Two part crash durable epoxy adhesives
View Patent ↗Two-component epoxy-based structural adhesives are disclosed which exhibit excellent impact resistance, even when cured at approximately room temperature. The adhesives include an epoxy resin component which includes an epoxy resin and a reactive tougher. The adhesives also include a hardener component, which includes from 15 to 50 weight percent of an amine-terminated polyether, from 4 to 40 weight percent of an amine terminated rubber having a glass transition temperature of −40° C. or below, and from 10 to 30 weight percent of an amine-terminated polyamide having a melting temperature of no greater than 50° C.
1. A two-component epoxy adhesive including an epoxy resin component A and a hardener component B, wherein:
the epoxy resin component A comprises at least one epoxy resin and the hardener component B comprises
B-1) from 15 to 35 weight percent of a primary or secondary amine-terminated polyether;
B-2) from 5 to 35 weight percent of a primary or secondary amine-terminated rubber having a glass transition temperature of −40° C. or below; and
B-3) from 10 to 20 weight percent of a primary or secondary amine-terminated polyamide having a melting temperature of no greater than 50° C.,
either component A or component B, or both contains at least one elastomeric toughener having blocked or capped isocyanate groups, and the epoxy adhesive contains at least one epoxy curing catalyst.
2. The two-component epoxy adhesive of claim 1 , wherein the hardener component B includes from 3 to 15 wt. % of a tertiary amine catalyst.
3. The two-component epoxy adhesive of claim 2 , wherein the hardener component B further comprises from 5 to 15 weight percent of at least one additional hardener having at least two primary or secondary amino groups per molecule and an equivalent weight per primary or secondary amino group of not more than 150.
4. The two-component epoxy adhesive of claim 3 , wherein the additional hardener includes a poly(ethyleneimine).
5. The two-component epoxy adhesive of claim 4 , wherein the amine-terminated polyether is a poly(propylene oxide), a block or random copolymer of ethylene oxide and propylene oxide, or a poly(tetrahydrofuran) having a molecular weight of from 200 to 5000 and having from 2 to 4 primary or secondary amino groups per molecule.
6. The two-component adhesive of claim 1 , wherein the amine-terminated polyether is a poly(propylene oxide) having a molecular weight of from 230 to 2200 and from 2 to 3 primary amino groups/molecule.
7. The two-component adhesive of claim 1 , wherein the elastomeric toughener contains one or more soft segments each having a molecular weight of from 1500 to 5000 daltons, and from 1 to 6 blocked or capped isocyanate groups per molecule.
8. The two-component adhesive of claim 7 , wherein the elastomeric toughener contains isocyanate groups that are capped with one or more of a primary aliphatic, cycloaliphatic, heterocyclic or araliphatic amine, a secondary aliphatic, cycloaliphatic, heterocyclic or araliphatic amine, a phenol, aminophenol, allylphenol or polyallylpolyphenol.
9. The two-component adhesive of claim 7 , wherein the elastomeric toughener contains one or more poly(tetrahydrofuran) soft segments each having a molecular weight of from 2200 to 4500 daltons.
10. The two-component adhesive of claim 1 , wherein the amine-terminated polyamide is a reaction product of a dimerized fatty acid and a polyamine.
11. The two-component adhesive of claim 1 , which further contains at least one core-shell rubber.
12. The two-component adhesive of claim 1 , wherein at least one of the epoxy resin component A and the hardener component B further contains at least one adhesion promoter, wetting agent, reactive diluent, filler, pigment or rheology modifier.
13. The two-component adhesive of claim 1 , wherein at least one of the epoxy resin component A and the hardener component B further contains an adduct of an epoxy resin and rubber that has epoxide-functional groups.
14. A method for assembling a first member to a second member, comprising forming a layer of the two-part epoxy composition of claim 1 between the first member and the second member and curing the two-part epoxy composition.
15. The method of claim 14 wherein the epoxy composition is cured at a temperature of 60° C. or less.
16. The method of claim 15 wherein the epoxy composition is cured at a temperature of from 10° C. to 40° C.
17. The two-component epoxy adhesive of claim 1 which cures at a temperature of 23° C. to form a cured adhesive having an impact peel resistance of at least 20 N/mm when measured at 23° C. according to ISO11343 wedge impact method, with testing being performed at an operating speed of 2 m/sec on a 0.75 mm cold rolled steel 14O3 substrate with a bonded area of 30×20 mm and an adhesive layer of 0.2 mm.