Resin composition and resin molded article
View Patent ↗A resin composition contains (A) an aliphatic polyester as a first polymer, (B) a second polymer having a higher glass transition temperature than the first polymer, and (C) a silicone oil.
1. A resin composition comprising (A) an aliphatic polyester as a first polymer, (B) a second polymer having a higher glass transition temperature than the first polymer, and (C) a silicone oil;
wherein the silicone oil is present in an amount of from about 1% to about 3% by mass based on the resin composition;
wherein the aliphatic polyester is present in an amount of from about 30% to about 90% by mass based on the resin composition;
wherein the second polymer is present in an amount of from about 10% to about 60% by mass based on the resin composition; and
wherein the aliphatic polyester is a polylactic acid, the second polymer is a polycarbonate resin, and the silicone oil is a straight silicone oil.
2. The resin composition according to claim 1 , wherein the aliphatic polyester has a weight average molecular weight of from about 5000 to about 200000.
3. The resin composition according to claim 1 , wherein the second polymer has a weight average molecular weight of from about 5000 to about 100000.
4. The resin composition according to claim 1 , wherein the mass ratio of the aliphatic polyester to the second polymer is from about 20/80 to about 80/20.
5. A resin molded article comprising (A) an aliphatic polyester as a first polymer, (B) a second polymer having a higher glass transition temperature than the first polymer, and (C) a silicone oil;
wherein the silicone oil is present in an amount of from about 1% to about 3% by mass based on the resin composition;
wherein the aliphatic polyester is present in an amount of from about 30% to about 90% by mass based on the resin composition;
wherein the second polymer is present in an amount of from about 10% to about 60% by mass based on the resin composition; and
wherein the aliphatic polyester is a polylactic acid, the second polymer is a polycarbonate resin, and the silicone oil is a straight silicone oil.
6. The resin molded article according to claim 5 , wherein the molded article has a surface portion and a central portion, and the ratio of the mass (Bs) of the second polymer to the mass (As) of the aliphatic polyester in the surface portion is not more than double the ratio of the mass (Bc) of the second polymer to the mass (Ac) of the aliphatic polyester in the central portion.
7. The resin molded article according to claim 5 , wherein the aliphatic polyester has a weight average molecular weight of from about 5000 to about 200000.
8. The resin molded article according to claim 5 , wherein the second polymer has a weight average molecular weight of from about 5000 to about 100000.
9. The resin molded article according to claim 5 , wherein the second polymer is present in an amount of from about 10% to about 60% by mass based on the resin composition.
10. The resin molded article according to claim 5 , wherein the mass ratio of the aliphatic polyester to the second polymer is from about 20/80 to about 80/20.
11. The resin composition according to claim 1 , wherein the straight silicone oil is at least one member selected from a group consisting of dimethyl silicone oil, methyl phenyl silicone oil, diphenyl silicone oil, carboxyl-modified silicone oils, and phenol-modified silicone oils.
12. The resin composition according to claim 5 , wherein the straight silicone oil is at least one member selected from a group consisting of dimethyl silicone oil, methyl phenyl silicone oil, diphenyl silicone oil, carboxyl-modified silicone oils, and phenol-modified silicone oils.