Polycarbonate-polyester blends, methods of manufacture, and articles thereof
View Patent ↗A composition comprises a blend of 50 to 90 wt. % of a polycarbonate copolymer, 10 to 50 wt. % of a polyester wherein the weight percent of the polycarbonate copolymer and the polyester are each based on the total weight of the polycarbonate copolymer and the polyester. A molded sample of the composition having a thickness of 2.5 mm has a luminous transmittance of greater than 80% and a haze of less than 20% when measured in accordance with ASTM D 1003.
1. A composition comprising a blend of:
50 to 90 wt. % of a polycarbonate copolymer comprising
from 20 to 40 mole percent of arylate carbonate units of the formula (1)
wherein R f is a halogen atom, a C 1-10 hydrocarbon or a halogen-substituted C 1-10 hydrocarbon and u is 0 to 4, and
from 60 to 80 mole percent of carbonate units of the formula (3)
wherein R 1 is not of formula (1) and at least 60% of the R 1 groups are divalent C 6-30 aromatic groups; and
10 to 50 wt. % of a polyester comprising units of the formula
wherein T is a divalent residue derived from a C 5 -C 7 cycloaliphatic or C 7 -C 12 aromatic dicarboxylic acid or a chemical equivalent thereof, and D is a divalent residue derived from a C 6 -C 12 aromatic or C 2 -C 12 aliphatic diol or a chemical equivalent thereof, provided that less than 50 mole percent of D is derived from 1,4-cyclohexanedimethanol or a chemical equivalent thereof, wherein
the weight percent of the polycarbonate copolymer and the polyester are each based on the total weight of the polycarbonate copolymer and the polyester, and
a molded sample of the composition having a thickness of 2.5 mm has a luminous transmittance of greater than 80% and a haze of less than 20% when measured in accordance with ASTM D 1003.
2. The composition of claim 1 , wherein a molded sample having a thickness of 2.5 mm has a luminous transmittance of greater than or equal to 85%, and a haze value of less than or equal to 10% when measured in accordance with ASTM D 1003.
3. The composition of claim 1 , wherein a molded sample of the composition has a Notched Izod impact value of more than 30 kJ/m 2 , measured in accordance with ISO 180 at 23° C.
4. The composition of claim 1 , wherein a molded sample of the composition has a Notched Izod impact value of more than 50 kJ/m 2 , measured in accordance with ISO 180 at 23° C.
5. The composition of claim 1 , wherein a molded sample of the composition has a tensile elongation at break of greater than 75% when measured in accordance with ASTM D638.
6. The composition of claim 1 , wherein a molded sample of the composition has a heat deflection temperature is greater than 75° C. at 1.8 MPa in accordance with ISO 75.
7. The composition of claim 1 , wherein the composition has a melt volume rate of greater than 5 cm 3 /10 min in accordance with ISO 1133 at 265° C.
8. The composition of claim 1 , wherein the composition has a melt volume rate of greater than 10 cm 3 /10 min in accordance with ISO 1133 at 265° C.
9. The composition of claim 1 , wherein a molded sample of the composition has a Vicat temperature of greater than 90° C. when measured in accordance with ISO 306.
10. The composition of claim 1 , wherein the optical properties of a molded sample of the composition are substantially unchanged after heat-aging the sample 110° C. for 3 hours.
11. The composition of claim 9 , wherein the optical properties of a molded sample of the composition are substantially unchanged after heat-aging the sample at the Vicat temperature for 3 hours.
12. The composition of claim 1 , wherein the optical properties of a molded sample of the composition of 4 mm thickness does not develop cracks or haze, and the sample does not dissolve or swell when contacted with at least one of oleic acid, suntan lotion, window cleaning agent, or household cleaning agent at a temperature of 23 C. for 48 hours.
13. The composition of claim 1 , wherein a molded sample of the composition of 4 mm thickness retains at least 80% of its initial tensile elongation at break when contacted with at least one of oleic acid, suntan lotion, window cleaning agent, or household cleaning agent when measured in accordance with ISO 527 when at a temperature of 23 C. for 48 hours.
14. The composition of claim 1 , wherein R 1 is derived from a bisphenol of the formula
wherein R a and R b are each independently a halogen atom or a C 1-12 monovalent alkyl, X a is a C 1-18 alkylene, a C 1-18 alkylidene, a C 3-18 cycloalkylidene, or a C 9-18 fused cycloalkylidene-aromatic group, and p and q are each independently 0 to 4.
15. The composition of claim 14 , wherein X a is isopropylidene and p and q are each zero.
16. The composition of claim 1 , wherein T is a residue derived from an aromatic dicarboxylic acid, optionally in combination with a different aliphatic or aromatic dicarboxylic acid or equivalent thereof, and D further comprises a residue derived from a C 2-4 diol and wherein the blend has a Notched Izod impact value greater than 30 kJ/m 2 when measured in accordance with ISO-180 at 23° C.
17. The composition of claim 1 , wherein T is derived from a mixture of terephthalic acid and isophthalic acid and D comprises 20 to 40 mole percent of a residue derived from 1,4-cyclohexanedimethanol based on total moles of D in the polyester.
18. The composition of claim 1 , wherein u is zero.
19. The composition of claim 1 , wherein the arylate unit linkages are para to one another.
20. The composition of claim 1 , wherein the arylate carbonate units are derived from 5-methyl resorcinol, 5-ethyl resorcinol, 5-propyl resorcinol, 5-butyl resorcinol, 5-t-butyl resorcinol, 5-phenyl resorcinol, 5-cumyl resorcinol, 2,4,5,6-tetrafluoro resorcinol, 2,4,5,6-tetrabromo resorcinol, catechol, hydroquinone; 2-methyl hydroquinone, 2-ethyl hydroquinone, 2-propyl hydroquinone, 2-butyl hydroquinone, 2-t-butyl hydroquinone, 2-phenyl hydroquinone, 2-cumyl hydroquinone, 2,5-di-t-butylhydroquinone, 2,3,5-trimethylhydroquinone, 2,3,5,6-tetramethyl hydroquinone, 2,3,5,6-tetra-t-butyl hydroquinone, 2,3,5,6-tetrafluoro hydroquinone, 2,3,5,6-tetrabromo hydroquinone, or a combination comprising at least one of the foregoing compounds.
21. The composition of claim 1 , further comprising an impact modifier, filler, antioxidant, a thermal stabilizer, a light stabilizer, an ultraviolet light absorbing additive, a quencher, a plasticizer, a lubricant, a mold release agent, an antistatic agents, a dye, a pigment, a filler, a light effect additive, a flame retardant, an anti-drip agent, a radiation stabilizer, or a combination comprising at least one of the foregoing additives.
22. The composition of claim 1 , wherein the composition further comprises a polycarbonate in an amount that is more than 0 and less than 25 weight percent.
23. An article comprising the composition of claim 1 .
24. The article of claim 23 , comprising a film, sheet, molded object, or composite.
25. The article of claim 23 , wherein the article is an extruded film or an extruded sheet.
26. The article of claim 23 , wherein the film, sheet, molded object, or composite has at least one layer comprising the composition.
27. A method of forming an article, comprising shaping by extruding, blow molding, injection molding, or gas-assisted injection molding the composition of claim 1 to form the article.
28. A method of forming a composition, comprising blending the components of the composition of claim 1 .
29. A composition comprising a blend of:
50 to 90 wt. % of a polycarbonate copolymer comprising
from 20 to 40 mole percent of carbonate units derived from hydroquinone or 2-methyl hydroquinone, and
from 60 to 80 mole percent of carbonate units derived from bisphenol A; and
10 to 50 wt. % of a polyester comprising units of the formula
wherein T is a residue derived from a mixture of terephthalic acid and isophthalic acid, and D comprises a residue derived from a C 2 -C 4 aliphatic diol or a chemical equivalent thereof, provided that less than 50 mole percent of D is derived from 1,4-cyclohexanedimethanol or a chemical equivalent thereof, wherein
the weight percent of the polycarbonate copolymer and the polyester are each based on the total weight of the polycarbonate copolymer and the polyester, and
a molded sample of the composition having a thickness of 2.5 mm has a luminous transmittance of greater than 80% and a haze of less than 20% when measured in accordance with ASTM D 1003.
30. The composition of claim 29 , wherein D comprises 20 to 40 mole percent of a residue derived from 1,4-cyclohexanedimethanol based on total moles of D units in the polyester.
31. The composition of claim 29 , wherein the composition further comprises a polycarbonate in an amount that is more than 0 and less than 25 weight percent.