IP Library Granted Patent US 8,119,258
Granted Patent B2
US 8,119,258 · App. 12/213,356 · Granted Feb 21, 2012

White organic light emitting device (OLED)

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Quick Facts
Patent No.
US 8,119,258
App. No.
12/213,356
Granted
Feb 21, 2012
Kind
B2
Abstract

A white Organic Light Emitting Device (OLED) includes: an anode and cathode spaced apart from each other; first, second, and third light emitting layers sequentially stacked between the anode and the cathode; and an electron injection induction layer, arranged between the second light emitting layer and the third light emitting layer, to induce the electron to flow into the second light emitting layer from the third light emitting layer. A difference between a Lowest Occupied Molecular Orbital (LUMO) energy level of the electron injection induction layer and the LUMO energy level of a dopant existing in the second light emitting layer is 0.4 eV or below.

Claims (27)

1. A white Organic Light Emitting Device (OLED) comprising:

an anode and cathode spaced apart from each other;

first, second, and third light emitting layers sequentially stacked between the anode and the cathode; and

an electron injection induction layer, arranged between the second light emitting layer and the third light emitting layer, to induce electrons to flow into the second light emitting layer from the third light emitting layer;

wherein a difference between a Lowest Occupied Molecular Orbital (LUMO) energy level of the electron injection induction layer and the LUMO energy level of a dopant in the second light emitting layer is 0.4 eV or below,

the distance between the first light emitting layer and the anode is shorter than the distance between the third light emitting layer and the anode, and

the first light emitting layer comprises a host material of a triphenylamine derivative.

2. The white OLED of claim 1 , wherein the electron injection induction layer comprises a material having a hole transporting property and electron transporting property.

3. The white OLED of claim 1 , wherein the electron injection induction layer comprises a carbazole compound.

4. The white OLED of claim 3 , wherein the carbazole compound comprises 4,4-N,N′-dicarbazole-biphenyl (CBP), a CBP derivative, N,N′-dicarbazolyl-3,5-benzene (mCP), or a mCP derivative.

5. The white OLED of claim 1 , wherein the electron injection induction layer has a thickness in a range of 1-10 nm.

6. The white OLED of claim 1 , wherein the first, second, and third light emitting layers respectively comprise red, green, and blue light emitting layers.

7. The white OLED of claim 1 , wherein the first and second light emitting layers comprise a host material having a better hole transporting property than an electron transporting property.

8. The white OLED of claim 1 , wherein the triphenylamine derivative comprises N,N′-diphenyl-N,N′-bis(3-methylphenyl)-1,1′-bi-phenyl-4,4′-diamine (TPD) or N,N′-di(naphthalen-1-yl)-N,N′-diphenyl-benzidine (NPB).

9. The white OLED of claim 1 , wherein the second light emitting layer comprises a host material of a triphenylamine derivative or a carbazole compound.

10. The white OLED of claim 1 , wherein the third light emitting layer comprises a fluorescent host material having a hole transporting property and electron transporting property or a phosphorescent host material having a better electron transporting property than a hole transporting property.

11. The white OLED of claim 1 , wherein the first, second, and third light emitting layers each have a thickness in a range of 1-20 nm.

12. The white OLED of claim 1 , further comprising a Hole Transporting Layer (HTL) arranged between the anode and the first light emitting layer and an Electron Transporting Layer (ETL) arranged between the cathode and the third light emitting layer.

13. The white OLED of claim 12 , wherein the HTL comprises N,N′-diphenyl-N,N′-bis(3-methylphenyl)-1,1′-bi-phenyl-4,4′-diamine (TPD) or N,N′-di(naphthalen-1-yl)-N,N′-diphenyl-benzidine (NPB).

14. The white OLED of claim 12 , wherein the ETL comprises an aryl compound.

15. The white OLED of claim 14 , wherein the aryl compound comprises oxadiazole, triazole, phenanthroline, benzoxazole, or benzthiazole.

16. The white OLED of claim 12 , further comprising a Hole Injecting Layer (HIL) arranged between the anode and the HTL and an Electron Injecting Layer (EIL) arranged between the cathode and the ETL.

17. The white OLED of claim 16 , wherein the HIL comprises 4,4′,4″-tris (3-methylphenylphenylamino)triphenylamine (MTDATA), copper phthalocyanine (CuPc), or poly (3,4-ethylenedioxythiphene, polystyrene sulfonated (PEDOT/PSS).

18. The white OLED of claim 16 , wherein the EIL comprises Lithium Fluoride (LIF) or Lithium Quinolate (LiQ).

19. The white OLED of claim 1 , wherein the anode comprises a material having a work function of 4.7 eV or above.

20. The white OLED of claim 1 , wherein the anode comprises Indium Tin Oxide (ITO), Indium Zinc Oxide (IZO), SnO 2 , or ZnO.

21. The white OLED of claim 1 , wherein the cathode comprises at least one metal selected from the group consisting of aluminum (Al), silver (Ag), magnesium (Mg), Lithium (Li), or Calcium (Ca).

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 27, 2012
From: SAMSUNG ELECTRONICS CO., LTD.
To: SAMSUNG DISPLAY CO., LTD.
Reel/Frame 029093/0177 →
MERGER Recorded Sep 21, 2012
From: SAMSUNG MOBILE DISPLAY CO., LTD.
To: SAMSUNG DISPLAY CO., LTD.
Reel/Frame 029241/0599 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2009
From: SAMSUNG SDI CO., LTD.
To: SAMSUNG MOBILE DISPLAY CO., LTD.
Reel/Frame 023620/0798 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2008
From: SONG, JUNG-BAE; LEE, SUNG-HUN; KIM, SANG-YEOL; KIM, MU-GYEOM
To: SAMSUNG ELECTRONICS CO., LTD., A CORP. OF THE REPUBLIC OF KOREA; SAMSUNG SDI CO., LTD., A CORP. OF THE REPUBLIC OF KOREA
Reel/Frame 021355/0262 →