Stable foamed cement slurry compositions and methods for making and using same
View Patent ↗A foamed cement composition is disclosed for utilization in performing a variety of well cementing operations, and to methods for making and using same. The foamed cement composition basically includes a cement, water sufficient to form a pumpable slurry, a gas sufficient to foam the slurry, a foaming agent and optionally a foam stabilizing agent.
1. A method for preparing a foamed, gelled cement composition comprising:
adding a cement to an aqueous fluid,
adding a first additive composition comprising:
a charged polymer,
a stabilizing agent, and
water
adding a second additive composition comprising an oppositely charged surfactant, where the charged polymer and the oppositely charged surfactant form a pre-foamed, gelled slurry including an ionic gel system comprising the charged polymer ionically bonded to the oppositely charged surfactant, and
injecting an amount of a gas sufficient to foam the pre-foamed, gelled slurry to form the foamed, gelled cement composition,
where the foamed, gelled cement composition is stable at temperatures from room temperature up to about 350° F. for a period of time sufficient for cement placement and cement setting, and
where the foamed, gelled cement composition is compressible prior to setting.
2. The method of claim 1 , wherein the cement is selected from the group consisting of API class cements, cements used for oil field applications, slag cements, and mixtures or combinations thereof.
3. The method of claim 1 , wherein the aqueous fluid is selected from the group comprising fresh water, salt water, brines, seawater, and mixtures or combinations thereof.
4. The method of claim 1 , wherein the gas is selected from the group consisting of nitrogen, air, other nitrogen-oxygen mixtures, and mixtures or combinations thereof.
5. The method of claim 1 , wherein the foamed cement composition has a density between about 6 and about 16 pounds per gallon.
6. The method of claim 1 , wherein the ionic gel system comprises (a) a cationic surfactant or a plurality of cationic surfactants and an anionic polymer or (b) an anionic surfactant or a plurality of anionic surfactants and a cationic polymer, or (c) mixtures or combinations thereof.
7. The method of claim 6 , wherein the ionic gel system is present in an amount between about 0.05% and about 10% by weight of the aqueous fluid in the composition.
8. The method of claim 1 , further comprising a cement dispersant present in an amount between about 0.15% and about 5% by weight of the aqueous fluid in the composition.
9. The method of claim 1 , further comprising a cement activator selected from the group consisting of hydrated lime, Ca(OH) 2 , sodium hydroxide, sodium sulfate, sodium carbonate, sodium silicate, Portland cement and mixtures or combinations thereof.
10. The method of claim 9 , wherein the activator is present in an amount between about 0.5% and about 10% by weight of the cement.
11. The method of claim 1 , wherein the stabilizing agent is present in an amount between about 0.01% and about 5% by weight of the aqueous fluid in the composition.
12. The method of claim 11 , wherein the foam stabilizing agent is selected from the group consisting of zwitterionic compounds, amine oxides, alkylated polyalkylene oxides, or mixture or combinations thereof.
13. The method of claim 12 , wherein the foam stabilizing agent is present in an amount between about 1% and about 2% by weight of the aqueous fluid in the composition.