Anode and battery
View Patent ↗A battery capable of obtaining superior cycle characteristics and safety is provided. The battery includes a cathode, an anode, and an electrolytic solution. The electrolytic solution is impregnated in a separator provided between the cathode and the anode. The anode has an insulative coat on an anode active material layer provided on an anode current collector. The coat contains an insulating material such as a meal hydroxide and a metal oxide. The coat is in a form of plate divided into a plurality of portions. The insulation property of the coat prevents internal short circuit. A plurality of portions of the coat prevent separation of the anode active material layer and decomposition of the electrolytic solution. Further, even when short circuit occurs, heat generation is prevented by heat absorption characteristics of the coat.
1. An anode comprising:
an anode current collector;
an active material layer on the anode current collector; and
an insulative coat on the anode active material layer,
wherein,
the insulative coat is divided into a plurality of spaced apart portions across an outer surface of the anode active material layer and is configured to provide a migration path for an electrode reactant to the active material layer between the portions, and
the insulative coat comprises (a) at least one of a metal hydroxide selected from the group consisting of aluminum hydroxide (Al(OH) 3 zirconium hydroxide (Zr(OH)) 4 ), and titanium hydroxide (Ti(OH) 4 ), and (b) at least one of a metal oxide selected from the group consisting of aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ), and titanium oxide (TiO 2 ).
2. The anode according to claim 1 , wherein the insulative coat is in the form of a plate.
3. The anode according to claim 1 , wherein:
the anode active material layer contains a plurality of anode active material particles, and
the insulative coat extends along a portion of the surfaces of the anode active material particles and partially covers the surfaces of the anode active material particles.
4. The anode according to claim 3 , wherein the insulative coat extends along a portion of a surface corresponding to each of two or more anode active material particles and continuously covers the portions of the two or more surfaces of the anode active material particles.
5. The anode according to claim 1 , wherein the insulative coat is formed by electrolytic plating method.
6. The anode according to claim 1 , wherein the anode active material layer contains a plurality of anode active material particles containing silicon.
7. The anode according to claim 1 , wherein where an area of the anode active material layer is S 1 and an area of the insulative coat is S 2 , and an area ratio S 2 /S 1 is in the range from 0.2 to 0.9, inclusive.
8. The anode according to claim 1 , wherein a weight per unit area of the insulative coat is in the range from 0.02 mg/cm 2 to 1 mg/cm 2 , inclusive.
9. A battery comprising:
a cathode;
an anode; and
an electrolytic solution,
wherein,
the anode comprises an anode current collector, an active material layer on the current collector and an insulative coat on the active material layer,
the insulative coat is divided into a plurality of spaced apart portions across an outer surface of the anode active material layer and is configured to provide a migration path for an electrode reactant to the active material layer between the portions, and
the insulative coat comprises (a) at least one of a metal hydroxide selected from the group consisting of aluminum hydroxide (Al(OH) 3 zirconium hydroxide (Zr(OH)) 4 ), and titanium hydroxide (Ti(OH) 4 ), and (b) at least one of a metal oxide selected from the group consisting of aluminum oxide (Al 2 O 3 ), zirconium oxide (ZrO 2 ), and titanium oxide TiO 2 ).
10. The battery according to claim 9 , wherein the insulative coat is in the form of a plate.
11. The battery according to claim 9 , wherein the anode active material layer contains a plurality of anode active material particles, and the insulative coat extends along a portion of the surfaces of the anode active material particles and partially covers the surfaces of the anode active material particles.
12. The battery according to claim 11 , wherein the insulative coat extends along a portion of a surface corresponding to each of two or more of the anode active material particles and covers the portions of the two or more surfaces of the anode active material particles.
13. The battery according to claim 9 , wherein the insulative coat is formed by electrolytic plating method.
14. The battery according to claim 9 , wherein the anode active material layer contains a plurality of anode active material particles containing silicon.
15. The battery according to claim 9 , wherein where an area of the anode active material layer is S 1 and an area of the coat is S 2 , and an area ratio S 2 /S 1 is in the range from 0.2 to 0.9, inclusive.
16. The battery according to claim 9 , wherein a weight per unit area of the coat is in the range from 0.02 mg/cm 2 to 1 mg/cm 2 , inclusive.