Thermoplastic resin composition
View Patent ↗A thermoplastic resin composition of the present invention has high impact resistance, not lowering the weather resistance thereof, even though the amount of an impact resistance improver added thereto is small. The thermoplastic resin composition contains 100 parts by weight of (A) a thermoplastic resin and from 0.5 to 20 parts by weight of (B) a graft copolymer, wherein the graft copolymer (B) contains from 70% to 99% by weight of a crosslinked core (b2) prepared through polymerization of a monomer for the core (b2), containing 70% by weight or more of an acrylate, in the presence of from 0.5% to 20% by weight of a non-crosslinked seed (b1) having a weight-average molecular weight of 40,000 or less, and from 0.5% to 10% by weight of a shell (b3) prepared through polymerization of a monomer for the shell (b3) containing 50% by weight or more of a methacrylate, and the thermoplastic composition further contains from 0.01 to 3.0 parts by weight of (C) a water-soluble polymer compound having the property of forming a physical gel, relative to 100 parts by weight of the graft copolymer (B).
1. A thermoplastic resin composition containing 100 parts by weight of (A) a thermoplastic resin and from 0.5 to 20 parts by weight of (B) a graft copolymer, wherein:
the graft copolymer (B) contains from 70% to 99% by weight of a crosslinked core (b2) prepared through polymerization of a monomer for the core (b2), containing 70% by weight or more of an acrylate, in the presence of from 0.5% to 20% by weight of a non-crosslinked seed (b1) having a weight-average molecular weight of 40,000 or less, and from 0.5% to 10% by weight of a shell (b3) prepared through polymerization of a monomer for the shell (b3) containing 50% by weight or more of a methacrylate,
and the thermoplastic composition further contains from 0.01 to 3.0 parts by weight, relative to 100 parts by weight of the graft copolymer (B), of (C) a water-soluble polymer compound having the property of forming a physical gel.
2. The thermoplastic resin composition according to claim 1 , wherein the non-crosslinked seed (b1) is prepared through polymerization of a monomer mixture for the seed (b1) containing from 15% to 98% by weight of (b1-1) at least one monomer selected from the group consisting of an acrylate with an alkyl group having from 2 to 8 carbon atoms, and a methacrylate with an alkyl group having from 1 to 4 carbon atoms, from 0% to 83% by weight of (b1-2) at least one monomer selected from the group consisting of an aromatic vinyl monomer, a vinyl cyanide, an acrylate with an alkyl group having 9 carbon atoms or more and a methacrylate with an alkyl group having 5 carbon atoms or more, and from 2% to 25% by weight of (b1-3) a chain transfer agent.
3. The thermoplastic resin composition according to claim 1 , wherein the monomer for the core (b2) is a mixture containing from 70% to 99.9% by weight of an acrylate with an alkyl group having from 2 to 8 carbon atoms, from 0.1% to 5% by weight of a polyfunctional monomer, and from 0% to 29.9% by weight of a monomer copolymerizable with the acrylate with an alkyl group having from 2 to 8 carbon atoms and the polyfunctional monomer, and the volume-average particle size of the crosslinked core (b2) is from 0.05 to 0.3 μm.
4. The thermoplastic resin composition according to claim 1 , wherein the monomer for the shell (b3) is a monomer containing from 50% to 100 % by weight of a methacrylate with an alkyl group having from 1 to 4 carbon atoms, and from 0% to 50% by weight of a monomer copolymerizable with the methacrylate with an alkyl group having from 1 to 4 carbon atoms.
5. The thermoplastic resin composition according to claim 1 , wherein the water-soluble polymer compound (C) having the property of forming a physical gel is one or more selected from the group consisting of hydroxyethylmethyl cellulose, hydroxypropylmethyl cellulose, carboxymethyl cellulose, alginic acid, sodium alginate, potassium alginate, ammonium alginate, agar, gelatin, carrageenan, glucomannan, pectin, curdlan and Gellan gum.
6. The thermoplastic resin composition according to claim 5 , wherein the water-soluble polymer compound (C) having the property of forming a physical gel is alginic acid, sodium alginate, potassium alginate or ammonium alginate.
7. The thermoplastic resin composition according to claim 1 , wherein the proportion of the shell (b3) in the graft copolymer (B) is from 0.5% to 7% by weight.
8. The thermoplastic resin composition according to claim 1 , wherein the proportion of the shell (b3) in the graft copolymer (B) is from 0.5% to 4% by weight.
9. The thermoplastic resin composition according to claim 1 , which contains from 0.5 to 10 parts by weight of the graft copolymer (B).
10. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin (A) is a vinyl chloride-based resin.