Method for producing duplex stainless steel seamless pipe
View Patent ↗The present invention is to provide a method for producing duplex stainless steel seamless pipe in which a duplex stainless steel billet can be inhibited from generating an oxide scale on the surface thereof during heating and the generation of outer surface flaw can also be prevented. The billet is heated in the a heating furnace for 1.5 hours or more and 4.0 hours or less at a heating temperature of 1250° C. or more and 1320° C. or less while regulating the average concentration of sulfur dioxide (SO 2 ) gas in the atmosphere within the furnace to 0.01 volume % or less.
1. A method for producing duplex stainless steel seamless pipe, the method comprising the steps of:
applying, onto a billet's surface, a lubricant composition for hot metal working consisting of an inorganic component as a first component; sodium hydroxide as a second component; water-soluble resins and/or water-soluble surfactants as a third component; and water,
wherein said lubricant composition for hot metal working, to a total mass of said first component, said second component, and said third component as 100 mass %, consists of: 96.5 mass % or more and 99.98 mass % or less of said first component; 0.01 mass % or more and 0.5 mass % or less of said second component; and 0.01 mass % or more and 1.5 mass % or less of said third component,
wherein said inorganic component is one or in combination of two or more selected from the group consisting of: Al 2 O 3 , SiO 2 , CaO, B 2 O 3 , K 2 O, and Na 2 O;
heating the billet in a heating furnace after the step of applying the lubricant composition, wherein, during the step of heating, said billet is heated in the heating furnace for 1.5 hours or more and 4.0 hours or less at 1250° C. or more and 1320° C. or less while regulating the average concentration of sulfur dioxide (SO 2 ) gas in the atmosphere within the furnace to 0.01 volume % or less, and
performing hot metal working of said billet after the step of heating.
2. The method for producing duplex stainless steel seamless pipe according to claim 1 , wherein sulfur (S) content in a fuel to be used in said heating furnace in the step of heating is regulated to 0.1 mass % or less.
3. The method for producing duplex stainless steel seamless pipe according to claim 1 , wherein a duplex stainless steel for said seamless pipe comprising said billet contains:
in mass %,
C: 0.03% or less,
Si: 0.1 to 2%,
Mn: 0.1 to 2%,
P: 0.05% or less,
S: 0.008% or less,
Al: 0.1% or less,
Ni: 5 to 11%,
Cr: 17 to 30%,
Mo: 1 to 6%,
N: 0.1 to 0.4%,
Ca: 0 to 0.02%,
Mg: 0 to 0.02%,
REM: 0 to 0.2%,
B: 0 to 0.05%,
Cu: 0 to 2%,
V: 0 to 1.5%,
Ti: 0 to 0.5%, and
Nb: 0 to 0.5%, and
a residue Fe as well as inevitable impurity.
4. The method for producing duplex stainless steel seamless pipe according to claim 1 , wherein said billet further contains, in mass %, over 1.5% and 5% or less of W.