Area bonded nonwoven fabric from single polymer system
View Patent ↗A nonwoven fabric is provided having a plurality of semi-crystalline filaments that are thermally bonded to each other and are formed of the same polymer and exhibit substantially the same melting temperature. The fabric is produced by melt spinning an amorphous crystallizable polymer to form two components having different levels of crystallinity. During spinning, a first component of the polymer is exposed to conditions that result in stress-induced crystallization such that the first polymer component is in a semi-crystalline state and serves as the matrix or strength component of the fabric. The second polymer component is not subjected to stress induced crystallization and thus remains in a substantially amorphous state which bonds well at relatively low temperatures. In a bonding step, the fabric is heated to soften and fuse the binder component. Under these conditions, the binder component undergoes thermal crystallization so that in the final product, both polymer components are semi-crystalline.
1. An area bonded nonwoven fabric comprising fibers of a semi-crystalline thermoplastic polymer fusion bonded to one another throughout the fabric to form a strong coherent nonwoven fabric, and wherein the fibers of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.
2. The nonwoven fabric of claim 1 , wherein the fibers include matrix fibers crystallized under stress and binder fibers thermally crystallized without stress, and wherein the fibers are fusion bonded only by the binder fibers.
3. The nonwoven fabric of claim 1 , wherein the matrix fibers and the binder fibers exhibit different dye uptakes.
4. The nonwoven fabric of claim 1 , wherein the semi-crystalline polymer of the fibers has a degree of crystallinity of at least 50%.
5. The nonwoven fabric of claim 4 , wherein the polymer has a degree of crystallinity of at least 80%.
6. The nonwoven fabric of claim 1 , wherein the semi-crystalline polymer is a polyester selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, and polylactic acid.
7. The nonwoven fabric of claim 1 , wherein the fibers of the nonwoven fabric comprise interconnected continuous filaments in which some of the filaments have fused to adjacent filaments at points contact and wherein some of the filaments have not fused to adjacent filaments at points of contact.
8. An area bonded spunbond nonwoven fabric consisting essentially of continuous filaments of a semi-crystalline thermoplastic polymer and a multiplicity of thermal fusion bonds located throughout the fabric, the fusion bonds consisting of areas in which contacting filaments have softened and thermally fused to one another, and wherein the filaments have retained their filamentary form throughout the fabric.
9. The nonwoven fabric according to claim 8 , wherein the filaments have a multilobal cross-section.
10. The nonwoven fabric according to claim 9 , wherein the fusion bonds are present only on the lobes of the multilobal filaments.
11. The nonwoven fabric of claim 8 , wherein the continuous filaments of the nonwoven fabric include matrix filaments crystallized under stress and binder filaments thermally crystallized without stress, and wherein said fusion bonds are formed only by the binder filaments.
12. The nonwoven fabric of claim 8 , wherein the semi-crystalline polymer of the fibers has a degree of crystallinity of at least 95%.
13. The nonwoven fabric of claim 8 , wherein the semi-crystalline polymer is a polyester selected from the group consisting of polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, and polylactic acid.
14. An area bonded spunbond nonwoven fabric comprising continuous filaments of polyethylene terephthalate homopolymer including matrix filaments melt extruded from a relatively higher intrinsic viscosity polyethylene terephthalate homopolymer and binder filaments melt extruded from a relatively lower intrinsic viscosity polyethylene terephthalate homopolymer, and a multiplicity of thermal fusion bonds located throughout the fabric, the fusion bonds consisting of areas in which the binder filaments have softened and thermally fused to adjacent filaments at points of contact, and wherein the binder and matrix filaments have retained their filamentary form throughout the fabric, and wherein both the matrix and binder filaments are in a semi-crystalline state and exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace trace.
15. The nonwoven fabric of claim 14 , wherein the matrix filaments are formed with polyethylene terephthalate homopolymer having an intrinsic viscosity of about 0.65 dl/g or greater and the binder filaments are formed with polyethylene terephthalate homopolymer having an intrinsic viscosity of about 0.62 dl/g or less.
16. The nonwoven fabric of claim 14 , wherein the matrix filaments and the binder filaments exhibit different dye uptakes.
17. The nonwoven fabric of claim 14 , wherein the semi-crystalline polymer of the matrix and binder filaments has a degree of crystallinity of at least 95%.
18. An area bonded spunbond nonwoven fabric comprising continuous bicomponent filaments of polyethylene terephthalate homopolymer including a matrix component melt extruded from a relatively higher intrinsic viscosity polyethylene terephthalate homopolymer and a binder component melt extruded from a relatively lower intrinsic viscosity polyethylene terephthalate homopolymer, and a multiplicity of thermal fusion bonds located throughout the fabric, the fusion bonds consisting of areas in which the binder component has softened and thermally fused to adjacent filaments at points of contact, and wherein both the matrix and binder components are in a semi-crystalline state and exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace trace.
19. The nonwoven fabric of claim 18 , wherein the matrix component is formed with polyethylene terephthalate homopolymer having an intrinsic viscosity of about 0.65 dl/g or greater and the binder component is formed with polyethylene terephthalate homopolymer having an intrinsic viscosity of about 0.62 dl/g or less.
20. The nonwoven fabric of claim 18 , wherein the bicomponent filaments have a sheath-core cross-sectional configuration with the matrix component occupying the core and the binder component occupying the surrounding sheath.
21. The nonwoven fabric of claim 18 , wherein the semi-crystalline polymer of the matrix and binder components has a degree of crystallinity of at least 95%.
22. An area bonded nonwoven fabric produced by a method comprising the steps of melt extruding a crystallizable amorphous polymer to produce a plurality of fibers; subjecting the polymer to processing conditions that produce a first polymer component that is at least partially crystalline and a second polymer component that is substantially amorphous; depositing the fibers on a collection surface to form a web containing both said partially crystalline first polymer component and said amorphous second polymer component; bonding the fibers to one another to form a bonded nonwoven web in which the amorphous second polymer component softens and fuses to form bonds with the first polymer component; and effecting crystallization of the second polymer component so that in the resulting nonwoven fabric both said polymer components are at least partially crystalline, and wherein the fibers of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.
23. An area bonded nonwoven fabric produced by a method comprising the steps of melt extruding a crystallizable amorphous polymer through one or more spinnerets that form first and second groups of continuous filaments;
subjecting the first and second groups of continuous filaments to processing conditions that impart stress to the first group of filaments producing stress-induced crystallization such that the filaments are at least partially crystallized, and imparts stress to the second group of continuous filaments insufficient to produce stress-induced crystallization such that the filaments remain substantially amorphous;
depositing the first and second groups of continuous filaments on a collection surface to form a web containing both said partially crystalline first filaments as matrix filaments and said amorphous second filaments as binder filaments;
heating the web so that the amorphous binder filaments soften and fuse to form bonds with one another and with the matrix filaments while maintaining their continuous filamentary form; and
effecting crystallization of the amorphous binder filament during the heating step so that in the resulting nonwoven fabric both said matrix filaments and said binder filaments are at least partially crystalline, and wherein the fibers of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.
24. An area bonded nonwoven fabric produced by a method comprising the steps of
melt extruding a crystallizable amorphous polymer through one or more spinnerets configured to form bicomponent filaments having first and second polymer components present in distinct portions of the cross section of the filament, wherein the intrinsic viscosity of the polymer in the second component is reduced relative to the intrinsic viscosity of the polymer in the first component;
attenuating the filaments to cause stress-induced crystallization in the first polymer component of the filaments but without producing stress-induced crystallization in the second polymer component such that the second polymer component remains substantially amorphous;
depositing the bicomponent filaments on a collection surface to form a web in which the first polymer component of the filaments is partially crystalline and serves as the matrix component of the filaments and the second polymer component of the filament is amorphous and serves as the binder component of the filaments;
heating the web so that the amorphous binder component of the filaments softens and fuses to form bonds with contacting filaments while the filaments maintain their continuous filamentary form; and
effecting crystallization of the amorphous binder component of the filaments during the heating step so that in the resulting nonwoven fabric both the matrix component and the binder component of the bicomponent filaments are at least partially crystalline, and wherein the fibers of the nonwoven fabric exhibit a single melting peak as evidenced by a differential scanning calorimetry (DSC) trace.