IP Library Granted Patent US 9,533,479
Granted Patent B2
US 9,533,479 · App. 12/233,215 · Granted Jan 3, 2017

Absorbent articles having antimicrobial properties and methods of manufacturing the same

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Quick Facts
Patent No.
US 9,533,479
App. No.
12/233,215
Granted
Jan 3, 2017
Kind
B2
Abstract

According to one embodiment, an absorbent article includes a moisture-impervious outer layer, an inner layer substantially co-extensive with the outer layer, and an absorbent layer interposed between the outer layer and the inner layer. The inner layer is treated with at least one antimicrobial booster. The absorbent layer is treated with at least one antimicrobial agent.

Claims (26)

1. An absorbent article comprising:

a moisture-impervious outer layer;

an inner layer substantially co-extensive with the outer layer, the inner layer being treated with at least one antimicrobial booster such that the at least one antimicrobial booster is mixed throughout the material of the inner layer prior to forming the inner layer, the at least one antimicrobial booster including two or more 1,2-alkanediols; and

an absorbent layer interposed between the outer layer and the inner layer, the absorbent layer being treated with at least one antimicrobial agent such that a wearer is insulated from the at least one antimicrobial agent, the at least one antimicrobial agent comprising polyhexamethylene biguanide,

wherein the at least one antimicrobial booster is configured to synergistically combine with the at least one antimicrobial agent when moisture is introduced into the article in use to (i) achieve a microbe kill rate that is greater than the microbe kill rate achieved by the antimicrobial booster or the antimicrobial agent individually, and (ii) minimize the irritating effects of the antimicrobial agent on a user when the absorbent article is in use.

2. The absorbent article of claim 1 , wherein the at least one antimicrobial agent further comprises at least one of additional cationic antimicrobial polymers, mono-quaternary ammonium salt based antimicrobials, poly-quaternary ammonium salt based antimicrobials, chlorinated phenoxy-based antimicrobials, pyrithione based antimicrobials, cationic polysaccharides, aminopolysaccharides, benzalkonium compounds, nitro compounds, dimethylbenzylammonium chloride, chlorhexidines, crosslinked polyethylene glycols of differing molecular weights, polyethylene glycols of differing molecular weights, hydantoin derivatives with halamine bond, antibiotics, natural extracts with antimicrobial properties, metallic materials, and combinations thereof.

3. The absorbent article of claim 1 , wherein the at least one antimicrobial agent further comprises at least one of trialkoxysilyl quaternary ammonium salt, 3-trimethoxy-silyl-propyldimethyloctadecyl ammonium chloride, polyquat-1, triclosan, zinc pyrithione, chitosan, chitosan derivatives, chitin derivatives, benzalkonium chloride, a mixture of benzalkonium chloride and silver nitrate, 5-nitrofurylacrolein, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, polymycine, neomycin, kanamycin, grisofulvien, grape fruit seed, hops, tea oil, aloe, thyme, rosemary, peppermint, basil, ginger, silver, copper, zinc, zinc oxide, silver oxide, silver chloride, silver nitrate, silver-zinc zeolite, tributylin maleate, and combinations thereof.

4. The absorbent article of claim 1 , wherein the two or more 1,2-alkanediols comprise 1,2-hexanediol and 1,2-octanediol.

5. The absorbent article of claim 1 , wherein the at least one antimicrobial booster is a preservative booster.

6. The absorbent article of claim 1 , wherein the at least one antimicrobial booster further includes at least one of aloe, alkyl diols, ethylenediaminetetraacetic acid, 1,2-hexanediol, 1,2-octanediol, tropolone, 1,2-decanediol, 1,2-pentanediol, and combinations thereof.

7. The absorbent article of claim 1 , wherein the absorbent layer comprises a fibrous material.

8. The absorbent article of claim 1 , wherein the absorbent article is a diaper, an underpad, or an adult incontinence brief.

9. The absorbent article of claim 1 , wherein the inner layer is treated with the at least one antimicrobial booster at a concentration level of about 0.1% to about 5.0%.

10. The absorbent article of claim 9 , wherein the inner layer is treated with the at least one antimicrobial booster at a concentration level of about 0.5%.

11. An absorbent article comprising:

a moisture-impervious outer layer;

an inner layer substantially co-extensive with the outer layer, the inner layer being treated with at least one antimicrobial booster such that the at least one antimicrobial booster is mixed throughout the material of the inner layer prior to forming the absorbent article, the at least one antimicrobial booster including one or more alkyl diol; and

an absorbent layer interposed between the outer layer and the inner layer, the absorbent layer being treated with at least one antimicrobial agent such that a wearer is insulated from the at least one antimicrobial agent, the at least one antimicrobial agent comprising polyhexamethylene biguanide,

wherein the at least one antimicrobial booster is configured to synergistically combine with the at least one antimicrobial agent when moisture is introduced into the article in use to (i) achieve a microbe kill rate that is greater than the microbe kill rate achieved by the antimicrobial booster or the antimicrobial agent individually, and (ii) minimize the irritating effects of the antimicrobial agent on a user when the absorbent article is in use.

12. The absorbent article of claim 11 , wherein the at least one antimicrobial agent further comprises at least one of additional cationic antimicrobial polymers, mono-quaternary ammonium salt based antimicrobials, poly-quaternary ammonium salt based antimicrobials, chlorinated phenoxy-based antimicrobials, pyrithione based antimicrobials, cationic polysaccharides, aminopolysaccharides, benzalkonium compounds, nitro compounds, dimethylbenzylammonium chloride, chlorhexidines, crosslinked polyethylene glycols of differing molecular weights, polyethylene glycols of differing molecular weights, hydantoin derivatives with halamine bond, antibiotics, natural extracts with antimicrobial properties, metallic materials, and combinations thereof.

13. The absorbent article of claim 11 , wherein the at least one antimicrobial agent further comprises at least one of trialkoxysilyl quaternary ammonium salt, 3-trimethoxy-silyl-propyldimethyloctadecyl ammonium chloride, polyquat-1, triclosan, zinc pyrithione, chitosan, chitosan derivatives, chitin derivatives, benzalkonium chloride, a mixture of benzalkonium chloride and silver nitrate, 5-nitrofurylacrolein, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, polymycine, neomycin, kanamycin, grisofulvien, grape fruit seed, hops, tea oil, aloe, thyme, rosemary, peppermint, basil, ginger, silver, copper, zinc, zinc oxide, silver oxide, silver chloride, silver nitrate, silver-zinc zeolite, tributylin maleate, and combinations thereof.

14. The absorbent article of claim 11 , wherein the at least one antimicrobial booster is a preservative booster.

15. The absorbent article of claim 11 , wherein the absorbent layer comprises a fibrous material.

16. The absorbent article of claim 11 , wherein the absorbent article is a diaper, an underpad, or an adult incontinence brief.

17. The absorbent article of claim 11 , wherein the inner layer is treated with the at least one antimicrobial booster at a concentration level of about 0.1% to about 5.0%.

18. The absorbent article of claim 17 , wherein the inner layer is treated with the at least one antimicrobial booster at a concentration level of about 0.5%.

Assignments (6)
PATENT SECURITY AGREEMENT Recorded May 28, 2026
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 075643/0462 →
PATENT SECURITY AGREEMENT Recorded Jun 20, 2025
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 071672/0100 →
ENTITY CONVERSION Recorded Nov 1, 2021
From: MEDLINE INDUSTRIES, INC.
To: MEDLINE INDUSTRIES, LP
Reel/Frame 057979/0606 →
SECURITY INTEREST Recorded Oct 21, 2021
From: MEDLINE INDUSTRIES, LP
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 057927/0091 →
SECURITY INTEREST Recorded Oct 21, 2021
From: MEDLINE INDUSTRIES, LP
To: BANK OF AMERICA, N.A.
Reel/Frame 058040/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2009
From: SETOODEH, AMIN; CHAKRAVARTHY, DEBASHISH; YAO, MIN; LOVE, DANIEL B.
To: MEDLINE INDUSTRIES, INC.
Reel/Frame 022370/0296 →