Substrate preparation for thin film solar cell manufacturing
View Patent ↗A thin film solar cell including a Group IBIIIAVIA absorber layer on a defect free base including a stainless steel substrate is provided. The stainless steel substrate of the base is surface treated to reduce the surface roughness such as protrusions that cause shunts. In one embodiment, the surface roughness is reduced by coating surface with a thin silicon dioxide which fills the cavities and recesses around the protrusions and thereby reducing the surface roughness. After the silicon dioxide film is formed, a contact layer is formed over the ruthenium layer and the exposed portions of the substrate to complete the base.
1. A process of manufacturing a thin film solar cell base structure, comprising:
providing a conductive substrate having a top surface including protruded surface portions and substantially flat surface portions;
depositing a high resistivity material to form a buffer layer on the top surface of the conductive substrate, wherein the high resistivity material substantially covers the substantially flat surface portions while leaving partially exposed some of the protruded surface portions;
depositing a conductive material on the buffer layer and on the some of the protruded surface portions to form a contact layer that is electrically connected to the conductive substrate through the some of the protruded surface portions; and
forming an absorber on the contact layer, wherein the contact layer is configured to act as an electrode for the absorber layer.
2. The method of claim 1 , wherein the conductive material comprises one of tungsten, tantalum, molybdenum, titanium, chromium, ruthenium, iridium and osmium.
3. The method of claim 2 wherein the step of forming the absorber layer forms one of a CIGS and a CIS absorber.
4. The method of claim 3 , wherein the step of forming the absorber layer forms the CIGS absorber and comprises:
electrodepositing a precursor layer comprising copper, indium and gallium; and
reacting the precursor layer in presence of at least one of selenium and sulfur at a temperature range of 350 to 600° C.
5. The method of claim 1 further comprising forming a transparent layer over the absorber, and forming a terminal including busbars and conductive fingers over the transparent layer, wherein the transparent layer includes a transparent buffer layer including one of cadmium sulfide and indium sulfide deposited over the absorber and a transparent conductive layer including one of zinc oxide, indium tin oxide, and indium zinc oxide deposited over the transparent buffer layer.
6. The method of claim 1 , wherein the high resistivity material comprises silicon dioxide.
7. The method of claim 1 , wherein the step of depositing high resistivity material comprises one of spinning, rolling, dipping and doctor-blading.
8. A process of manufacturing a thin film solar cell base structure, comprising:
providing a conductive substrate having a top surface including protruded surface portions and substantially flat surface portions;
depositing a high resistivity material to form a buffer layer on the top surface of the conductive substrate, wherein the high resistivity material fully covers the substantially flat surface portions and the protruded surface portions;
planarizing the buffer layer to expose some of the protruded surface portions;
depositing a conductive material on the buffer layer and on the some exposed protruded surface portions to form a contact layer that is electrically connected to the conductive substrate through the some exposed protruded surface portions; and
forming an absorber on the contact layer, wherein the contact layer is configured to act as an electrode for the absorber layer.
9. The method of claim 8 , wherein the conductive material comprises one of tungsten, tantalum, molybdenum, titanium, chromium, ruthenium, iridium and osmium.
10. The method of claim 9 wherein the step of forming the absorber layer forms one of a CIGS and a CIS absorber.
11. The method of claim 10 , wherein the step of forming the absorber layer forms the CIGS absorber and comprises:
electrodepositing a precursor layer comprising copper, indium and gallium; and
reacting the precursor layer in presence of at least one of selenium and sulfur at a temperature range of 350 to 600° C.
12. The method of claim 10 further comprising forming a transparent layer over the absorber, and forming a terminal including busbars and conductive fingers over the transparent layer, wherein the transparent layer includes a transparent buffer layer including one of cadmium sulfide and indium sulfide deposited over the Group IBIIIAVIA layer and a transparent conductive layer including one of zinc oxide, indium tin oxide, and indium zinc oxide deposited over the transparent buffer layer.
13. The method of claim 8 , wherein the high resistivity material comprises silicon dioxide.
14. The method of claim 8 , wherein the step of depositing a high resistivity material comprises one of spinning, rolling, dipping and doctor-blading.
15. The method of claim 8 , the step of planarizing the buffer layer comprises one of chemical mechanical polishing and mechanical polishing.