IP Library Granted Patent US 9,266,307
Granted Patent B2
US 9,266,307 · App. 12/208,301 · Granted Feb 23, 2016

Heated multiple layer glazings

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Quick Facts
Patent No.
US 9,266,307
App. No.
12/208,301
Granted
Feb 23, 2016
Kind
B2
Abstract

The present invention provides interlayers that comprise a polymer film onto which micro lines have been formed from a conductive material. The interlayers comprising such films can be incorporated, for example, into a two glass pane multiple layer glazing. Such glazings can be used, for example, in automobile windscreens or rear window applications or other applications that require a heated glazing panel.

Claims (37)

1. A multiple layer glazing interlayer, comprising:

a polymer layer comprising a polymer selected from the group consisting of: poly(vinyl butyral), polyurethane, polyvinyl chloride, poly(ethylene-co-vinyl acetate), polyethylene, polyethylene copolymers, partially neutralized ethylene/(meth)acrylic copolymers, and combinations thereof;

a polymer film disposed in contact with said polymer layer, wherein said polymer film comprises polyethylene terephthalate and electrically conductive heated micro lines having a thickness of 5 to 25 microns;

an input electrode; and,

an output electrode, wherein said input electrode and said output electrode are in electrical continuity with said micro lines.

2. The glazing interlayer of claim 1 , wherein said polymer layer comprises poly(vinyl butyral).

3. The glazing interlayer of claim 1 , wherein said micro lines have a thickness of 5 to 15 microns.

4. The glazing interlayer of claim 1 , wherein said micro lines are formed as parallel lines.

5. The glazing interlayer of claim 1 , where said micro lines comprise a metal or carbon nanotubes.

6. The glazing interlayer of claim 1 , wherein said micro lines are formed in a grid pattern.

7. The glazing interlayer of claim 1 , wherein said polymer film has a surface resistivity of 0.050 to 5 ohms per square.

8. The glazing interlayer of claim 1 , further comprising a second polymer layer disposed in contact with said polymer film.

9. The glazing interlayer of claim 1 , wherein said glazing interlayer has a transparency of at least 70%.

10. A multiple layer glazing, comprising:

two glazing panes; and,

a multiple layer glazing interlayer disposed between said glazing panes, comprising,

a polymer layer comprising a polymer selected from the group consisting of: polyvinyl (vinyl butyral), polyurethane, polyvinyl chloride, poly(ethylene-co-vinyl acetate), polyethylene, polyethylene copolymers, partially neutralized ethylene/(meth)acrylic copolymers, and combinations thereof;

a polymer film disposed in contact with said polymer layer, wherein said polymer film comprises polyethylene terephthalate and electrically conductive heated micro lines having a thickness of 5 to 25 microns;

an input electrode; and,

an output electrode, wherein said input electrode and said output electrode are in electrical continuity with said micro lines.

11. The multiple layer glazing of claim 10 , wherein said polymer layer comprises poly(vinyl butyral).

12. The multiple layer glazing of claim 10 , wherein said micro lines have a thickness of 5 to 15 microns.

13. The multiple layer glazing of claim 10 , wherein said micro lines are formed as parallel lines.

14. The multiple layer glazing of claim 10 , where said micro lines comprise a metal or carbon nanotubes.

15. The multiple layer glazing of claim 10 , wherein said micro lines are formed in a grid pattern.

16. The multiple layer glazing of claim 10 , wherein said polymer film has a surface resistivity of 0.050 to 5 ohms per square.

17. The multiple layer glazing of claim 10 , further comprising a second polymer layer disposed in contact with said polymer film.

18. The multiple layer glazing of claim 10 , wherein said glazing interlayer has a transparency of at least 70%.

19. A method of heating a vehicle windshield, comprising:

providing a multiple layer glazing, comprising:

two glazing panes; and,

a multiple layer glazing interlayer disposed between said glazing panes, comprising,

a polymer layer comprising a polymer selected from the group consisting of: poly(vinyl butyral), polyurethane, polyvinyl chloride, poly(ethylene-co-vinyl acetate), polyethylene, polyethylene copolymers, partially neutralized ethylene/(meth)acrylic copolymers, and combinations thereof;

a polymer film disposed in contact with said polymer layer, wherein said polymer film comprises polyethylene terephthalate and electrically conductive heated micro lines having a thickness of 5 to 25 microns;

an input electrode; and,

an output electrode, wherein said input electrode and said output electrode are in electrical continuity with said micro lines; and,

applying a voltage potential across said input electrode and said output electrode.

Assignments (7)
RELEASE OF SECURITY INTEREST Recorded Jul 17, 2012
From: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
To: SOLUTIA INC.; CPFILMS INC.; FLEXSYS AMERICA L.P.
Reel/Frame 028563/0241 →
SECURITY AGREEMENT Recorded May 17, 2010
From: SOLUTIA INC.; CP FILMS INC.; FLEXSYS AMERICA L.P.
To: DEUTSCHE BANK TRUST COMPANY AMERICAS, AS COLLATERAL AGENT
Reel/Frame 024390/0281 →
RELEASE OF ABL SECURITY INTEREST IN PATENTS - REEL/FRAME 022043/0539 Recorded Mar 23, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.
Reel/Frame 024120/0499 →
RELEASE OF TERM LOAN SECURITY INTEREST IN PATENTS RECORDED AT REEL/FRAME 022043/0533 Recorded Mar 23, 2010
From: CITIBANK, N.A.
To: SOLUTIA INC.
Reel/Frame 024120/0461 →
TERM LOAN PATENT SECURITY AGREEMENT Recorded Dec 31, 2008
From: SOLUTIA INC.
To: CITIBANK, N.A.
Reel/Frame 022043/0533 →
ABL PATENT SECURITY AGREEMENT Recorded Dec 31, 2008
From: SOLUTIA INC.
To: CITIBANK, N.A.
Reel/Frame 022043/0539 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 19, 2008
From: D'HAENE, POL
To: SOLUTIA, INC.
Reel/Frame 021863/0507 →