Reactor having titanium silicate recycling
View Patent ↗The invention relates to a plant for carrying out chemical reactions, having a reactor ( 1 ), the reaction space of which contains hydrogen peroxide (H 2 O 2 ) and titanium silicalite (TS-1). The object of the invention is to improve such a plant such that continuous separation and recycling of the active catalyst to the reaction space is possible with a long filter service life. This is achieved in that the reaction space contains a solid silicon source, in that the plant comprises a water takeoff line ( 3 ) which is set up for drawing off water in addition to components which are dissolved and/or dispersed therein from the reaction space, in that the water takeoff line ( 3 ) leads to a filter ( 4 ) which separates off the components which are dissolved and/or dispersed in the water, and in that the plant has a return line ( 5 ) which is set up for recirculating to the reaction space components which are separated off by means of the filter ( 4 ).
1. A plant for carrying out a chemical reactions, comprising:
a water takeoff line;
a return line; and
at least one reactor defining a reaction space of which comprises hydrogen peroxide and titanium silicalite, wherein
a) the reaction space further comprises a solid silicon source,
b) the water takeoff line is set up for drawing off water in addition to components which are dissolved and/or dispersed in the water, from the reaction space,
c) the water takeoff line leads to a filter which separates off the components which are dissolved and/or dispersed in the water, and
d) the return line is set up for recirculating to the reaction space components which are separated off by the filter;
wherein the at least one reactor comprises an agitator, and the filter is a filter tube surrounding the agitator.
2. The plant according to claim 1 , wherein the solid silicon source is precipitated silicic acid.
3. The plant according to claim 1 , wherein the at least one reactor is a multiplicity of reactors connected one after the other to form a cascade.
4. The plant according to claim 1 , further comprising a liquid/liquid separator assigned to the at least one reactor, wherein the liquid/liquid separator separates the water which is to be drawn off from the reaction space in addition to the components which are dissolved and/or dispersed in the water, from remaining liquid components which are situated in the reaction space.
5. The plant according to claim 1 , wherein the water takeoff line is, at least in sections, a flow path within a flow profile formed in the at least one reactor.
6. The plant according to claim 1 , wherein the filter is a membrane filter comprising a ceramic membrane.
7. The plant according to claim 6 , wherein the filter is a cross flow filter.
8. A process for carrying out an ammoximation reaction, comprising: reacting a ketone or an aldehyde to obtain an oxime, wherein said ammoximation reaction is carried out in the plant according to claim 1 .
9. A process for carrying out a reaction in the presence of titanium silicalite in a plant according to claim 1 , the process comprising:
(A) taking off water from the reaction space via the water takeoff line, said water comprising titanium silicalite dissolved and/or dispersed therein from the reaction;
(B) separating off the titanium silicalite from the water with the filter;
(C) recirculating the titanium silicalite that is separated off to the reaction space via the return line; and
(D) adding a solid silicon source to the reaction space.
10. The process according to claim 9 , wherein the solid silicon source is precipitated silicic acid.
11. The process according to claim 9 , wherein a ratio of a mass of the silicon source to a mass of the titanium silicalite is 1:1 or greater.
12. The process according to claim 9 , wherein the water is taken off from the reaction space continuously, and the titanium silicalite separated off is recirculated to the reaction space continuously.
13. The process according to claim 9 , wherein the reaction is carried out under alkaline conditions.
14. The process according to claim 13 , wherein the reaction is an ammoximation reaction.
15. The plant according to claim 2 , wherein the at least one reactor is a multiplicity of reactors connected one after the other to form a cascade.
16. The plant according to claim 2 , further comprising a liquid/liquid separator assigned to the at least one reactor, wherein the liquid/liquid separator separates the water which is to be drawn off from the reaction space in addition to the components which are dissolved and/or dispersed in the water, from remaining liquid components which are situated in the reaction space.
17. The plant according to claim 3 , further comprising a liquid/liquid separator assigned to the at least one reactor, wherein the liquid/liquid separator separates the water which is to be drawn off from the reaction space in addition to the components which are dissolved and/or dispersed in the water, from remaining liquid components which are situated in the reaction space.
18. The plant according to claim 15 , further comprising a liquid/liquid separator assigned to the at least one reactor, wherein the liquid/liquid separator separates the water which is to be drawn off from the reaction space in addition to the components which are dissolved and/or dispersed in the water, from remaining liquid components which are situated in the reaction space.