ARTICLES PREPARED FROM CERTAIN HYDROGENATED BLOCK COPOLYMERS
The present invention relates to articles prepared from novel anionic block copolymers of mono alkenyl arenes and conjugated dienes, and to blends of such block copolymers with other polymers. The block copolymers are selectively hydrogenated and have the structure C-A-B 2 -A-C or (C-A-B) n X, where the molecular weight of B 2 is twice that of B, n is an integer between 2 and about 30, X is the residue of a coupling agent, and wherein prior to hydrogenation each A block is a mono alkenyl arene homopolymer block, each B block is a polymer block of at least one conjugated diene and each C block is a polymer block of (i) ethylene, (ii) alpha olefins of 3 to 10 carbon atoms; or (iii) monomers of 1,3-butadiene having a vinyl content less than 10 mol percent prior to hydrogenation. The block copolymer may be blended with at least one other polymer selected from the group consisting of olefin polymers, styrene polymers and amorphous resins.
1 . An article comprising at least one hydrogenated block copolymer and, optionally, at least one other component selected from the group consisting of olefin polymers, styrene polymers, tackifying resins and polymer extending oils, wherein said hydrogenated block copolymer is of the structure (C-A-B 2 -A-C) or (C-A-B) n X, where the molecular weight of B 2 is two times that of B, n is an integer between 2 and about 30, X is the residue of a coupling agent, and wherein:
a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block, each B block is a polymer block of at least one conjugated diene and each C block is a polymer block of (i) ethylene, (ii) alpha olefins of 3 to 10 carbon atoms; or (iii) monomers of 1,3-butadiene having a vinyl content less than 10 mol percent prior to hydrogenation;
b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;
c. each A block having a true number average molecular weight between about 5,000 and about 20,000, each B block having a true number average molecular weight between about 20,000 and about 100,000, and each C block having a true number average molecular weight of between about 1,000 and about 7,000; and
d. the total amount of A blocks in the hydrogenated block copolymer is about 20 percent weight to about 35 percent weight and the total amount of C blocks in the hydrogenated block copolymer is about 1 and about 5 weight percent.
2 . The article according to claim 1 wherein said mono alkenyl arene is styrene and said conjugated diene is selected from the group consisting of isoprene and butadiene.
3 . The article according to claim 2 wherein said conjugated diene is butadiene, and wherein about 20 to about 80 mol percent of the condensed butadiene units in block B have 1,2-configuration prior to hydrogenation.
4 . The article according to claim 3 wherein said C block is a block of 1,3-butadiene having 5 to 10 mol percent 1,2-configuration prior to hydrogenation.
5 . The article according to claim 4 wherein the A blocks each have a mol weight of 6,000 to 19,000, the B blocks each have a mol weight of 25,000 to 70,000 and the C blocks each have a mol weight of 1,000 to 5,000.
6 . The article according to claim 5 comprising 100 parts by weight of said hydrogenated block copolymer and about 20 to about 200 parts by weight of a polymer extending oil.
7 . The article according to claim 6 wherein said extending oil is a paraffinic oil.
8 . The article according to claim 5 comprising 100 parts by weight of said hydrogenated block copolymer, about 20 to about 200 parts by weight of an extending oil and about 10 to about 100 parts by weight of an olefin polymer selected from the group consisting of ethylene homopolymers, ethylene/alpha olefin copolymers, propylene homopolymers, propylene/alpha olefin copolymers, high impact polypropylene, and ethylene/vinyl acetate copolymers.
9 . The article according to claim 6 also comprising about 5 to about 50 parts by weight of a tackifying resin.
10 . The article according to claim 6 also comprising about 5 to about 40 parts by weight of a styrene polymer selected from the group consisting of crystal polystyrene, high impact polystyrene, syndiotactic polystyrene and acrylonitrile/butadiene/styrene terpolymer.
11 . A formulated elastomeric composition comprising at least one hydrogenated block copolymer and at least one component selected from the group consisting of fillers, reinforcements, polymer extending oils, tackifying resins, lubricants and polyolefins, wherein said hydrogenated copolymer is of the structure C-A-B 2 -A-C or (C-A-B) n X, where the molecular weight of B 2 is twice that of B, n is an integer between 2 and about 30, X is the residue of a coupling agent, and wherein:
a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block, each B block is a polymer block of at least one conjugated diene and each C block is a polymer block of (i) ethylene, (ii) alpha olefins of 3 to 10 carbon atoms; or (iii) monomers of 1,3-butadiene having a vinyl content less than 10 mol percent prior to hydrogenation;
b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;
c. each A block having a true number average molecular weight between about 5,000 and about 20,000, each B block having a true number average molecular weight between about 20,000 and about 100,000, and each C block having a true number average molecular weight of between about 1,000 and about 7,000; and
d. the total amount of A blocks in the hydrogenated block copolymer is about 20 percent weight to about 35 percent weight and the total amount of C blocks in the hydrogenated block copolymer is about 2 and about 10 weight percent.
12 . The article according to claim 1 wherein the article is in the form of a film, sheet, coating, band, strip, profile, molding, foam, tape, fabric, thread, filament, ribbon, fiber, plurality of fibers or fibrous web.
13 . The article according to claim 1 wherein said article is formed in a process selected from the group consisting of injection molding, over molding, dipping, extrusion, roto molding, slush molding, fiber spinning, film making or foaming.