Process to produce an enriched composition
View Patent ↗A process is provided for producing an enriched carboxylic acid compositions produced by contacting composition comprising a carboxylic acid with an enrichment feed in an enrichment zone to form an enriched carboxylic acid composition. This invention also relates to a process and the resulting compositions for removing catalyst from a carboxylic acid composition to produce a post catalyst removal composition.
1. A process to produce an enriched composition suitable for use in the production of step-growth polymers, said process comprising:
a) oxidizing an aromatic feedstock comprising para-xylene in a primary oxidation zone to form a crude carboxylic acid composition comprising terephthalic acid;
b) optionally subjecting said crude carboxylic acid composition to a liquid displacement zone to form a slurry composition;
c) crystallizing said slurry composition or said crude carboxylic acid composition in a crystallization zone to form a crystallized slurry composition;
d) cooling and optionally enriching said crystallized slurry composition in a cooling zone to form a cooled carboxylic acid composition;
e) subjecting said cooled carboxylic acid composition to a wash feed comprising acetic acid in a catalyst removal zone to form a post catalyst removal composition, a wash liquor, and a catalyst rich liquor; and
f) contacting said post catalyst removal composition with an enrichment feed in an enrichment zone to form said enriched composition, said enrichment feed comprising at least one compound selected from the group consisting of isophthalic acid, phthalic acid, benzene-tricarboxylic acid isomers, hydroxybenzoic acid isomers, hydroxymethylbenzoic acid isomers, dicarboxybiphenyl isomers, dicarboxystilbene isomers, tricarboxybiphenyl isomers, tricarboxybenzophenone isomers, dicarboxybenzophenone isomers, dicarboxybenzil isomers, form-acet-hydroxybenzoic acid isomers, acet-hydroxymethylbenzoic acid isomers, and phthaldehyde isomers.
2. The process according to claim 1 wherein said primary oxidation zone comprises at least one oxidation reactor operated at a temperature from 110° C. to 200° C.
3. The process according to claim 1 wherein said liquid displacement zone comprises a solid-liquid separator that is operated at a temperature between about 50° C. to about 200° C.
4. The process according to claim 3 wherein said solid liquid displacement zone comprises a solid liquid separator selected from the group consisting of a belt filter, a rotary vacuum filter, and a rotary disk pack centrifuge.
5. The process according to claim 2 wherein said liquid displacement zone comprises a solid-liquid separator that is operated at a temperature between about 50° C. to about 200° C.
6. The process according to claim 1 wherein said cooled carboxylic acid composition is cooled to a temperature ranging from about 20° C. to about 90° C.
7. The process according to claim 1 wherein said cooled carboxylic acid composition is cooled to a temperature ranging from about 5° C. to about 195° C.
8. The process according to claim 1 wherein said wash feed is at a temperature ranging from about 20° C. to about 90° C.
9. The process according to claim 1 wherein said wash feed is at a temperature ranging from about 5° C. to about 195° C.
10. The process according to claim 1 wherein a liquid displacement zone is between the crystallization zone and cooling zone.