Manufacturing carbon nanotube ropes
View Patent ↗Techniques for manufacturing carbon nanotube (CNT) ropes are provided. In some embodiments, a CNT rope manufacturing method optionally includes preparing a metal tip, preparing a CNT colloid solution, immersing the metal tip into the CNT colloid solution; and withdrawing the metal tip from the CNT colloid solution.
1. A method for manufacturing a cold cathode comprising:
immersing a metal tip into a carbon nanotube (CNT) colloid solution, wherein the metal tip has a conical-shaped apex with a radius from about 10 nm to about 700 nm;
withdrawing the metal tip from the CNT colloid solution to form a carbon nanotube (CNT) rope attached to the conical-shaped apex of the metal tip and extending between the metal tip and the CNT colloidal solution, wherein an influx of carbon nanotubes from the CNT colloidal solution occurs towards the metal tip due to a meniscus and the influx is in the range of about 1 cm/hour to about 9 cm/hour;
immersing the CNT rope in an electroplating solution comprising at least one metal; and
applying a voltage to the CNT rope to deposit at least a portion of the metal on the CNT rope.
2. The method of claim 1 , further comprising:
preparing the metal tip.
3. The method of claim 1 , further comprising:
preparing the CNT colloid solution.
4. The method of claim 1 , wherein the metal tip comprises tungsten.
5. The method of claim 4 , wherein the metal tip comprises metals having high wettability with the CNT colloidal solution.
6. The method of claim 2 , wherein preparing the metal tip comprises performing an electrochemical etching process on the metal tip.
7. The method of claim 1 , wherein the conical-shaped apex has a radius of less than or equal to about 250 nm.
8. The method of claim 3 , wherein preparing a CNT colloid solution includes dispersing purified CNTs in a solvent.
9. The method of claim 8 , wherein preparing a CNT colloid solution includes performing an ultrasonication treatment to the CNTs.
10. The method of claim 3 , wherein preparing a CNT colloid solution includes adding polymers to the CNT colloid solution.
11. The method of claim 8 , wherein the solvent is dimethylformamide (DMF).
12. The method of claim 8 , wherein the purified CNTs are in the form of a dispersed powder in the solvent.
13. The method of claim 1 , wherein the CNT colloid solution is contained in a vessel that is made of a hydrophobic material.
14. The method of claim 1 , wherein the metal tip is withdrawn from the CNT colloid solution at a pre-determined withdrawal velocity.
15. The method of claim 14 , wherein the given withdrawal velocity ranges from about 0.2 mm/minute to about 1.0 mm/minute.
16. The method of claim 14 , wherein the given withdrawal velocity is about 0.3 mm/minute.
17. The method of claim 1 , wherein the CNT rope includes single-walled nanotubes (SWNTs).
18. The method of claim 1 , wherein the CNT rope includes multi-walled nanotubes (MWNTs).
19. A method for manufacturing a carbon nanotube (CNT) rope comprising:
immersing a metal tip into a carbon nanotube (CNT) colloidal solution, wherein the metal tip has a conical-shaped apex with a radius from about 10 nm to about 700 nm;
withdrawing the metal tip from the CNT colloidal solution to form a CNT rope attached to the conical-shaped apex of the metal tip and extending between the metal tip and the CNT colloidal solution, wherein an influx of carbon nanotubes from the CNT colloidal solution occurs towards the metal tip due to a meniscus and the influx is in the range of about 1 cm/hour to about 9 cm/hour.
20. The method of claim 19 , wherein the metal tip is made of tungsten.
21. The method of claim 1 , wherein the CNT rope has a diameter from about 5 μm to about 30 μm.
22. The method of claim 21 , wherein the CNT rope has a length from about 0.5 cm to about 20 cm.