Use of predehydration towers in an ethane oxidation to acetic acid/ethylene process
View Patent ↗Described herein is a process in which acetic acid is produced by ethane oxidation. One byproduct of the ethane oxidation is water, which is commonly removed from the process in the same stream as the acetic acid process. As described herein, the ethane oxidation reactor effluent is processed in a predehydration tower so as to separately recover water, acetic acid, and a gas stream for recycle back to the ethane oxidation reactor.
1. A process for the production of acetic acid, comprising:
oxidizing ethane in an ethane oxidation reactor to form a gaseous product stream comprising water, acetic acid, and ethane, and
feeding the gaseous product stream directly to a tower to separately recover a bottoms stream comprising at least 90 percent acetic acid, a water stream comprising less than 1 percent acetic acid, and a gas stream comprising ethylene and unreacted ethane, wherein the gaseous product stream is fed to the tower at an elevated temperature such that due to the high temperature of the stream, the stream provides energy necessary to effectuate the separation of acetic acid from water in the tower.
2. The process of claim 1 , wherein the product stream flows through a filter after the oxidizing step and before the processing step.
3. The process of claim 1 , wherein the pressure of the predehydration tower is about 1 bar to about 50 bar.
4. The process of claim 1 , wherein the processing step comprises providing additional energy input into the tower by using a reboiler.
5. The process of claim 1 , wherein the processing comprises cooling the gas stream with an overhead condensing system.
6. The process of claim 5 , wherein the gas stream is cooled to about 100° C. to about 120° C.
7. The process of claim 1 , wherein the oxidizing step is performed at about 400° C. to about 600° C.
8. The process of claim 1 , wherein the oxidizing step utilizes a carrier gas.
9. The process of claim 8 , wherein the carrier gas is selected form the group consisting of nitrogen, methane, carbon monoxide, carbon dioxide, air, steam, and a combination thereof.
10. The process of claim 1 , wherein the pressure of the oxidation reactor is about 1 bar to about 50 bar.
11. A process for the production of acetic acid, comprising:
oxidizing ethane in an ethane oxidation reactor to form a gaseous product stream comprising water, acetic acid, and ethane, at an elevated temperature between about 450° C. and about 600° C. and
feeding the gaseous product stream to a tower to separately recover a bottoms stream comprising acetic acid, a water stream comprising less than 1 percent acetic acid, and a gas stream comprising ethylene and unreacted ethane, wherein the gaseous product stream is fed to the tower at the elevated temperature such that due to the high temperature of the stream, the stream provides energy necessary to effectuate the separation of acetic acid from water in the tower.
12. The method of claim 11 , carried out in an apparatus for manufacturing acetic acid, including:
an ethane oxidation reactor in communication with an ethane source, an oxygen source, a recycle stream, and a gaseous outlet product stream;
a predehydration tower in communication with the gaseous outlet product stream and an overhead condensing system, wherein the predehydration tower is adapted to separately recover a bottoms stream containing acetic acid, a water stream and an overhead gas stream; and
a CO x converter in communication with the overhead gas stream and the recycle stream.
13. The method of claim 12 , wherein the overhead condensing system is in communication with an overhead recycle stream, reflux stream, and water stream.
14. The method of claim 13 , wherein the condensing system comprises a condenser which has an operating temperature of about 100° C. to about 120° C.
15. The method of claim 12 , wherein the predehydration tower further comprises a reboiler in communication with the predehydration tower, a reboiler reflux stream, and an acetic acid stream.
16. The method of claim 15 , wherein the reboiler has an operating temperature that is high enough to vaporize part of the reboiler reflux stream.
17. The method of claim 12 , wherein the predehydration tower has 25-35 stages.
18. The method according to claim 11 , carried out in an apparatus for manufacturing acetic acid, including:
an ethane oxidation reactor in communication with an ethane source, an oxygen source, a recycle stream, and a gaseous outlet product stream;
a predehydration tower in communication with the gaseous outlet product stream, an acetic acid stream, and an overhead gas stream, wherein the predehydration tower is adapted to separately recover a bottoms stream containing acetic acid, a water stream and an overhead gas stream;
a condenser in communication with the overhead gas stream; and
a reboiler in communication with the acetic acid stream.
19. The method according to claim 18 , wherein the apparatus further comprises a CO x converter in communication with the overhead gas stream and the recycle stream.
20. The method according to claim 11 , carried out in an apparatus for manufacturing acetic acid, including:
means for oxidizing ethane to produce a gaseous product stream comprising water, acetic acid, and ethane; and
means for processing the gaseous product stream to separately recover a bottoms stream comprising at least 90 percent acetic acid, a water stream comprising less than 1 percent acetic acid, and a gas stream comprising ethylene and unreacted ethane.
21. The method according to claim 20 , wherein the means for processing comprises a reboiler in communication with the predehydration tower, a reboiler reflux stream, and an acetic acid stream.
22. The process of claim 1 wherein the gaseous product stream exits the reactor at a temperature between about 450° and about 600° C.
23. The process of claim 22 , wherein the product stream comprises ethylene, acetic acid, water, CO, CO 2 and unreacted ethane.