Commercial Fischer-Tropsch reactor
View Patent ↗A catalytic reaction system comprising: a catalytic reactor fluidly connected with at least two slurry loops, wherein the reactor comprises at least as many reactor product outlets and at least as many slurry return inlets as slurry loops; wherein each slurry loop comprises a separation system comprising a separation system inlet, a separation system product outlet, and a concentrated catalyst slurry outlet; a slurry offtake fluidly connecting the separation system inlet with one of the reactor product outlets; and a slurry return fluidly connecting the separation system outlet with one of the slurry return inlets. The system may comprise at least three slurry loops. The system may comprise at least four slurry loops. A method for converting synthesis gas into liquid hydrocarbons via the catalytic reaction system in also disclosed.
1. A catalytic reaction system comprising:
a catalytic reactor fluidly connected with at least two slurry loops, wherein the catalytic reactor is a substantially cylindrical vessel, wherein the substantially cylindrical vessel comprises openings therethrough providing at least as many reactor product outlets and at least as many slurry return inlets as slurry loops;
wherein each slurry loop comprises a separation system external to the catalytic reactor and comprising at least one separation device for separating concentrated catalyst slurry and gas from liquid product, wherein the at least one separation device comprises a product outlet for removal of liquid product therefrom; a slurry offtake fluidly connecting an inlet of the at least one separation device to one of the reactor product outlets such that, during operation, a portion of a slurry within the catalytic reactor can be introduced directly from the vessel to the separation device; a slurry return fluidly connecting an outlet of the at least one separation device to one of the slurry return inlets; and a separator gas outlet located at or near a top of the at least one separation device, and through which gas is removed therefrom,
wherein at least one separation device of at least one separation system comprises a magnetic dynamic separation vessel comprising a vertical feed conduit fluidly connected with the inlet of the magnetic dynamic separation vessel, and wherein the vertical feed conduit is located at a side of the magnetic dynamic settling vessel and extends at least 70% of the length of the magnetic dynamic separation vessel.
2. The system of claim 1 comprising at least 3 slurry loops.
3. The system of claim 2 comprising at least 4 slurry loops.
4. The system of claim 1 wherein the catalytic reactor is a multi-phase Fischer-Tropsch slurry bubble column reactor.
5. The system of claim 4 wherein the catalytic reactor has a main cylindrical body with an inner diameter greater than 6 feet.
6. The system of claim of 4 wherein the catalytic reactor has a total vertical height greater than 50 feet.
7. The system of claim of 1 wherein the catalytic reactor has exterior walls that can withstand internal pressures in the range of from about 10 atmospheres to about 40 atmospheres.
8. The system of claim of 1 wherein the catalytic reactor further comprises a synthesis gas inlet comprising multiple nozzles.
9. The system of claim 8 wherein additional multiple nozzles are positioned within the lower 50% of the total vertical height (L) of the catalytic reactor.
10. The system of claim 9 wherein the multiple nozzles are positioned within the lower 20% of the total vertical height of the catalytic reactor.
11. The system of claim 1 wherein the reactor product outlets are located within the top 50% of the total vertical height of the catalytic reactor.
12. The system of claim 1 wherein the reactor product outlets have a diameter in the range of from about 4 in. and about 5 ft.
13. The system of claim 1 wherein at least one separation system of the at least two slurry loops comprises 2 or more dynamic settlers.
14. The system of claim 1 wherein each separation system comprises at least one separation device selected from the group consisting of filtration units, magnetic separators, vertical settlers, inclined settlers, dynamic settlers, dynamic magnetic settling vessels and combinations thereof.
15. The system of claim 14 wherein the catalytic reactor has an internal diameter, and wherein the internal diameter of each separation device is greater than about 2 ft. and less than the internal diameter of the catalytic reactor.
16. The system of claim 15 wherein the vertical height of each separation device is less than the slurry loop height of the catalytic reactor.
17. The system of claim 1 wherein the slurry return inlets are positioned within the bottom 50% of the total vertical height of the catalytic reactor.
18. The system of claim 1 wherein the distance between the reactor product outlet and the slurry return inlet of at least one slurry loop is greater than about half the total vertical height of the catalytic reactor.
19. The system of claim 1 wherein the distance between the reactor product outlet and the slurry return inlet of each slurry loop is greater than about one half the total vertical height of the catalytic reactor.
20. The system of claim 1 wherein the reactor product outlets are located in the lower 90% of the total vertical height of the catalytic reactor.
21. The system of claim 1 wherein the at least one magnetic dynamic separation vessel operates via a magnetic field therein.