Methods of fabricating polycrystalline diamond and polycrystalline diamond compacts with a carbonate material
View Patent ↗Embodiments relate to polycrystalline diamond (“PCD”), polycrystalline diamond compacts (“PDCs”) having a PCD table comprising such PCD, methods of fabricating such PCD and PDCs, and applications. In an embodiment, a method includes sintering diamond particles in the presence of a carbonate material to form PCD. The carbonate material includes at least one alkali metal carbonate. In an embodiment, PCD includes a plurality of bonded diamond grains defining a matrix. An interstitial constituent may be dispersed through the matrix. The interstitial constituent includes at least one alkali metal carbonate, at least one alkali metal oxide, or both. In an embodiment, a PDC includes a substrate bonded to a PCD table. The PCD table may be formed from any of the disclosed embodiments of PCD.
1. A method of fabricating a polycrystalline diamond compact, comprising:
assembling a plurality of diamond particles with a substrate; and
sintering at least a portion of the plurality of diamond particles with a carbonate material at a temperature at or near a eutectic temperature of the carbonate material to form at least a portion of a polycrystalline diamond table of the polycrystalline diamond compact, wherein the carbonate material comprises at least one alkali metal carbonate and at least one melting point depressant in proportions at or near a eutectic composition for a chemical system of the at least one alkali metal carbonate and the at least one melting point depressant.
2. The method of claim 1 wherein the at least one melting point depressant comprises at least a second alkali metal carbonate.
3. The method of claim 1
further comprising selecting the at least one alkali metal carbonate to be a first alkali metal carbonate and the at least one melting point depressant to include at least a second alkali metal carbonate.
4. The method of claim 1
further comprising selecting the at least one alkali metal carbonate to be lithium carbonate and the at least one melting point depressant to include sodium carbonate and potassium carbonate.
5. The method of claim 1 :
wherein sintering at least a portion of the plurality diamond particles with a carbonate material to form at least a portion of a polycrystalline diamond table of the polycrystalline diamond compact comprises sintering the at least a portion of the plurality of diamond particles at a first temperature to form the at least a portion of the polycrystalline diamond table;
further comprising heating the at least a portion of the polycrystalline diamond table and the substrate at a second temperature that is greater than that of the first temperature.
6. The method of claim 5 wherein heating the polycrystalline diamond table and the substrate at a second temperature that is greater than that of the first temperature effects infiltrating a portion of the polycrystalline diamond table with a constituent from the substrate.
7. The method of claim 1 , further comprising converting at least a portion of the carbonate material during the act of sintering to at least one sintering by-product including at least one of the following: an alkali metal oxide or a non-stoichiometric alkali metal carbonate.
8. The method of claim 1 , further comprising, prior to the act of sintering, mixing, with the plurality of diamond particles, first particles comprising the at least one alkali metal carbonate and second particles comprising the at least one melting point depressant.
9. The method of claim 1 , further comprising, prior to the act of sintering, positioning a first layer comprising the carbonate material adjacent to a second layer comprising the plurality of diamond particles.
10. The method of claim 1 wherein sintering at least a portion of the plurality of diamond particles with a carbonate material to form at least a portion of a polycrystalline diamond table of the polycrystalline diamond compact comprises subjecting the plurality of diamond particles and the carbonate material to a temperature below about 2250° Celsius and a pressure below about 80 kilobar.
11. A method of forming a polycrystalline diamond compact, comprising:
providing an at least partially leached polycrystalline diamond table including a plurality of interstitial regions; and
after the act of providing the at least partially leached polycrystalline diamond table, infiltrating at least a portion of the interstitial regions of the at least partially leached polycrystalline diamond table with a carbonate material.
12. The method of claim 11 wherein providing an at least partially leached polycrystalline diamond table including a plurality of interstitial regions comprises disposing the at least partially leached polycrystalline diamond table between a substrate and a layer of the carbonate material.
13. The method of claim 11 wherein the carbonate material comprises at least alkali metal carbonate.
14. The method of claim 1 wherein sintering at least a portion of the plurality of diamond particles in the presence of a carbonate material to form at least a portion of a polycrystalline diamond table of the polycrystalline diamond compact effects infiltration of a metal-solvent catalyst from the substrate into a portion of the plurality of diamond particles adjacent to the substrate.
15. The method of claim 11 wherein the carbonate material comprises two or more alkali metal carbonates in proportions at or near a eutectic composition for a chemical system of the two or more alkali metal carbonates.
16. The method of claim 11 , further comprising attaching a cemented carbide substrate to the at least partially leached polycrystalline diamond table.
17. The method of claim 11 wherein the at least partially leached polycrystalline diamond table is disposed between a layer of the carbonate material and a substrate.
18. The method of claim 11 wherein the at least partially leached polycrystalline diamond table is disposed adjacent to a layer of the carbonate material and a substrate.
19. The method of claim 11 wherein the at least partially leached polycrystalline diamond table is attached to a substrate prior to the act of infiltrating.