Flame retardant, optically clear thermoplastic molding composition
A flame-retardant, optically clear thermoplastic molding composition is disclosed. The composition contains aromatic polycarbonate resin, a bromine-substituted carbonate oligomer, a phosphorous containing compound and an inorganic salt of perfluoroalkane sulfonic acid in amounts effective to impart to the composition flame resistance that in accordance with UL-94-5V standard is rated A at 3.00 mm and V-0 at 1.5 mm.
1. A transparent thermoplastic molding composition free of fluorinated polyolefin, comprising
A) 70 to 90 pbw of aromatic polycarbonate,
B) 1 to 20 pbw of bromine-substituted oligocarbonate
C) 1 to 20 pbw of a phosphorus-containing compound, and
D) 0.01 to 1 pbw of at least one alkali or alkaline-earth or C 1-6 -alkylammonium or ammonium salt of perfluoroalkane sulfonic acid or sodium diphenylsulfone-sulphonate or potassium diphenylsulfone-sulphonate or tetraethyl ammonium diphenylsulfone-sulphonate,
wherein the molding composition has a haze value <1.0%.
2. The composition of claim 1 wherein said bromine substituted oligocarbonate is present in an amount of 5 to 15 pbw, said phosphorus-containing compound is present in an amount of 2 to 10 pbw and said salt is present in an amount of 0.02 to 0.5 pbw.
3. The composition of claim 1 wherein said bromine-substituted oligocarbonate conforms structurally to
where R 1 ,R 2 , R 3 and R 4 independently one of the others denote H, Br or CH 3 with the proviso that at least one of R 1 , R 2 , R 3 , R 4 denotes Br, and where R5 denotes an aryl, alkylaryl or alkyl radicals, and n is 1-100.
4. The composition of claim 1 wherein said phosphorus-containing compound conforms structurally to
wherein
R 1 , R 2 , R 3 and R 4 independently one of the others, each represents C 1 - to C 8 -alkyl, or C 5-6 -cycloalkyl, C 6-20 -aryl or C 7-12 -aralkyl,
n independently one of the others denotes 0 or 1 q denotes 0.5 to 30, and
X is a mono- or poly-nuclear aromatic radical having from 6 to 30 carbon atoms, or an aliphatic radical having from 2 to 30 carbon atoms.
5. The composition of claim 1 wherein said salt of perfluoroalkane sulfonic acid is at least one perfluoroalkane sulfonate salt of a member selected from the group consisting of alkali metal, alkaline earth metal, C 1-6 -alkylammonium, and ammonium.
6. The composition of claim 1 wherein the salt is at least one member selected from the group consisting of sodium perfluoromethylbutane sulphonate, potassium perfluoromethylbutane sulphonate, tetraethyl ammonium perfluoromethylbutane sulphonate, sodium perfluoromethane sulphonate, potassium perfluoromethane sulphonate, tetraethyl ammonium perfluoromethane sulphonate, sodium perfluoroethane sulphonate, potassium perfluoroethane sulphonate, tetraethyl ammonium perfluoroethane sulphonate, sodium perfluoropropane sulphonate, potassium perfluoropropane sulphonate, tetraethyl ammonium perfluoropropane sulphonate; sodium perfluorohexane sulphonate, potassium perfluorohexane sulphonate, tetraethyl ammonium perfluorohexane sulphonate, sodium perfluoroheptane sulphonate. potassium perfluoroheptane sulphonate, tetraethyl ammonium perfluoroheptane sulphonate, sodium perfluoroctanesulphonate, potassium perfluoroctane-sulphonate, tetraethyl ammonium perfluoroctanesulphonate, sodium perfluorobutane sulfonate, potassium perfluorobutane sulfonate, tetraethyl ammonium perfluorobutane sulfonate.
7. A transparent thermoplastic molding composition free of fluorinated polyolefin, comprising
A) 70 to 90 pbw of aromatic polycarbonate,
B) 1 to 20 pbw of bromine-substituted oligocarbonate conforming to
having bromine content greater than 40 percent relative to its weight, and
C) 1 to 20 pbw of a phosphorus-containing compound conforming to
and
D) 0.01 to 1 pbw of Potassium Perfluorobutane Sulfonate,
wherein the molding composition has a haze value <1.0%.