Methods of positioning and/or orienting nanostructures
View Patent ↗Methods of positioning and orienting nanostructures, and particularly nanowires, on surfaces for subsequent use or integration. The methods utilize mask based processes alone or in combination with flow based alignment of the nanostructures to provide oriented and positioned nanostructures on surfaces. Also provided are populations of positioned and/or oriented nanostructures, devices that include populations of positioned and/or oriented nanostructures, systems for positioning and/or orienting nanostructures, and related devices, systems and methods.
1. A method of making a nanowire based device, comprising:
depositing a plurality of nanowires on at least a first region of a surface of a substrate; and
forming at least first and second electrical contacts on the first region of the surface of the substrate such that at least a first nanowire of the plurality of nanowires is positioned in contact with both the first and second electrical contacts, wherein the plurality of nanowires are made from a material selected from the group comprising Si, Ge, Sn, Se, Te, P, Si—C, Si—Ge, Si—Sn, Ge—Sn, SiC, AlN/AlP/AlAs/AlSb, GaN/GaP/GaAs/GaSb, InN/InP/InAs/InSb, AlN/AlP/AlAs/AlSb, GaN/GaP/GaAs/GaSb, InN/InP/InAs/InSb, ZnO/ZnS/ZnSe/ZnTe, CdS/CdSe/CdTe, HgS/HgSe/HgTe, BeS/BeSe/BeTe/MgS/MgSe, GeS, GeSe, GeTe, SnS, SnSe, SnTe, PbO, PbS, PbSe, PbTe, CuF, CuCl, CuBr, CuI, AgF, AgCl, AgBr, AgI, BeSiN2, CaCN2, ZnGeP2, CdSnAs2, ZnSnSb2, CuGeP3, CuSi2P3, (Cu, Ag)(Al, Ga, In, Tl, Fe)(S, Se, Te)2, Si3N4, Ge3N4, Al2O3, (Al, Ga, In)2(S, Se, Te)3, or Al2CO or alloys thereof, wherein the first and second electrical contacts are separated from each other on the first surface of the substrate by a distance that is less than 50% of an average length of the plurality of nanowires.
2. The method of claim 1 , wherein the plurality of nanowires are oriented substantially longitudinally in a first direction on the first region of the surface of the substrate.
3. The method of claim 1 , wherein the plurality of nanowires are randomly oriented.
4. The method of claim 1 , wherein the first and second electrical contacts are separated from each other by a distance that is less than 10 μm.
5. The method of claim 1 , wherein the first and second electrical contacts are separated from each other by a distance that is less than 5 μm.
6. The method of claim 1 , wherein said depositing comprises flowing the plurality of nanowires in a fluid containing the nanowires over the surface of the substrate, and permitting the nanowires in the fluid to become immobilized onto the surface.
7. The method of claim 6 , further comprising providing the first surface of the substrate as a functionalized first surface that is capable of binding the nanowires from the fluid.
8. The method of claim 7 , wherein the step of providing the first surface of the substrate as a functionalized first surface comprises providing functional groups on only a portion of the first surface.
9. The method of claim 8 , wherein the functional groups comprise protectable or deprotectable functional groups.
10. The method of claim 1 , further comprising immobilizing said plurality of nanowires in said first region of the surface of the substrate via ionic interaction with said surface.
11. The method of claim 1 , further comprising immobilizing said plurality of nanowires in said first region of the surface of the substrate via covalent interaction with said surface.
12. The method of claim 1 , further comprising immobilizing said plurality of nanowires in said first region of the surface of the substrate via hydrophobic or hydrophilic interaction with said surface.
13. The method of claim 1 , further comprising immobilizing said plurality of nanowires in said first region of the surface of the substrate via electrostatic interaction with said surface.
14. The method of claim 1 , further comprising immobilizing said plurality of nanowires in said first region of the surface of the substrate via magnetic interaction with said surface.
15. The method of claim 1 , wherein the first and second electrical contacts are formed on the surface of the substrate before depositing the plurality of nanowires on the surface.
16. The method of claim 1 , wherein the first and second electrical contacts are formed on the surface of the substrate after the plurality of nanowires have been deposited on the surface.
17. The method of claim 1 , wherein more than two of said plurality of nanowires are positioned in contact with both the first and second electrical contacts.
18. The method of claim 1 , wherein the plurality of nanowires are made from silicon.
19. The method of claim 1 , wherein the plurality of nanowires are made from germanium.
20. A method of making a nanowire based device, comprising:
depositing a plurality of nanowires on at least a first region of a surface of a substrate; and
forming at least first and second electrical contacts on the first region of the surface of the substrate such that at least a first nanowire of the plurality of nanowires is positioned in contact with both the first and second electrical contacts, wherein the plurality of nanowires are made from a material selected from the group comprising Si, Ge, Sn, Se, Te, P, Si—C, Si—Ge, Si—Sn, Ge—Sn, SiC, AlN/AlP/AlAs/AlSb, GaN/GaP/GaAs/GaSb, InN/InP/InAs/InSb, AlN/AlP/AlAs/AlSb, GaN/GaP/GaAs/GaSb, InN/InP/InAs/InSb, ZnO/ZnS/ZnSe/ZnTe, CdS/CdSe/CdTe, HgS/HgSe/HgTe, BeS/BeSe/BeTe/MgS/MgSe, GeS, GeSe, GeTe, SnS, SnSe, SnTe, PbO, PbS, PbSe, PbTe, CuF, CuCl, CuBr, CuI, AgF, AgCl, AgBr, AgI, BeSiN2, CaCN2, ZnGeP2, CdSnAs2, ZnSnSb2, CuGeP3, CuSi2P3, (Cu, Ag)(Al, Ga, In, Tl, Fe)(S, Se, Te)2, Si3N4, Ge3N4, Al2O3, (Al, Ga, In)2(S, Se, Te)3, or Al2CO or alloys thereof, wherein the first and second electrical contacts are separated from each other on the first surface of the substrate by a distance that is less than 50% of an average length of the plurality of nanowires; and
disposing third and fourth electrical contacts in a separate discrete region of the surface of the substrate such that at least one nanowire from the plurality of nanowires bridges and connects said at least third and fourth electrical contacts.