IP Library Granted Patent US 8,460,824
Granted Patent B2
US 8,460,824 · App. 12/253,516 · Granted Jun 11, 2013

Lithium-iron disulfide cell design

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,460,824
App. No.
12/253,516
Granted
Jun 11, 2013
Kind
B2
Abstract

The invention relates to electrochemical cells having a jellyroll electrode assembly that includes a lithium-based negative electrode, a positive electrode with a coating comprising greater than about 94 wt. % of iron disulfide.

Claims (10)

1. A battery comprising:

a. a jellyroll electrode assembly comprising an anode consisting essentially of lithium or a lithium alloy without the use of a separate current collector, a microporous separator having a thickness between 16 and 22 microns, and a cathode comprising a cathode dry mix coated onto at least one side of a current collector, said coating having a thickness, exclusive of the current collector, between 80 microns and 102 microns and a void volume, exclusive of the current collector, between 28% and 40%, said cathode dry mix comprising at least one binder, at least one conductor, at least one processing aid and between 95-98 wt. % of pyrite having at least 95 wt. % of iron disulfide, and said cathode dry mix further having a cathode dry mix density of at least 4.35 g/cc and a cathode loading, after coating and densification on the current collector, of at least 24 mg/cm 2 ;

b. an organic electrolyte comprising 1,3-dioxolane and 1,2-dimethoxyethane;

c. a cylindrical container having a yield strength, a height and a diameter, said height exceeding the diameter of the container; and

d. wherein, under any discharge condition, the jellyroll electrode assembly exerts between greater than 50% but no more than 80% of the yield strength of the container.

2. The battery of claim 1 , wherein the battery has a capacity of at least 4000 mAh at 200 mA continuous drain for a FR6 battery.

3. The battery of claim 1 , wherein the coating comprises less than 2 wt. % conductor.

4. The battery of claim 3 , wherein the coating comprises 2 wt. % or less of binder, processing aid, or combination thereof.

5. The battery of claim 1 , wherein the cylindrical container is formed from cold rolled steel.

6. The battery of claim 5 , wherein the cylindrical container has a wall with a thickness between 7-10 mils when the cell is an FR6 cell.

Assignments (8)
AMENDED AND RESTATED INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 19, 2025
From: ENERGIZER BRANDS, LLC; ENERGIZER AUTO, INC.,; ENERGIZER AUTO SALES, INC.
To: JPMORGAN CHASE BANK, N.A., AS COLLATERAL AGENT
Reel/Frame 070565/0282 →
PATENT SECURITY AGREEMENT Recorded Dec 30, 2020
From: ENERGIZER BRANDS, LLC; ENERGIZER AUTO, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 054875/0651 →
PATENT SECURITY AGREEMENT Recorded Jan 8, 2019
From: ENERGIZER HOLDINGS, INC.; AMERICAN COVERS, LLC; ASSOCIATED PRODUCTS, LLC; CALIFORNIA SCENTS, LLC; ENERGIZER BRANDS, LLC; ENERGIZER MANUFACTURING, INC.
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 048029/0246 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENT RIGHTS Recorded Jan 8, 2019
From: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
To: ENERGIZER BRANDS, LLC
Reel/Frame 048888/0300 →
CORRECTIVE ASSIGNMENT TO CORRECT THE APPLICATION NUMBER 29/499,135 PREVIOUSLY RECORDED AT REEL: 036019 FRAME: 814. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 16, 2016
From: EVEREADY BATTERY COMPANY
To: ENERGIZER BRANDS, LLC
Reel/Frame 040054/0660 →
SECURITY AGREEMENT Recorded Jul 15, 2015
From: ENERGIZER BRANDS, LLC
To: JPMORGAN CHASE BANK, N.A., AS AGENT
Reel/Frame 036106/0392 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2015
From: EVEREADY BATTERY COMPANY, INC.
To: ENERGIZER BRANDS, LLC
Reel/Frame 036019/0814 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 20, 2008
From: MARPLE, JACK W
To: EVEREADY BATTERY COMPANY, INC.
Reel/Frame 021702/0085 →