Coated article with low-E coating including zirconium oxide and/or zirconium silicon oxynitride and methods of making same
View Patent ↗This application relates to a coated article including at least one infrared (IR) reflecting layer of a material such as silver or the like in a low-E coating. In certain embodiments, at least one layer of the coating is of or includes zirconium oxide (e.g., ZrO 2 ) or zirconium silicon oxynitride (e.g., ZrSiO x N y ). When a layer comprising zirconium oxide or zirconium silicon oxynitride is provided as the uppermost or overcoat layer of the coated article (e.g., over a silicon nitride based layer), this results in improved chemical and heat stability in certain example embodiments. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windows, or in other suitable applications such as monolithic window applications, laminated windows, and/or the like.
1. A coated article including a coating supported by a glass substrate, the coating comprising, in this order from the glass substrate outwardly:
a first dielectric layer comprising silicon nitride;
a first contact layer comprising Ni and/or Cr;
an infrared (IR) reflecting layer comprising silver located on the substrate over at least and contacting the first contact layer;
a second contact layer comprising Ni and/or Cr located over and contacting the IR reflecting layer, the second contact layer having a thickness of less than or equal to 11 angstroms;
a second dielectric layer comprising silicon nitride located over and contacting the second contact layer; and
an overcoat dielectric layer comprises one or more of zirconium oxide, zirconium oxynitride, and/or zirconium silicon oxynitride located over and contacting the second dielectric layer comprising silicon nitride, and wherein the overcoat dielectric layer is doped with Al and Y.
2. The coated article of claim 1 , wherein the first dielectric layer comprising silicon nitride is in direct contact with the glass substrate.
3. The coated article of claim 1 , wherein the overcoat layer comprises zirconium silicon oxynitride.
4. The coated article of claim 1 , wherein the coated article has a sheet resistance (R s ) of no greater than about 15 ohms/square and a visible transmission of at least about 70%.
5. The coated article of claim 1 , wherein the first contact layer has a thickness of 7-8 angstroms.
6. The coated article of claim 1 , wherein the first contact layer has a thickness of less than or equal to 12 angstroms.
7. The coated article of claim 1 , wherein the overcoat layer comprises zirconium oxide and is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
8. The coated article of claim 1 , wherein the overcoat layer comprises zirconium oxynitride.
9. The coated article of claim 8 , wherein the overcoat layer is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
10. A coated article including a coating supported by a glass substrate, the coating comprising, in this order from the glass substrate outwardly:
a first dielectric layer;
a first contact layer;
an infrared (IR) reflecting layer comprising silver located on the substrate over at least and contacting the first contact layer;
a second contact layer comprising Ni and/or Cr located over and contacting the IR reflecting layer;
a second dielectric layer comprising silicon nitride located over the second contact layer; and
an overcoat dielectric layer comprises one or more of zirconium oxide, zirconium oxynitride, and/or zirconium silicon oxynitride located over and contacting the second dielectric layer comprising silicon nitride, wherein the overcoat layer is doped with Al and Y.
11. The coated article of claim 10 , wherein the first dielectric layer comprises silicon nitride and is in direct contact with the glass substrate.
12. The coated article of claim 10 , wherein the overcoat layer comprises zirconium silicon oxynitride.
13. The coated article of claim 10 , wherein the overcoat layer comprises zirconium oxide.
14. The coated article of claim 10 , wherein the coated article has a sheet resistance (R s ) of no greater than about 15 ohms/square and a visible transmission of at least about 70%.
15. The coated article of claim 10 , wherein the first contact layer has a thickness of 7-8 angstroms.
16. The coated article of claim 10 , wherein the first contact layer has a thickness of less than or equal to 12 angstroms.
17. The coated article of claim 10 , wherein the second contact layer has a thickness of less than or equal to 11 angstroms.
18. The coated article of claim 10 , wherein the overcoat layer comprises zirconium oxide and is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
19. The coated article of claim 10 , wherein the overcoat layer comprises zirconium silicon oxynitride and is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
20. A coated article including a coating supported by a glass substrate, the coating comprising, in this order from the glass substrate outwardly:
a first dielectric layer;
a first contact layer;
an infrared (IR) reflecting layer located on the substrate over at least and contacting the first contact layer;
a second contact layer located over and contacting the IR reflecting layer;
a second dielectric layer located over the second contact layer; and
an overcoat dielectric layer comprises one or more of zirconium oxide, zirconium oxynitride, and/or zirconium silicon oxynitride located over and contacting the second dielectric layer, and wherein the overcoat layer is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
21. A coated article including a coating supported by a glass substrate, the coating comprising, in this order from the glass substrate outwardly:
a first dielectric layer;
a first contact layer;
an infrared (IR) reflecting layer located on the substrate over at least and contacting the first contact layer;
a second contact layer located over and contacting the IR reflecting layer;
a second dielectric layer located over at least the second contact layer;
an overcoat dielectric layer comprising one or more of zirconium oxide, zirconium oxynitride, and/or zirconium silicon oxynitride located over and contacting the second dielectric layer; and
wherein the overcoat layer is doped with from about 2-8% Al.
22. The coated article of claim 21 , wherein the overcoat layer is doped with from about 2-8% Al and from about 2-12% Y 2 O 3 .
23. The coated article of claim 21 , wherein the overcoat layer is doped with Y.
24. The coated article of claim 21 , wherein the overcoat layer comprises zirconium oxide and is doped with from about 2-12% Y 2 O 3 .
25. The coated article of claim 21 , wherein the overcoat layer comprises zirconium oxynitride.
26. The coated article of claim 25 , wherein the overcoat layer is doped with from about 2-12% Y 2 O 3 .
27. The coated article of claim 21 , wherein the overcoat layer comprises zirconium silicon oxynitride.
28. The coated article of claim 21 , wherein the first dielectric layer comprises silicon nitride.
29. The coated article of claim 21 , wherein the IR reflecting layer comprises silver.
30. The coated article of claim 21 , wherein the second contact layer comprises Ni and Cr.
31. The coated article of claim 21 , wherein the coated article has a sheet resistance (R s ) of no greater than about 15 ohms/square and a visible transmission of at least about 50%.