metal structure circumscribing the dendritic metal nanosheet.
8. The method of claim 7 , further comprising removing the template bicelles from the metal nanodisks.
9. The method of claim 7 , wherein the anionic surfactant and the cationic surfactant form a catanionic surfactant.
10. The method of claim 7 , wherein the anionic surfactant is a salt of perfluorooctanoate or an alkyl sulfate salt.
11. The method of claim 7 , wherein the cationic surfactant is selected from the group consisting of a cetylpyridinium salt, a benzalkonium salt, a benzethonium salt, polyethoxylated tallow amine, a cetyltrialkylammonium salt, a (1-octyl)trialkylammonium salt, a (1-decyl)trialkylammonium salt, a dodecyltrialkylammonium salt, a tetradecyltrialkylammonium salt, and an octadecyltrialkylammonium salt, wherein alkyl is methyl or ethyl.
12. The method of claim 7 , wherein the reducing agent is selected from the group consisting of ascorbic acid and its salts, oxalic acid and its salts, malic acid and its salts, citric acid and its salts, ethylenediaminetetraacetic acid and its salts, triethanolamine, triethylamine, and nitrite.
13. The method of claim 7 , wherein the metal salt is a selected from the group consisting of salts and complexes of Pt(II) and salts and complexes of Pt(IV).
14. The method of claim 7 , wherein the metal salt is dissolved in a solvent to form a metal salt solution before combining with the solution of template bicelles.
15. The method of claim 14 , wherein the metal salt solution comprises an aged platinum solution.
16. The method of claim 7 , further comprising adjusting the temperature of the reaction solution to control the forming of the rim-like metal structure.