IP Library Granted Patent US 8,168,704
Granted Patent B2
US 8,168,704 · App. 12/222,563 · Granted May 1, 2012

Adhesive composition and optical member including the same

Assignee: Cheil Industries, Inc.
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Quick Facts
Patent No.
US 8,168,704
App. No.
12/222,563
Filed
Aug 12, 2008
Granted
May 1, 2012
Kind
B2
Art Unit
1762
USPC
524/81
Abstract

An adhesive composition includes a base polymer, the base polymer including a copolymer having at least one (meth)acrylic ester with a halogen element and at least one (meth)acrylate in a copolymeric unit, and an antistatic agent, the antistatic agent including an ionic compound.

Claims (18)

1. An adhesive composition, comprising:

a base polymer, the base polymer including a copolymer having at least one (meth)acrylic ester with a halogen element and at least one (meth)acrylate in a copolymeric unit; and

an antistatic agent, the antistatic agent including an ionic compound.

2. The adhesive composition as claimed in claim 1 , wherein the halogen element in the (meth)acrylic ester is fluorine (F) or chlorine (Cl).

3. The adhesive composition as claimed in claim 2 , wherein the (meth)acrylic ester with the halogen element is represented by a general formula H 2 C═CR 1 —COOR 2 ,

wherein R 1 is H or CH 3 and R 2 is CH 2 CF 3 , CH 2 (CF 2 ) 2 H, CH 2 (CF 2 ) 4 H, CH 2 CH 2 (CF 2 ) 6 F, CH 2 CH 2 2(CF 2 ) 8 F, CH 2 CH 2 (CF 2 ) 10 F, CH 2 CH 2 (CF 2 ) 12 F, CH(CF 3 ) 2 , CF(CF 3 ) 2 , CH 2 CH(OH)CH 2 Cl, CH 2 C 6 Br 6 , CH 2 C 6 H 3 Br 3 , or CH 2 C 6 H 4 Br 2 .

4. The adhesive composition as claimed in claim 1 , wherein an amount of the (meth)acrylic ester with halogen element in the base polymer is about 0.1% by weight to about 15% by weight of a total weight of the base polymer.

5. The adhesive composition as claimed in claim 1 , wherein the (meth)acrylic ester with the halogen element includes one or more of 2,2,2-trifluoroethyl (meth)acrylate; 2,2,3,3-tetrafluoropropyl acrylate; 1H,1H,5H-octafluoropentyl (meth)acrylate; hexafluoro-2-propyl (meth)acrylate; heptafluoro-2-propyl acrylate; 2-(perfluorooctyl)ethyl methacrylate; 2-propenic acid 3,3,4,4,5,5,6,6,7,7,8,8,8-tri decafluorooctylester; 2-propenic acid 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro octylester; 2-propenic acid 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosa fluorododecylester; 2-propenic acid 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13, 14,14,14-pentacosa fluorotetra decylester; 3-chloro-2-hydroxypropyl methacrylate; pentabromobenzyl acrylate; 2,4,6-tribromobenzyl acrylate; and 2,6-dibromobenzyl acrylate.

6. The adhesive composition as claimed in claim 1 , wherein an amount of the (meth)acrylate in the base polymer is about 50% by weight to about 99.1% by weight of a total weight of the base polymer.

7. The adhesive composition as claimed in claim 6 , wherein the (meth)acrylate includes one or more of methyl(meth)acrylate; ethyl(meth)acrylate; n-butyl(meth)acrylate; t-butyl(meth)acrylate; isobutyl(meth)acrylate; hexyl(meth)acrylate; 2-ethylhexyl(meth)acrylate; n-octyl(meth)acrylate; isooctyl(meth)acrylate; n-nonyl(meth)acrylate; isononyl(meth)acrylate; n-decyl(meth)acrylate; isodecyl(meth)acrylate; n-dodecyl(meth)acrylate; n-tridecyl(meth)acrylate; n-tetradecyl(meth)acrylate; methoxyethyl(meth)acrylate; ethoxyethyl(meth)acrylate; butoxylethyl(meth)acrylate; cyclohexyl(meth)acrylate; t-butylcyclohexyl(meth)acrylate; phenoxyethyl(meth)acrylate; nonylphenoxy polyethyleneglycol(meth)acrylate; benzyl(meth)acrylate; isobonyl(meth)acrylate; and tetrahydrofurfuryl(meth)acrylate.

8. The adhesive composition as claimed in claim 6 , wherein the base polymer may further include an additive, the additive including one or more of a sulfonic acid group containing monomer, a phosphate group containing monomer, a cyano group containing monomer, a vinyl ester, an aromatic vinyl compound, a carboxyl group containing monomer, an acid anhydride group monomer, an epoxy group containing monomer, n-acryloyl morpholine and a vinyl ether.

9. The adhesive composition as claimed in claim 1 , wherein the base polymer has a weight average molecular weight of about 1,000,000 to about 2,000,000 and a glass transition temperature of about (−100)° C. to about (−5)° C.

10. The adhesive composition as claimed in claim 9 , wherein the base polymer is cross-linked with a gel fraction rate ranging from about 50% to about 80%.

11. The adhesive composition as claimed in claim 1 , wherein the ionic compound in the antistatic agent includes one or more of an imidazolium salt, a pyridinium salt, an alkylammonium salt, an alkylpyrrolidium salt, an alkylphosphonium salt, a nitrogen containing onium salt, a sulfur containing onium salt, and a phosphorus containing salt.

12. The adhesive composition as claimed in claim 1 , wherein an amount of the antistatic agent in the adhesive composition is about 0.01% by weight to about 5% by weight of a total weight of the adhesive composition.

13. An optical member, comprising:

an optical sheet; and

an adhesive layer on the optical sheet, the adhesive layer including a base polymer, the base polymer including a copolymer having at least one (meth)acrylic ester with a halogen element and at least one (meth)acrylate in a copolymeric unit, and an antistatic agent, the antistatic agent including an ionic compound.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2026
From: WUXI HENGXIN OPTOELECTRONIC MATERIALS CO., LTD.
To: HOARDSUN HENGXIN(WUXI) MATERIALS CO., LTD.
Reel/Frame 075049/0450 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 14, 2025
From: SAMSUNG SDI CO., LTD.
To: WUXI HENGXIN OPTOELECTRONIC MATERIALS CO., LTD.
Reel/Frame 073062/0496 →
MERGER Recorded Jun 16, 2025
From: CHEIL INDUSTRIES INC.
To: SAMSUNG SDI CO., LTD.
Reel/Frame 071636/0099 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 12, 2008
From: OGAWA, HIBROSHI; SUWA, TATSUHIRO; SONG, CHEONG HUN
To: CHEIL INDUSTRIES, INC.
Reel/Frame 021433/0040 →
Priority Claims (2)
JP 2007-211538 · Aug 14, 2007 · national
JP 2007-211539 · Aug 14, 2007 · national
Continuity (1)
Related Publication 20090053519A1 · Feb 26, 2009