Polysilazane thermosetting polymers for use in chromatographic systems and applications

1. A non-glass vessel or conduit, said vessel or conduit having an interior surface and a coating over the interior surface, said coating providing a barrier against adsorption to said interior surface of a component of a fluid in contact with said surface, said coating comprising an amorphous non-glassy ceramic composition that is derived from a cross-linked polymer chosen from a polysilazane, a polysiloxane, or a mixture of a polysilazane and a polysiloxane.

2. A vessel or conduit as set forth in claim 1 wherein the preparation of said vessel or conduit comprises:

applying to the interior surface of said vessel or conduit a flowable dispersion comprising said oligomer; and

heating said dispersion on said interior surface to form said ceramic composition.

3. The conduit of claim 1 wherein the conduit is tubing or a transfer line.

4. The conduit of claim 1 wherein the conduit is a stainless steel gas regulator or tube.

5. The conduit of claim 1 wherein the conduit is a chromatographic fitting.

6. The conduit of claim 5 wherein the chromatographic fitting is a valve, a tee, or an elbow.

7. The vessel of claim 1 wherein the vessel is a vessel for conducting reaction or adsorption operations.

8. The vessel of claim 1 wherein the vessel is a container for liquids or gases.

9. The vessel of claim 8 wherein the container is for SUMMA or TO type sampling.

10. The conduit of claim 1 wherein the conduit is a chromatographic column or instrument hardware.

11. The conduit of claim 10 wherein the chromatographic column or instrument hardware is a gas or liquid chromatographic column or instrument hardware.

12. The conduit of claim 10 wherein chromatographic instrument hardware is an injection material liner, an inlet disk, or a detector assembly.

13. The conduit of claim 1 wherein the conduit is high pressure liquid chromatography hardware.

14. The conduit of claim 13 wherein the hardware is a nozzle, a combustion chamber, a spray ring, or a flow restrictor.

15. The vessel or conduit of claim 1 further comprising a particulate adsorbent material that is lodged in the coating or that is adhered to the interior surface of the vessel or conduit via the coating.

16. The vessel or conduit of claim 1 further comprising a fluid in contact with the vessel or conduit.

17. The vessel or conduit of claim 15 further comprising a fluid in contact with the vessel or conduit.

18. A glass vessel or conduit having an interior surface and a coating over the interior surface, said coating providing a barrier against adsorption to said interior surface of a component of a fluid in contact with said surface, said coating comprising an amorphous non-glassy ceramic composition that is derived from a cross-linked polymer chosen from a polysilazane, a polysiloxane, or a mixture of a polysilazane and a polysiloxane.

19. The vessel or conduit of claim 18 wherein said glass vessel or conduit is selected from the group consisting of inlet sleeves, syringe barrels, sample vials, connectors, adsorbent trap assemblies, and thermal tubes.

20. A non-glass vessel or conduit, said vessel or conduit having an interior surface and a coating over the interior surface, said coating providing a barrier against adsorption to said interior surface of a component of a fluid in contact with said surface, said coating comprising an amorphous non-glassy ceramic composition that is derived from a silazane oligomer having the formula:

wherein R is H or —CH═CH 2 and n is 1 to 20.

21. A glass vessel or conduit having an interior surface and a coating over the interior surface, said coating providing a barrier against adsorption to said interior surface of a component of a fluid in contact with said surface, said coating comprising an amorphous non-glassy ceramic composition is derived from a silazane oligomer having the formula:

wherein R is H or —CH═CH 2 and n is 1 to 20.