Heat-resistant insulating layer-provided separator containing heat-resistant resin and oxidation-resistant ceramic particles and non-aqueous electrolyte secondary battery
A heat-resistant insulating layer-provided separator includes a polyolefin layer and a heat-resistant insulating layer formed on one or both surfaces of the polyolefin layer and containing a heat-resistant resin and an oxidation-resistant ceramic particle. The heat-resistant insulating layer contains the oxidation-resistant ceramic particle in a proportion of from 60 to 90%.
1. A non-aqueous electrolyte secondary battery comprising:
a positive electrode including a positive electrode mixture layer comprising a positive electrode active material on a positive electrode collector, wherein the positive electrode active material comprises a lithium cobalt oxide, and at least a part of the lithium cobalt oxide is coated with an oxide comprising nickel and manganese;
a negative electrode including a negative electrode mixture layer on a negative electrode collector, wherein the negative electrode mixture layer comprises artificial graphite, and a ratio of a surface density of the positive electrode mixture layer to a surface density of the negative electrode mixture layer is from 1.90 to 2.15;
a heat-resistant insulating layer-provided separator; and
a non-aqueous electrolyte comprising LiPF 6 as an electrolyte salt in a solvent of a mixture of ethylene carbonate, dimethyl carbonate, methylethyl carbonate and 4-fluoroethylene carbonate, wherein
the non-aqueous electrolyte secondary battery is configured to operate at an open circuit voltage in a completely charged state per pair of the positive electrode and the negative electrode from 4.35 V to not more than 4.55 V,
the heat-resistant insulating layer-provided separator includes a polyolefin layer disposed between the positive and negative electrodes, and a heat-resistant insulating layer comprising a heat-resistant resin and oxidation-resistant ceramic primary particles dispersed therein,
the oxidation-resistant ceramic primary particles comprise at least alumina,
the heat-resistant insulating layer comprises the oxidation-resistant ceramic primary particles in a mass proportion of from 60 to 90% of the mass of the oxidation-resistant ceramic primary particles and the heat-resistant resin, and
the heat-resistant resin is an aramid in a fibrous state.
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the mass proportion ranges from 80 to 90%.
3. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the mass proportion ranges from 65 to 85%.
4. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the oxidation-resistant ceramic primary particles consist of alumina.
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the heat-resistant resin comprises at least an aromatic polyamide.
6. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the porosity of the heat-resistant insulating layer-provided separator ranges from 35% to 50%.
7. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the heat-resistant insulating layer-provided separator comprises 10% or more by mass proportion of a thermoplastic polymer that melts at a temperature of 260° C. or less, the mass proportion being with respect to the whole heat-resistant insulating layer-provided separator.
8. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte secondary battery is configured to operate at an open circuit voltage in a completely charged state per pair of a positive electrode and a negative electrode of not more than 4.45 V.