Method for producing a stimulation electrode
View Patent ↗A stimulation electrode is provided having an electrically conducting electrode base member which is partially covered with an electrically insulating ceramic layer. The ceramic layer is formed of an oxide and/or an oxynitride of at least one metal of the group of titanium, niobium. tantalum, zirconium, aluminum and silicon. Various methods are provided for production of the stimulation electrode, including methods in which the ceramic layer is formed in situ by a thermal, chemical or electrochemical oxidation or oxynitridation process. The stimulation electrode may be used as a cardiac pacemaker electrode, a neuro-stimulation electrode, or another human implant.
1. A method for producing a stimulation electrode comprising an electrically conducting electrode base member partially covered with an electrically insulating ceramic layer, wherein the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is formed of an oxide and/or an oxynitride of at least one metal selected from the group consisting of titanium, niobium, tantalum, zirconium, aluminum, and silicon, and wherein the electrode base member ( 2 , 2 a , 2 b , 2 c , 2 d , 2 e , 2 f , 2 g ) is further at least partially coated with an electrically conducting layer ( 4 b , 4 c , 4 d , 4 e , 4 f , 4 g ) comprising at least one material selected from the group consisting of titanium nitride, niobium nitride, tantalum nitride, zirconium nitride, aluminum nitride, silicon nitride, vanadium nitride, iridium oxide, and an alloy of platinum and iridium, wherein the iridium portion of the alloy is ≧21 wt. % and the platinum portion of the alloy is about 100 ppm, wherein the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is formed by depositing a metallic layer comprising at least one metal selected from the group consisting of titanium, niobium, tantalum, zirconium, aluminum, and silicon, and the deposited metallic layer is subsequently subjected to a thermal oxidation, electrochemical oxidation, chemical oxidation, or oxynitridation process.
2. The method for producing a stimulation electrode according to claim 1 , wherein the electrode base member ( 2 , 2 a , 2 b , 2 c , 2 d , 2 e , 2 f , 2 g ) is made of titanium, and the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is formed by the deposited titanium layer to titanium oxide.
3. The method for producing a stimulation electrode according to claim 1 , wherein the electrode base member ( 2 , 2 a , 2 b , 2 c , 2 d , 2 e , 2 f , 2 g ) is made of tantalum, and the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is formed by oxidizing the deposited tantalum layer to tantalum oxide by thermal or electrochemical oxidation.
4. The method for producing a stimulation electrode according to claim 1 , wherein the electrically conducting layer is made of titanium nitride and the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is formed by at least partially oxidizing the titanium nitride electrically conducting layer ( 4 a , 4 d , 4 e , 4 f , 4 g ) to titanium oxide by thermal or electrochemical oxidation, and wherein the oxidation includes at least a portion of a layer thickness of the titanium nitride electrically conducting layer ( 4 d , 4 e , 4 f , 4 g ).
5. The method according to claim 1 , wherein the thermal oxidation takes place by a laser.
6. The method according to claim 2 , wherein the thermal oxidation takes place by a laser.
7. The method according to claim 3 , wherein the thermal oxidation takes place by a laser.
8. The method according to claim 4 , wherein the thermal oxidation takes place by a laser.
9. The method according to claim 1 , wherein the ceramic layer ( 3 , 3 a , 3 b , 3 c , 3 d , 3 e , 3 f , 3 g ) is first formed on an entire coated or uncoated surface of the electrode base member ( 2 , 2 a , 2 b , 2 c , 2 d , 2 e , 2 f , 2 g ), and is then partially removed by etching.