Method for recovering hydrolysis products
View Patent ↗An improved method for treating lignocellulosic material, including a prehydrolysis-mass transfer process, which produces a concentrated hydrolysate volume during the time required for the hydrolysis itself. The improved process comprises the heating of the digester and chip content by direct steam to the required hydrolysis temperature, starting a flow of hot, stored hydrolysate to the top of the chip bed in order to create a trickle-bed type down-flow of hydrolysate, collecting a first fraction of the trickled-down hydrolysate as a product fraction, adding extraction liquid and continuing the trickle flow to collect a second hydrolysate fraction, which will be discharged from the digester to a hot hydrolysate storage tank to be used as the first trickle flow liquid in the next batch.
1. A method for recovering carbohydrates in a prehydrolysis batch pulping process comprising the following stages:
a) providing a digester having a top and bottom, and containing a column of lignocellulosic material having voids within the column of lignocellulosic material,
b) heating the digester and its contents to a predetermined pre-hydrolysis reaction temperature by directly adding steam to the digester,
c) providing a flow of hydrolysate liquid at a temperature essentially corresponding to the prehydrolysis reaction temperature and containing hydrolysis product from lignocellulosic material to the top of the column, creating a trickle-bed downflow of hydrolysate liquid wherein the liquid volume of the trickle-bed downflow within the digester facilitates the retention of voids within the column of lignocellulosic material, forming a liquid phase not filling the voids in the lignocellulosic material, but trickling uniformly through the column of lignocellulosic material towards the digester bottom,
d) collecting a first fraction of the hydrolysate liquid resulting from said trickle-bed downflow from the digester bottom,
e) adding liquid to the flow provided to the top of the column and continuing the trickle-bed downflow wherein the liquid volume of the trickle-bed downflow within the digester facilitates the retention of voids within the column of lignocellulosic material, collecting a second hydrolysate fraction and discharging said second hydrolysate fraction from the digester to a hydrolysate storage tank.
2. The method according to claim 1 , wherein the digester and its contents are heated in stage b) to a temperature in the range 150- 180° C.
3. The method according to claim 1 , wherein liquid is recycled from the digester bottom discharge to the top of the column in stage c).
4. The method according to claim 1 , wherein the liquid is recycled from the digester bottom discharge to the top of the column in stage e).
5. The method according to claim 1 , wherein a hydrolysis agent is added to the flow provided to the top of the column in stage e).
6. The method according to claim 1 , comprising the additional steps of f) introducing a volume of washing liquid into the digester, and g) removing said volume of washing liquid from the end of the digester opposite to the introduction end.
7. The method according to claim 6 , wherein the washing liquid is introduced at the top of the digester.
8. The method according to claim 6 , wherein the washing liquid is introduced at the bottom of the digester.