Ink carriers containing low viscosity functionalized waxes, phase change inks including same, and methods for making same
View Patent ↗A phase change ink including a colorant and a carrier including a tri-ester of the formula wherein R 1 , R 2 and R 3 , and n are as defined herein.
1. An ink carrier comprising:
a tri-ester of the formula
wherein R 1 , R 2 and R 3 , each, independently of the other, is (a) an alkyl group, including linear and branched, and wherein hetero atoms may or may not be present in the alkyl group, cyclic and acyclic, and substituted and unsubstituted alkyl groups, (b) an aryl group, including substituted and unsubstituted aryl groups, and wherein hetero atoms may or may not be present in the aryl group, (c) an arylalkyl group, including substituted and unsubstituted arylalkyl groups, wherein the alkyl portion of the arylalkyl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the arylalkyl group, or (d) an alkylaryl group, including substituted and unsubstituted alkylaryl groups, wherein the alkyl portion of the alkylaryl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the alkylaryl group, and wherein n is an integer.
2. The ink carrier of claim 1 , wherein at least one of R 1 , R 2 , and R 3 is an alkyl group having from about 20 to about 100 carbon atoms.
3. The ink carrier of claim 1 , wherein at least one of R 1 , R 2 , and R 3 is an alkyl group having about 25 carbon atoms.
4. The ink carrier of claim 1 , wherein R 1 , R 2 , and R 3 are the same as each other.
5. The ink carrier of claim 1 , wherein n is an integer of from about 1 to about 50.
6. The ink carrier of claim 1 , wherein the tri-ester is of the formula
wherein m is an integer having an average value of from about 15 to about 50 and n is an integer having an average value of from about 5 to about 17.
7. The ink carrier of claim 1 , wherein the tri-ester has a viscosity of from about 3 to less than about 100 centipoise at a temperature of about 120° C.
8. The ink carrier of claim 1 , wherein the tri-ester has an onset of crystallization of greater than about 70° C. to about 105° C.
9. The ink carrier of claim 1 , wherein the tri-ester has a peak of melting at about 60° C. and an upper end melting point of less than about 120° C.
10. The ink carrier of claim 1 , wherein the tri-ester comprises at least one component derived from a renewable resource.
11. A phase change ink comprising a colorant and an ink carrier, wherein the ink carrier comprises a tri-ester of the formula
wherein R 1 , R 2 and R 3 , each, independently of the other, is (a) an alkyl group, including linear and branched, and wherein hetero atoms may or may not be present in the alkyl group, cyclic and acyclic, and substituted and unsubstituted alkyl groups, (b) an aryl group, including substituted and unsubstituted aryl groups, and wherein hetero atoms may or may not be present in the aryl group, (c) an arylalkyl group, including substituted and unsubstituted arylalkyl groups, wherein the alkyl portion of the arylalkyl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the arylalkyl group, or (d) an alkylaryl group, including substituted and unsubstituted alkylaryl groups, wherein the alkyl portion of the alkylaryl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the alkylaryl group, and wherein n is an integer from about 1 to about 50.
12. The phase change ink of claim 11 , wherein at least one of R 1 , R 2 , and R 3 is an alkyl group having from about 20 to about 100 carbon atoms.
13. The phase change ink of claim 11 , wherein R 1 , R 2 , and R 3 are the same as each other.
14. The phase change ink of claim 11 , wherein the tri-ester is of the formula
wherein m is an integer having an average value of from about 15 to about 50 and n is an integer having an average value of from about 5 to about 17.
15. The phase change ink of claim 11 , wherein the tri-ester comprises at least one component derived from a renewable resource.
16. The phase change ink of claim 11 , wherein the tri-ester is prepared with a glycerol propoxylate starting material that is a by-product of biodiesel manufacture via transesterification of vegetable oil.
17. The phase change ink of claim 11 , wherein the colorant is a pigment.
18. The phase change ink of claim 11 , wherein the colorant is a dye.
19. A method which comprises:
incorporating into an ink jet printing apparatus a phase change ink composition comprising a colorant and an ink carrier comprising a low a tri-ester of the formula
wherein R 1 , R 2 and R 3 , each, independently of the other, is (a) an alkyl group, including linear and branched, and wherein hetero atoms may or may not be present in the alkyl group, cyclic and acyclic, and substituted and unsubstituted alkyl groups, (b) an aryl group, including substituted and unsubstituted aryl groups, and wherein hetero atoms may or may not be present in the aryl group, (c) an arylalkyl group, including substituted and unsubstituted arylalkyl groups, wherein the alkyl portion of the arylalkyl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the arylalkyl group, or (d) an alkylaryl group, including substituted and unsubstituted alkylaryl groups, wherein the alkyl portion of the alkylaryl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the alkylaryl group, and wherein n is an integer from about 1 to about 50;
wherein the tri-ester is prepared with at least one component derived from a renewable resource.
melting the low energy phase change ink composition; and
causing droplets of the melted ink to be ejected in an imagewise pattern onto a substrate.
20. A compound of the formula
wherein R 1 , R 2 and R 3 , each, independently of the other, is (a) an alkyl group, including linear and branched, and wherein hetero atoms may or may not be present in the alkyl group, cyclic and acyclic, and substituted and unsubstituted alkyl groups, (b) an aryl group, including substituted and unsubstituted aryl groups, and wherein hetero atoms may or may not be present in the aryl group, (c) an arylalkyl group, including substituted and unsubstituted arylalkyl groups, wherein the alkyl portion of the arylalkyl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the arylalkyl group, or (d) an alkylaryl group, including substituted and unsubstituted alkylaryl groups, wherein the alkyl portion of the alkylaryl group can be linear or branched, cyclic or acyclic, and substituted or unsubstituted, and wherein hetero atoms either may or may not be present in either the aryl portion or the alkyl portion of the alkylaryl group, and wherein n is an integer.
21. The compound of claim 20 , wherein at least one of R 1 , R 2 , and R 3 is an alkyl group having at least about 25 carbon atoms; and
wherein n is an integer of from about 1 to about 50.
22. The compound of claim 20 , wherein R 1 , R 2 , and R 3 are the same as each other.
23. The compound of claim 20 , wherein the tri-ester is of the formula
wherein m is an integer having an average value of from about 15 to about 50 and n is an integer having an average value of from about 5 to about 17.
24. The compound of claim 20 , wherein the tri-ester has a viscosity of from about 3 to less than about 100 centipoise at a temperature of about 120° C.
25. The compound of claim 20 , wherein the portion of the tri-ester corresponding to a glycerol propoxylate is derived from a renewable resource.