Antistatic ionomer composition and articles therewith
View Patent ↗Disclosed are ionomer compositions neutralized by a combination of cesium and potassium that have antistatic properties. Also disclosed are articles, including laminates and monolayer or multilayer structures comprising such compositions to which neither powders nor dusts easily adhere electrostatically.
1. A composition comprising an ionomer wherein
the composition is electrostatic dissipative and the ionomer comprises at least one E/X/Y copolymer;
the composition has a melt index of at least 0.1 g/10 min at 190° C. with a weight of 2.16 Kg;
the composition has a surface resistivity of less than 1×10 12 ohm/square, measured at 23° C. at 50% relative humidity;
E is ethylene, X is a C 3 to C 8 α,β ethylenically unsaturated carboxylic acid, and Y is alkyl acrylate or alkyl methacrylate and, based on the weight of the copolymer, is present in the copolymer from about 0 to about 40%; and
at least 80% of the total acid moieties in the copolymer are neutralized with cesium and potassium.
2. The composition of claim 1 wherein the composition has a surface resistivity of less than 1×10 11 ohm/square and from 10 to 60 mol % of the total carboxylic acid moieties are neutralized by cesium and at least 40 mol % of the total carboxylic acid moieties are neutralized by potassium.
3. The composition of claim 2 wherein the composition has a surface resistivity of less than 1×10 13 ohm/square, measured at 23° C. at 30% relative humidity and the E/X/Y copolymer does not contain Y.
4. The composition of claim 3 wherein the composition has a surface resistivity of less than 1×10 12 ohm/square, measured at 23° C. at 30% relative humidity.
5. The composition of claim 2 wherein the weight % of X in the copolymer multiplied by the mol fraction of the total carboxylic acid moieties that are neutralized is greater than or equal to 12%.
6. The composition of claim 2 wherein
the composition further comprises one or more additional polymers;
the additional polymer includes thermoplastic elastomer, styrene-butadiene-styrene block copolymer, styrene(ethylene-butylene)-styrene block copolymer, polyesters, polyamides, polyvinyl alcohol, polyolefin, ethylene copolymer, functionalized polymer, EPDM, or ground up powders of thermoset elastomer;
the thermoplastic elastomer is polyurethane, polyetheresters, polyamideethers, polyetherureas, or block copolymer based on polyether-block-amide;
the polyolefin is polyethylene, polypropylene, or ethylene/propylene copolymer;
the ethylene copolymer comprises a polar comonomer including vinyl acetate, alkyl acrylates, alkyl methacrylate, epoxy-functionalized monomer, CO, or vinyl alcohol; and
the functionalized polymer with maleic anhydride grafting or epoxidization.
7. The composition of claim 6 wherein the additional polymer is polyethylene.
8. The composition of claim 7 wherein the polyethylene is present in the composition in the range of about 1 to about 35 weight %.
9. The composition of claim 7 wherein the polyethylene is present in the composition in the range of about 50 to about 90 weight %.
10. The composition of claim 6 wherein the additional polymer is the ethylene copolymer.
11. The composition of claim 10 wherein the additional polymer is an ethylene alkyl acrylate copolymer or ethylene alkyl methacrylate copolymer.
12. The composition of claim 11 wherein the additional polymer is ethylene methyl acrylate copolymer or ethylene methyl methacrylate copolymer.
13. The composition of claim 11 further comprising a polyol, ester of polyol polyalkylene glycol, or ester polyalkylene glycol.
14. The composition of claim 13 wherein the polyol is glycerol, polyglycerol or pentaerythritol; the polyalkylene glycol is polyethylene glycol or polypropylene glycol; and the ester is polyethylene glycol glycerin ester, glycerol monostearate, glycerol distearate, or glycerol tristearate.
15. An article comprising or produced from a composition wherein the article includes monolayer film or sheet, multilayer film, multilayer sheet, multilayer laminate, molded part, or combinations of two or more thereof and the composition is as recited in claim 1 .
16. The article of claim 15 wherein the E/X/Y copolymer does not contain Y.
17. The article of claim 15 wherein the composition is a surface layer of the article.
18. The article of claim 15 , 16 , or 17 wherein the article has two surface layers and one or both of the layers comprises the composition and the composition further one or more additional polymers.
19. The article of claim 18 wherein the article is the multilayer film, the multilayer sheet, or the multilayer laminate; the article has two surface layers and at least one intermediate layer; and the the additional polymer is polyethylene, ethylene methyl acrylate copolymer, or ethylene methyl methacrylate copolymer.
20. The article of claim 19 wherein the intermediate layer comprises the composition the intermediate layer is in contact with a surface layer.