Composite material component with silicon-containing ceramic matrix, protected against corrosion
View Patent ↗An environmental barrier is formed on a substrate ( 10 ) of ceramic matrix composite material and comprises an outer anticorrosion protection layer ( 12 ) containing a compound of the type comprising an aluminosilicate of an alkali, or an alkaline-earth, or a rare-earth element. A bond sub-layer ( 14 ) is formed between the substrate ( 10 ) and the protection layer ( 12 ), the composition of the bond sub-layer varying from substantially pure silicon to substantially pure mullite between an inner face beside the substrate and an outer face, with the silicon content decreasing and the mullite content increasing.
1. A part comprising:
a substrate of ceramic matrix composite material containing silicon; and
an environmental barrier formed on the substrate and comprising:
an outer anticorrosion protection layer containing a compound comprising an aluminosilicate of an alkali, element, an aluminosilicate of an alkaline-earth element, or an aluminosilicate of a rare-earth element, and
a bond sub-layer containing silicon and formed on the substrate,
wherein:
the bond sub-layer is formed between the substrate and the anticorrosion protection layer,
the composition of the bond sub-layer varying from silicon to mullite between an inner face beside the substrate and an outer face, with the silicon content decreasing and the mullite content increasing,
the bond sub-layer beginning, beside its inner face, in a layer of silicon formed on the substrate and having a thickness of no more than 50 μm, and
the bond sub-layer terminating, beside its outer face, in a layer of mullite having a thickness of no more than 50 μm.
2. The part according to claim 1 , wherein the environmental barrier further comprises an outside thermal protection layer formed on the outer anticorrosion protection layer.
3. The part according to claim 1 , wherein the environmental barrier comprises the anticorrosion protection layer formed by a compound comprising an aluminosilicate of an alkali, element, an aluminosilicate of an alkaline-earth element, or an aluminosilicate of a rare-earth element, and an underlying layer formed on the bond sub-layer and comprising an association of said compound together with mullite.
4. The part according to claim 3 , wherein said underlying layer has a composition that varies between mullite at an inner face situated beside the bond sub-layer and substantially solely the compound forming the anticorrosion protection layer at an outer face situated beside said anticorrosion protection layer, with the mullite content decreasing progressively and the content of said compound increasing progressively.
5. The part according to claim 1 , constituting a component of a hot portion of a gas turbine.
6. The part according to claim 5 , constituting at least a portion of a wall of a gas turbine combustion chamber.