Lithium secondary battery and method for producing the same
View Patent ↗Disclosed is a method for producing a lithium secondary battery including forming an electrode assembly using a cathode, an anode and a separator, introducing the electrode assembly into a battery case, injecting an electrolyte into the battery case, and sealing the battery case, wherein, during assembly of the electrode assembly, insulating particles are dispersed on part of the surface of the separator, or at least one of the cathode and the anode contacting the separator. The step of dispersing insulating particles on the part of the surface of the separator or at least one of the cathode and the anode contacting the separator during battery assembly can considerably reduce short-circuits in a lithium secondary battery caused by intrinsic and extrinsic factors and thus low-voltage defects, and thereby significantly improve yield of a lithium secondary battery.
1. A method for producing a lithium secondary battery, the method consisting of:
(a) distributing or scattering an insulating material directly onto a surface of at least one of a preformed cathode, a preformed anode or a polymer film separator to form a layer consisting of the insulating material, wherein the insulating material consists of powder and is selected from the group consisting of MgO, TiO 2 , Li 4 Ti 5 O 12 , ZrO 2 , InSnO 2 , Al 2 O 3 , SiO 2 , GeO 2 , MoO, SnO, Cr 2 O 3 and Sb 2 O 3 —SnO 2 , wherein the insulating material partially covers the surface, and wherein the layer formed by the distributing or the scattering of the insulating material has a thickness of 20 nm-5 μm;
(b) forming an electrode assembly having the preformed cathode, the preformed anode and the polymer film separator by interposing the polymer film separator between the preformed cathode and the preformed anode and fusing the polymer film separator, the preformed cathode and the preformed anode at a hot fusion temperature to form the electrode assembly after the distributing or the scattering of the insulating material onto the surface in step (a);
(c) introducing the electrode assembly formed in step (b) into a casing and injecting an electrolyte;
(d) sealing the casing to finish assembly of the battery;
(e) optionally performing formation of the battery by repeating charge/discharge cycles after the assemblage of the battery in order to activate the battery; and
(f) optionally performing aging of the battery to stabilize the activated battery.
2. The method as claimed in claim 1 , wherein the insulating material has a particle diameter of 20 nm-1 μm.
3. The method as claimed in claim 1 , wherein the distribution or the scattering of the insulating material directly onto the surface is via a fine net or sieve vibration system.
4. The method as claimed in claim 1 , wherein the insulating material is used in an amount of 2 μg/cm 2 ˜50 mg/cm 2 per unit area.
5. The method as claimed in claim 1 , wherein the hot fusion is performed at a temperature of 60° C.-100° C.
6. The method of claim 1 , wherein the polymer film separator is a microporous polymer separator.