IP Library Granted Patent US 7,638,449
Granted Patent B2
US 7,638,449 · App. 12/192,149 · Granted Dec 29, 2009

Optical glass

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Quick Facts
Patent No.
US 7,638,449
App. No.
12/192,149
Granted
Dec 29, 2009
Kind
B2
Abstract

This invention provides an optical glass including, by mass %: 30 to 40% of B 2 O 3 ; 2.5 to 6% of Li 2 O; 10 to 17% of ZnO; 12 to 22% of La 2 O 3 ; 15 to 25% of Gd 2 O 3 ; 0 to 5% of SiO 2 ; 0 to 5% of Bi 2 O 3 ; 0 to 15% of Al 2 O 3 ; 0 to 3% of ZrO 2 ; 0 to 5% of WO 3 ; 0 to 5% of Ta 2 O 5 ; 0 to 3% of TiO 2 ; 0 to 5% of Y 2 O 3 ; and 0 to 5% of MgO+CaO+SrO+BaO.

Claims (35)

1. An optical glass comprising, by mass %:

30 to 40% of B 2 O 3 ;

2.5 to 6% of Li 2 O;

10 to 17% of ZnO;

12 to 22% of La 2 O 3 ;

15 to 25% of Gd 2 O 3 ;

0 to 5% of SiO 2 ;

0 to 5% of Bi 2 O 3 ;

0 to 15% of Al 2 O 3 ;

0 to 3% of ZrO 2 ;

0 to 5% of WO 3 ;

0 to 5% of Ta 2 O 5 ;

0 to 3% of TiO 2 ;

0 to 5% of Y 2 O 3 ; and

0 to 5% of MgO+CaO+SrO+BaO,

wherein an average linear thermal expansion coefficient (α) from 50 to 350° C. is 85×10 −7 /° C. or less.

2. The optical glass according to claim 1 , wherein a refractive index (nd) is 1.65 to 1.72 and an Abbe number (νd) is 47 to 57.

3. The optical glass according to claim 1 , wherein a glass transition temperature (Tg) is 580° C. or less.

4. The optical glass according to claim 1 , wherein a liquid phase temperature (L.T.) is 950° C. or less.

5. The optical glass according to claim 1 , wherein a viscosity (η L.T. ) at the liquid phase temperature (L.T.) is 10 0.5 to 10 2.4 dPa·s.

6. The optical glass according to claim 1 , wherein the B 2 O 3 is present in an amount of from 33.2 to 38%.

7. The optical glass according to claim 1 , wherein the Li 2 O is present in an amount of from 2.9 to 5.4%.

8. The optical glass according to claim 1 , wherein the ZnO is present in an amount of from 10.4 to 15.5%.

9. The optical glass according to claim 1 , wherein the La 2 O 3 is present in an amount of from 14.8 to 20.3%.

10. The optical glass according to claim 1 , wherein Gd 2 O 3 is present in an amount of 16.5 to 22.6%.

11. The optical glass according to claim 1 , wherein SiO 2 is present in an amount of 0.1% or more.

12. The optical glass according to claim 1 , wherein each of BaO, MgO, CaO and SrO or the sum of the contents thereof are present in an amount of 0.1% or more.

13. The optical glass according to claim 1 , wherein each of Na 2 O and K 2 O or a sum of the contents thereof are present in an amount of 0.1% or more.

14. The optical glass according to claim 1 , wherein each of Bi 2 O 3 , ZrO 2 , WO 3 , Ta 2 O 5 , TiO 2 and Y 2 O 3 is present in an amount of 0.1% or more.

15. The optical glass according to claim 1 , wherein Al 2 O 3 is present in an amount of 0.1% or more.

16. The optical glass according to claim 1 , wherein Sb 2 O 3 is present in an amount of 0.1% or more.

17. The optical glass according to claim 1 , wherein none of PbO, As 2 O 3 or TlO 2 are present.

18. The optical glass according to claim 2 , wherein the refractive index (Nd) is from 1.68 to 1.70 and the Abbe number (νd) is 52 to 54.

19. The optical glass according to claim 3 , wherein the glass transition temperature (Tg) is 560° C. or less.

20. The optical glass according to claim 4 , wherein the liquid phase temperature (l.t.) is 870° C. or less.

Assignments (1)
CHANGE OF NAME Recorded Aug 7, 2018
From: ASAHI GLASS COMPANY, LIMITED
To: AGC INC.
Reel/Frame 046730/0786 →