IP Library Granted Patent US 8,709,108
Granted Patent B2
US 8,709,108 · App. 12/236,867 · Granted Apr 29, 2014

Fuel compositions

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Quick Facts
Patent No.
US 8,709,108
App. No.
12/236,867
Granted
Apr 29, 2014
Kind
B2
Abstract

There is disclosed a fuel composition comprising (a) a major amount of a middle distillate fuel comprising from about 0.5% to about 30% by weight fatty acid methyl esters, relative to the total amount of the fuel composition; and (b) a minor amount of an additive composition comprising an antioxidant system comprising at least one cyclic amine antioxidant and at least one phenolic antioxidant, and at least one ashless dispersant, wherein said fuel composition demonstrates reduced sediment formation as compared to a fuel composition devoid of the additive composition, and methods of use thereof.

Claims (20)

1. A fuel composition comprising:

(a) a major amount of a middle distillate fuel comprising from about 0.5% to about 30% by weight fatty acid methyl esters, relative to the total amount of the fuel composition; and

(b) a minor amount of an additive composition comprising an antioxidant system comprising N,N-dimethyl cyclohexamine, at least one phenolic antioxidant, and at least one hydrocarbyl-substituted succinimide dispersant, wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 300 ppm, and wherein the N,N-dimethyl cyclohexamine and the at least one phenolic antioxidant are present in an amount to deliver from about 20 ppm to about 100 ppm;

wherein said fuel composition demonstrates reduced sediment formation as compared to a fuel composition devoid of the additive composition.

2. The fuel composition of claim 1 , wherein the hydrocarbyl substituent of the succinimide is derived from polyisobutene having a number average molecular weight ranging from about 500 to about 5,000.

3. The fuel composition of claim 1 , wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 200 ppm.

4. The fuel composition of claim 1 , wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 90 ppm.

5. The fuel composition of claim 1 , wherein the phenolic antioxidant is a tertiary butyl phenol.

6. The fuel composition of claim 1 , wherein the phenolic antioxidant is a di-substituted tertiary butyl phenol.

7. The fuel composition of claim 1 , wherein the middle distillate fuel comprises from about 10% to about 20% by weight fatty acid methyl esters.

8. The fuel composition of claim 1 , further comprising at least one additive selected from the group consisting of supplementary dispersants/detergents, antioxidants, thermal stabilizers, carrier fluids, metal deactivators, dyes, markers, corrosion inhibitors, biocides, antistatic additives, drag reducing agents, friction modifiers, demulsifiers, emulsifiers, dehazers, anti-icing additives, antiknock additives, anti-valve-seat recession additives, surfactants, other lubricity additives combustion improvers, cetane number improvers, and mixtures thereof.

9. A method of reducing sediment formation in a fuel composition, said method comprising:

providing a major amount of a middle distillate fuel comprising from about 0.5% to about 30% by weight fatty acid methyl esters; and

mixing with said fuel a minor amount of an additive composition comprising an antioxidant system comprising N,N-dimethylcyclohexamine, at least one phenolic antioxidant, and at least one hydrocarbyl-substituted succinimide dispersant, wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 300 ppm, and wherein the N,N-dimethyl cyclohexamine and the at least one phenolic antioxidant are present in an amount to deliver from about 20 ppm to about 100 ppM.

10. The method of claim 9 , wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 200 ppm.

11. The method of claim 9 , wherein the hydrocarbyl-substituted succinimide is present in an amount ranging from about 60 ppm to about 90 ppm.

12. The method of claim 9 , wherein the phenolic antioxidant is a tertiary butyl phenol.

13. The method of claim 9 , wherein the phenolic antioxidant is a di-substituted tertiary butyl phenol.

14. The fuel composition of claim 1 , wherein the middle distillate fuel comprises from about 10% to about 20% by weight fatty acid methyl esters.

15. The method of claim 9 , further comprising mixing with said fuel at least one additive selected from the group consisting of supplementary dispersants/detergents, antioxidants, thermal stabilizers, carrier fluids, metal deactivators, dyes, markers, corrosion inhibitors, biocides, antistatic additives, drag reducing agents, friction modifiers, demulsifiers, emulsifiers, dehazers, anti-icing additives, antiknock additives, anti-valve-seat recession additives, surfactants, other lubricity additives combustion improvers, cetane number improvers, and mixtures thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 3, 2019
From: NOVI MANUFACTURING, LLC
To: ADELL GROUP, INC.
Reel/Frame 049667/0297 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 26, 2008
From: CLAYDON, DAVID JOHN
To: AFTON CHEMICAL CORPORATION
Reel/Frame 021589/0810 →